Beneficial Reuse
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Waste valorization, beneficial reuse, beneficial use, value recovery or waste reclamation is the process of
waste Waste are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor Value (economics), economic value. A wast ...
products or residues from an economic process being valorized (given economic value), by
reuse Reuse is the action or practice of using an item, whether for its original purpose (conventional reuse) or to fulfill a different function (creative reuse or repurposing). It should be distinguished from recycling, which is the breaking down of ...
or
recycling Recycling is the process of converting waste materials into new materials and objects. This concept often includes the recovery of energy from waste materials. The recyclability of a material depends on its ability to reacquire the propert ...
in order to create economically useful materials. The term comes from practices in sustainable manufacturing and
economics Economics () is a behavioral science that studies the Production (economics), production, distribution (economics), distribution, and Consumption (economics), consumption of goods and services. Economics focuses on the behaviour and interac ...
,
industrial ecology Industrial ecology (IE) is the study of material and energy flows through industrial systems. The global industrial economy can be modelled as a network of industrial processes that extract resources from the Earth and transform those resource ...
and
waste management Waste management or waste disposal includes the processes and actions required to manage waste from its inception to its final disposal. This includes the collection, transport, treatment, and disposal of waste, together with monitor ...
. The term is usually applied in industrial processes where residue from creating or processing one good is used as a raw material or energy feedstock for another industrial process.
Industrial waste Industrial waste is the waste produced by industrial activity which includes any material that is rendered useless during a manufacturing process such as that of factories, mills, and mining operations. Types of industrial waste include dirt and ...
s in particular are good candidates for valorization because they tend to be more consistent and predictable than other waste, such as
household waste Municipal solid waste (MSW), commonly known as trash or garbage in the United States and rubbish in Britain, is a waste type consisting of everyday items that are discarded by the public. "Garbage" can also refer specifically to food waste, ...
. Historically, most industrial processes treated waste products as something to be disposed of, causing
industrial pollution Pollution is the introduction of contaminants into the natural environment that cause harm. Pollution can take the form of any substance (solid, liquid, or gas) or energy (such as radioactivity, heat, sound, or light). Pollutants, the component ...
unless handled properly. However, increased regulation of residual materials and socioeconomic changes, such as the introduction of ideas about
sustainable development Sustainable development is an approach to growth and Human development (economics), human development that aims to meet the needs of the present without compromising the ability of future generations to meet their own needs.United Nations General ...
and
circular economy A circular economy (also referred to as circularity or CE) is a model of resource Production (economics), production and Resource consumption, consumption in any economy that involves sharing, leasing, Reuse, reusing, repairing, refurbishing, and ...
in the 1990s and 2000s increased focus on industrial practices to recover these resources as value add materials. Academics focus on finding economic value to reduce environmental impact of other industries as well, for example the development of
non-timber forest product Non-timber forest products (NTFPs) are useful foods, substances, materials and/or commodities obtained from forests other than timber. Harvest ranges from wild collection to farming. They typically include game animals, fur-bearers, nuts, see ...
s to encourage conservation.


Biomass


Crop residue

Crop residue Crop residues are waste materials generated by agriculture. The two types are: * Field residues are materials left in an agricultural field or orchard after the crop has been harvested. These residues include stalks and stubble (stems), leav ...
, such as
corncob A corncob, also called corn cob or cob of corn, is the hard core of an ear of maize, bearing the kernels, made up of the chaff, woody ring, and pith. Corncobs contain mainly cellulose, hemicellulose, and lignin. However, during several instance ...
, and other residues from the food processing industry, such as residues from
biorefineries A biorefinery is a refinery that converts biomass to energy and other beneficial byproducts (such as chemicals). The International Energy Agency Bioenergy Task 42 defined biorefining as "the sustainable processing of biomass into a spectrum of bi ...
, have high potential for use in further processes, such as producing
biofuel Biofuel is a fuel that is produced over a short time span from Biomass (energy), biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricu ...
,
bioplastic Bioplastics are plastic materials produced from renewable biomass sources. Timeline of plastic development, Historically, bioplastics made from natural materials like shellac or Celluloid, cellulose had been the first plastics. Since the end of ...
s, and other
biomaterial A biomaterial is a substance that has been Biological engineering, engineered to interact with biological systems for a medical purpose – either a therapeutic (treat, augment, repair, or replace a tissue function of the body) or a Medical diag ...
s for industrial processes.


