Automotive Thermoelectric Generator
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An automotive thermoelectric generator (ATEG) is a device that converts some of the
waste heat Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utility ...
of an
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal comb ...
(IC) into electricity using the
Seebeck Effect The thermoelectric effect is the direct conversion of temperature differences to electric voltage and vice versa via a thermocouple. A thermoelectric device creates a voltage when there is a different temperature on each side. Conversely, when ...
. A typical ATEG consists of four main elements: A hot-side
heat exchanger A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
, a cold-side heat exchanger,
thermoelectric materials Thermoelectric materials show the thermoelectric effect in a strong or convenient form. The ''thermoelectric effect'' refers to phenomena by which either a temperature difference creates an electric potential or an electric current creates a te ...
, and a compression assembly system. ATEGs can convert waste heat from an engine's coolant or exhaust into electricity. By reclaiming this otherwise lost energy, ATEGs decrease fuel consumed by the electric generator load on the engine. However, the cost of the unit and the extra fuel consumed due to its weight must be also considered.


Operation principles

In ATEGs, thermoelectric materials are packed between the hot-side and the cold-side
heat exchangers A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
. The thermoelectric materials are made up of p-type and n-type semiconductors, while the heat exchangers are metal plates with high
thermal conductivity The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1. Heat transfer occurs at a lower rate in materials of low ...
. The temperature difference between the two surfaces of the thermoelectric module(s) generates electricity using the Seebeck Effect. When hot exhaust from the engine passes through an exhaust ATEG, the
charge carrier In solid state physics, a charge carrier is a particle or quasiparticle that is free to move, carrying an electric charge, especially the particles that carry electric charges in electrical conductors. Examples are electrons, ions and holes. ...
s of the semiconductors within the generator diffuse from the hot-side heat exchanger to the cold-side exchanger. The build-up of charge carriers results in a net charge, producing an
electrostatic potential Electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as electric potential energy per unit of electric charge. More precisely, electric potential is the amount of work needed ...
while the heat transfer drives a current. With exhaust temperatures of 700 °C (≈1300 °F) or more, the temperature difference between
exhaust gas Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through ...
on the hot side and coolant on the cold side is several hundred degrees. This temperature difference is capable of generating 500-750 W of electricity. The compression assembly system aims to decrease the thermal contact resistance between the thermoelectric module and the heat exchanger surfaces. In coolant-based ATEGs, the cold side heat exchanger uses engine coolant as the cooling fluid, while in exhaust-based ATEGs, the cold-side heat exchanger uses ambient air as the cooling fluid.


Efficiency

Currently, ATEGs are about 5% efficient. However, advancements in
thin-film A thin film is a layer of materials ranging from fractions of a nanometer (monolayer) to several micrometers in thickness. The controlled synthesis of materials as thin films (a process referred to as deposition) is a fundamental step in many a ...
and
quantum well A quantum well is a potential well with only discrete energy values. The classic model used to demonstrate a quantum well is to confine particles, which were initially free to move in three dimensions, to two dimensions, by forcing them to occup ...
technologies could increase efficiency up to 15% in the future. The efficiency of an ATEG is governed by the thermoelectric conversion efficiency of the materials and the
thermal efficiency In thermodynamics, the thermal efficiency (\eta_) is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, steam turbine, steam engine, boiler, furnace, refrigerator, ACs etc. For ...
of the two heat exchangers. The ATEG efficiency can be expressed as: : ΖOV = ζCONV х ζHX х ρ Where: * ΖOV : The overall efficiency of the ATEG * ΖCONV : Conversion efficiency of thermoelectric materials * ΖHX: Efficiency of the heat exchangers * Ρ : The ratio between the heat passed through thermoelectric materials to that passed from the hot side to the cold side


