The Beilstein test is a simple
qualitative chemical test
In chemistry, a chemical test is a qualitative property, qualitative or Quantitative property, quantitative procedure designed to identify, quantify, or characterise a chemical compound or substituent, chemical group.
Purposes
Chemical testing m ...
for organic
halides
In chemistry, a halide (rarely halogenide) is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluo ...
. It was developed by
Friedrich Konrad Beilstein.
A
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
wire is cleaned and heated in a
Bunsen burner
A Bunsen burner, named after Robert Bunsen, is a kind of ambient air gas burner used as laboratory equipment; it produces a single open gas flame, and is used for heating, sterilization, and combustion.
The gas can be natural gas (which is main ...
flame to form a coating of
copper(II) oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or so ...
. It is then dipped in the sample to be tested and once again heated in a flame. A positive test is indicated by a green flame caused by the formation of a copper halide. The test does not detect fluorine/fluorides.
This test is no longer frequently used. One reason why it is not widely used is that it is possible to generate the highly toxic
chloro-dioxins if the test material is a
polychloroarene.
An alternative wet test for halide is the
sodium fusion test — this test converts organic material to inorganic salts include the sodium halide. Addition of
silver nitrate
Silver nitrate is an inorganic compound with chemical formula . It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called ''lunar causti ...
solution causes any halides to precipitate as the respective silver halide.
References
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Chemical tests