Food waste

One of the more fruitful fields of work is food waste—when deposited in landfills, food waste produces the greenhouse gas methane and other toxic compounds that can be dangerous to humans and local ecosystems.
Landfill gas utilization Landfill gas utilization is a process of gathering, processing, and treating the methane or another gas landfill gas, emitted from decomposing garbage to produce electricity, heat, fuels, and various chemical compounds. After fossil fuel and agr ...
and
municipal compost Municipal solid waste (MSW), commonly known as trash or garbage in the United States and rubbish in Britain, is a waste type consisting of everyday items that are discarded by the public. "Garbage" can also refer specifically to food waste, as ...
ing can capture and use the organic nutrients. Food waste collected from non-industrial sources is harder to use, because it often has much greater diversity than other sources of waste—different locations and different windows of time produce very different compositions of material, making it hard to use for industrial processes. Transforming food waste to either food products, feed products, or converting it to or extracting food or feed ingredients is termed as food waste valorisation. Valorisation of food waste offers an economical and environmental opportunity, which can reduce the problems of its conventional disposal. Food wastes have been demonstrated to be valuable bioresources that can be utilised to obtain a number of useful products, including
biofertilizer A biofertilizer is a substance containing living micro-organisms which, when applied to seeds, plant surfaces, or soil, colonize the rhizosphere or the interior of the plant and promotes growth by increasing the supply or availability of primary n ...
s,
bioplastic Bioplastics are plastic materials produced from renewable biomass sources. Timeline of plastic development, Historically, bioplastics made from natural materials like shellac or Celluloid, cellulose had been the first plastics. Since the end of ...
s,
biofuel Biofuel is a fuel that is produced over a short time span from Biomass (energy), biomass, rather than by the very slow natural processes involved in the formation of fossil fuels such as oil. Biofuel can be produced from plants or from agricu ...
s, chemicals, and nutraceuticals. There is much potential to recycle food wastes by conversion to
insect protein Insects as food or edible insects are insect species used for human consumption. Over 2 billion people are estimated to eat insects on a daily basis. Globally, more than 2,000 insect species are considered edible, though far fewer are discussed ...
.


Human excreta


Mine wastes

Mine tailings and other mining residues can be very large in volume and cause significant environmental issues even when stored correctly (such as
tailings dam A tailings dam is typically an earth-fill embankment dam used to store byproducts of mining operations after separating the ore from the gangue. Tailings can be liquid, solid, or a slurry of fine particles, and are usually highly toxic and poten ...
failures and
acid mine drainage Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines and coal mines. Acid rock drainage occurs naturally within some environments as part of the rock weatherin ...
). Additionally, demand for the rare minerals found in tailings is increasing. Sometimes reuse can be done on site to address other problems from mining, such as using alkaline rocks to abate
acid mine drainage Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines and coal mines. Acid rock drainage occurs naturally within some environments as part of the rock weatherin ...
.
Red mud Red mud, now more frequently termed bauxite residue, is an industrial waste generated during the processing of bauxite into alumina using the Bayer process. It is composed of various oxide compounds, including the iron oxides which give its red ...
is a byproduct of the
Bayer process The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer. Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al2O3), the ...
which is the main process employed to generate
alumina Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula . It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly ...
from
bauxite Bauxite () is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (), boehmite (γ-AlO(OH)), and diaspore (α-AlO(OH) ...
. Numerous uses of the highly
alkaline In chemistry, an alkali (; from the Arabic word , ) is a basic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The ...
substance have been proposed, among them mitigating acid mine drainage. The largest waste by volume - especially in
open pit mining Open-pit mining, also known as open-cast or open-cut mining and in larger contexts mega-mining, is a surface mining technique that extracts rock or minerals from the earth. Open-pit mines are used when deposits of commercially useful ore or ro ...
- is usually
overburden In mining, overburden (also called waste or spoil) is the material that lies above an area that lends itself to economical exploitation, such as the rock, soil, and ecosystem that lies above a coal seam or ore body. Overburden is distinct from tai ...
which is either used to fill the mine back in when mining ceases or can be used for various construction purposes, as aggregate or to create infill. However, depending on the composition of the material, this may come with risks and hazards if pollutants like heavy metals contaminate the material. In mining operations that remove significant amounts of material even after filling the overburden back in, the resulting land is often below the natural water table. In Germany the former
lignite Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered the lowest ...
pits were thus turned into the
Lusatian Lake District The Lusatian Lake District (, , ) is a chain of artificial lakes under construction in Germany across the north-eastern part of Saxony and the southern part of Brandenburg. Through flooding as a part of an extensive regeneration programme, sever ...
, the
Central German Lake District The Central German Lake District (''German:'' Mitteldeutsches Seenland) is a group of artificial lakes that are the result of extensive open pit lignite mining. The area around Leipzig Leipzig (, ; ; Upper Saxon: ; ) is the most populous ci ...
and other similar areas.