Benefits

The primary goal of ATEGs is to reduce fuel consumption and therefore reduce operating costs of a vehicle or help the vehicle comply with
fuel efficiency Fuel efficiency (or fuel economy) is a form of thermal efficiency, meaning the ratio of effort to result of a process that converts chemical energy, chemical potential energy contained in a carrier (fuel) into kinetic energy or Mechanical work, w ...
standards. Forty percent of an IC engine's energy is lost through exhaust gas heat.Yu, C. “Thermoelectric automotive waste heat energy recovery using maximum power point tracking”. Energy Conversion and Management, 2008, VOL 50; page 1506 Implementing ATEGs in diesel engines seems to be more challenging compared to gasoline engines due to lower exhaust temperature and higher mass-flow rates. This is the reason most ATEG development has been focused on gasoline engines. However, there exist several ATEG designs for light-duty and heavy-duty diesel engines. By converting the lost heat into electricity, ATEGs decrease fuel consumption by reducing the electric generator load on the engine. ATEGs allow the automobile to generate electricity from the engine's thermal energy rather than using mechanical energy to power an electric generator. Since the electricity is generated from waste heat that would otherwise be released into the environment, the engine burns less fuel to power the vehicle's electrical components, such as the headlights. Therefore, the automobile releases fewer emissions. Decreased fuel consumption also results in increased fuel economy. Replacing the conventional electric generator with ATEGs could ultimately increase the fuel economy by up to 4%. The ATEG's ability to generate electricity without moving parts is an advantage over mechanical electric generators alternatives. In addition, it has been stated that for low power engine conditions, ATEGs may be able to harvest more net energy than electric turbogenerators.


Challenges

The greatest challenge to the scaling of ATEGs from prototyping to production has been the cost of the underlying thermoelectric materials. Since the early-2000s, many research agencies and institutions poured large sums of money into advancing the efficiency of thermoelectric materials. While efficiency improvements were made in materials such as the half heuslers and
skutterudite Skutterudite is a cobalt arsenide mineral containing variable amounts of nickel and iron substituting for cobalt with the ideal formula CoAs3. Some references give the arsenic a variable formula subscript of 2–3. High nickel varieties are refe ...
s, like their predecessors
bismuth telluride Bismuth telluride () is a gray powder that is a compound of bismuth and tellurium also known as bismuth(III) telluride. It is a semiconductor, which, when alloyed with antimony or selenium, is an efficient thermoelectric material for refrigeration ...
and
lead telluride Lead telluride is a compound of lead (element), lead and tellurium (PbTe). It crystallizes in the NaCl crystal structure with Pb atoms occupying the cation and Te forming the anionic lattice. It is a narrow gap semiconductor with a band gap of 0.3 ...
, the cost of these materials has proven prohibitive for large-scale manufacturing. Recent advances by some researchers and companies in low-cost thermoelectric materials have resulted in significant commercial promise for ATEGs, most notably the low-cost production of
tetrahedrite Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, ...
by
Michigan State University Michigan State University (Michigan State or MSU) is a public university, public Land-grant university, land-grant research university in East Lansing, Michigan, United States. It was founded in 1855 as the Agricultural College of the State o ...
and its commercialization by US-based
Alphabet Energy Alphabet Energy was a startup company founded in 2009 at the University of California, Berkeley by thermoelectrics expert Matthew L. Scullin and Peidong Yang. The company uses nanotechnology and materials science applications to create thermoe ...
with
General Motors General Motors Company (GM) is an American Multinational corporation, multinational Automotive industry, automotive manufacturing company headquartered in Detroit, Michigan, United States. The company is most known for owning and manufacturing f ...
. Like any new component on an automobile, the use of an ATEG presents new engineering problems to consider, as well. However, given an ATEG's relatively low impact on the use of an automobile, its challenges are not as considerable as other new automotive technologies. For instance, since exhaust has to flow through the ATEG's heat exchanger, kinetic energy from the gas is lost, causing increased pumping losses. This is referred to as
back pressure Back pressure (or backpressure) is the term for a resistance to the desired flow of fluid through pipes. Obstructions or tight bends create backpressure via friction loss and pressure drop. In distributed systems in particular event-driven archi ...
, which reduces the engine's performance. This can be accounted for by downsizing the muffler, resulting in zero net or even negative total back-pressure on the engine, as Faurecia and other companies have shown. To make the ATEG's efficiency more consistent, coolant is usually used on the cold-side heat exchanger rather than ambient air so that the temperature difference will be the same on both hot and cold days. This may increase the radiator's size since piping must be extended to the exhaust manifold, and it may add to the radiator's load because there is more heat being transferred to the coolant. Proper thermal design does not require an upsized cooling system. The added weight of ATEGs causes the engine to work harder, resulting in lower gas mileage. Most automotive efficiency improvement studies of ATEGs, however, have resulted in a net positive efficiency gain even when considering the weight of the device.