Nuclear waste

While
low Low or LOW or lows, may refer to: People * Low (surname), listing people surnamed Low Places * Low, Quebec, Canada * Low, Utah, United States * Lo Wu station (MTR code LOW), Hong Kong; a rail station * Salzburg Airport (ICAO airport code: LO ...
and intermediate level waste are usually not the subject of much public attention, they make up the bulk (by volume and mass) of
nuclear waste Radioactive waste is a type of hazardous waste that contains radioactive material. It is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear ...
. However,
spent fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and ...
is responsible for the vast majority of the radioactivity produced by nuclear power plants. There are active industrial scale applications of waste valorization using spent nuclear fuel - primarily
nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...
using the
PUREX PUREX (plutonium uranium reduction extraction) is a chemical method used to purify fuel for nuclear reactors or nuclear weapons. It is based on liquid–liquid extraction ion-exchange. PUREX is the '' de facto'' standard aqueous nuclear reproc ...
process which yields
reactor grade plutonium Reactor-grade plutonium (RGPu) is the isotopic grade of plutonium that is found in spent nuclear fuel after the uranium-235 primary fuel that a nuclear nuclear reactor, power reactor uses has burnup, burnt up. The uranium-238 from which most of the ...
for use in
MOX-fuel Mixed oxide fuel (MOX fuel) is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an alternative to the low-enric ...
as well as
reprocessed uranium Reprocessed uranium (RepU) is the uranium recovered from nuclear reprocessing, as done commercially in France, the UK and Japan and by nuclear weapons states' military plutonium production programs. This uranium makes up the bulk of the material ...
. In addition to that process, there are numerous proposals and small scale applications of recovering various substances for use. While over 90% of spent fuel is uranium, the rest (namely
fission products Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the releas ...
,
minor actinides Minor may refer to: Common meanings * Minor (law), a person not under the age of certain legal activities. * Academic minor, a secondary field of study in undergraduate education Mathematics * Minor (graph theory), a relation of one graph to an ...
and plutonium) has also attracted considerable attention. High value products contained in spent fuel have both radioactive applications such as
Americium-241 Americium-241 (Am, Am-241) is an isotope of americium. Like all isotopes of americium, it is radioactive, with a half-life of . Am is the most common isotope of americium as well as the most prevalent isotope of americium in nuclear waste. It ...
for use in smoke detectors,
Tritium Tritium () or hydrogen-3 (symbol T or H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.33 years. The tritium nucleus (t, sometimes called a ''triton'') contains one proton and two neutrons, whereas the nucleus of the ...
,
Neptunium-237 Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be ...
for use as a precursor to
Plutonium-238 Plutonium-238 ( or Pu-238) is a radioactive isotope of plutonium that has a half-life of 87.7 years. Plutonium-238 is a very powerful alpha emitter; as alpha particles are easily blocked, this makes the plutonium-238 isotope suitable for usage ...
or various industrial radionuclides like
Krypton-85 Krypton-85 (85Kr) is a radioisotope of krypton. Krypton-85 has a half-life of 10.756 years and a maximum decay energy of 687 keV. It decays into stable rubidium-85. Its most common decay (99.57%) is by beta particle emission with a maximum ene ...
,
Caesium-137 Caesium-137 (), cesium-137 (US), or radiocaesium, is a radioactive isotope of caesium that is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nucle ...
or
Strontium-90 Strontium-90 () is a radioactive isotope of strontium produced by nuclear fission, with a half-life of 28.79 years. It undergoes β− decay into yttrium-90, with a decay energy of 0.546 MeV. Strontium-90 has applications in medicine a ...
, as well as nonradioactive applications as some fission products decay quickly to stable or essentially stable nuclides. Elements in the latter category include
xenon Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
,
ruthenium Ruthenium is a chemical element; it has symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is unreactive to most chem ...
or
rhodium Rhodium is a chemical element; it has symbol Rh and atomic number 45. It is a very rare, silvery-white, hard, corrosion-resistant transition metal. It is a noble metal and a member of the platinum group. It has only one naturally occurring isot ...
. There are also proposals to use the
decay heat Decay heat is the heat released as a result of radioactive decay. This heat is produced as an effect of radiation on materials: the energy of the alpha particle, alpha, Beta particle, beta or gamma radiation is converted into the thermal movement ...
of spent fuel, which is currently "wasted" in the
spent fuel pool Spent fuel pools (SFP) are storage pools (or "ponds" in the United Kingdom) for spent fuel from nuclear reactors. They are typically 40 or more feet (12 m) deep, with the bottom 14 feet (4.3 m) equipped with storage racks designed to hold ...
, to generate power and/or
district heating District heating (also known as heat networks) is a system for distributing heat generated in a centralized location through a system of insulated pipes for residential and commercial heating requirements such as space heater, space heating and w ...
. Strontium-90 is suitable as a fuel for a
radioisotope thermoelectric generator A radioisotope thermoelectric generator (RTG, RITEG), or radioisotope power system (RPS), is a type of nuclear battery that uses an array of thermocouples to convert the Decay heat, heat released by the decay of a suitable radioactive material i ...
and has been extracted from spent nuclear fuel for this purpose in the past. However, the need to process the highly reactive metal into the inert
perovskite Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as , known as the perovskite (stru ...
form
Strontium titanate Strontium titanate is an oxide of strontium and titanium with the chemical formula strontium, Srtitanium, Tioxygen, O3. At room temperature, it is a centrosymmetric paraelectricity, paraelectric material with a Perovskite (structure), perovskite st ...
reduces the
power density Power density, defined as the amount of power (the time rate of energy transfer) per unit volume, is a critical parameter used across a spectrum of scientific and engineering disciplines. This metric, typically denoted in watts per cubic meter ...
to "only" about 0.46 watts per gram. Caesium-137 can also be used for
food irradiation Food irradiation (sometimes American English: radurization; British English: radurisation) is the process of exposing food and food packaging to ionizing radiation, such as from gamma rays, x-rays, or electron beams. Food irradiation improves ...
.


Field of study

The academic journal Waste & Biomass Valorization publishes scholarship on the topic and was first published in 2010. A special edition of the Journal of Industrial Ecology focused on valorization in 2010. Routledge published a textbook on the topic in 2016. A special issue of the
Journal of Environmental Management The ''Journal of Environmental Management'' is a semi-monthly peer-reviewed scientific journal covering research on environmental science and quality that was established in 1973 by Academic Press in London. It is currently published by Elsevier a ...
focused on biomass and biowaste valorization in 2019.


References

{{Reflist Economics and climate change Recycling Reuse