History

Although the Seebeck effect was discovered in 1821, the use of thermoelectric power generators was restricted mainly to military and space applications until the second half of the twentieth century. This restriction was caused by the low conversion efficiency of thermoelectric materials at that time. In 1963, the first ATEG was built and reported by Neild et al. In 1988, Birkholz et al. published the results of their work in collaboration with
Porsche Dr. Ing. h.c. F. Porsche AG, usually shortened to Porsche (; see below), is a German automobile manufacturer specializing in luxury, high-performance sports cars, SUVs and sedans, headquartered in Stuttgart, Baden-Württemberg, Germany. Th ...
. These results described an exhaust-based ATEG which integrated
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
-based thermoelectric materials between a
carbon steel Carbon steel is a steel with carbon content from about 0.05 up to 2.1 percent by weight. The definition of carbon steel from the American Iron and Steel Institute (AISI) states: * no minimum content is specified or required for chromium, cobalt ...
hot-side heat exchanger and an aluminium cold-side heat exchanger. This ATEG could produce tens of watts out of a
Porsche 944 The Porsche 944 is a sports car manufactured by German automobile manufacturer Porsche from 1982 until 1991. A front-engine, rear-wheel drive mid-level model based on the Porsche 924, 924 Car platform, platform, the 944 was available in coupé o ...
exhaust system. In the early 1990s, Hi-Z Inc designed an ATEG which could produce 1 kW from a diesel truck exhaust system. The company in the following years introduced other designs for diesel trucks as well as military vehicles In the late 1990s,
Nissan Motors is a Japanese multinational automobile manufacturer headquartered in Yokohama, Kanagawa, Japan. The company sells its vehicles under the ''Nissan'' and '' Infiniti'' brands, and formerly the ''Datsun'' brand, with in-house performance tuning ...
published the results of testing its ATEG which utilized SiGe thermoelectric materials. Nissan ATEG produced 35.6 W in testing conditions similar to the running conditions of a 3.0 L gasoline engine in hill-climb mode at 60.0 km/h. Since the early-2000s, nearly every major automaker and exhaust supplier has experimented or studied thermoelectric generators, and companies including General Motors, BMW, Daimler, Ford, Renault, Honda, Toyota, Hyundai, Valeo, Boysen, Faurecia, Tenneco, Denso
Gentherm Inc.
Alphabet Energy, and numerous others have built and tested prototypes. In January 2012, ''
Car and Driver ''Car and Driver'' (''CD'' or ''C/D'') is an American automotive enthusiast magazine first published in 1955. In 2006 its total circulation was 1.23 million. It is owned by Hearst Magazines, who purchased it from its prior owner Hachette Fi ...
'' named an ATEG created by a team led by Amerigon (now
Gentherm Incorporated Gentherm Incorporated, formerly Amerigon, is an American thermal management technologies company. Gentherm created the first thermoelectrically heated and cooled seat system for the automotive industry. Called the "Climate Control Seat" system, ...
) one of the 10 "most promising" technologies.“2012 10Best: 10 Most Promising Future Technologies: Thermal Juice”
''
Car & Driver ''Car and Driver'' (''CD'' or ''C/D'') is an American automotive enthusiast magazine first published in 1955. In 2006 its total circulation was 1.23 million. It is owned by Hearst Magazines, who purchased it from its prior owner Hachette Fil ...
'', December 2011.


External links


Powering Your Car with Waste Heat


References

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