Metal
A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
s used for
architectural purposes include
lead
Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
, for
water pipes,
roofing, and windows;
tin, formed into
tinplate;
zinc
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
,
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
and
aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
, in a range of applications including roofing and decoration; and
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
, which has structural and other uses in the form of
cast iron
Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its car ...
or
wrought iron, or made into
steel
Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...
. Metal
alloy
An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
s used in building include
bronze
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
(mainly copper and tin);
brass
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
(copper and zinc);
monel metal and
nickel silver, mainly consisting of nickel and copper; and
stainless steel
Stainless steel, also known as inox, corrosion-resistant steel (CRES), or rustless steel, is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Stainless steel's resistance to corrosion comes from its chromi ...
, with important components of nickel and
chromium.
Metal types
Lead
The low
melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state of matter, state from solid to liquid. At the melting point the solid and liquid phase (matter), phase exist in Thermodynamic equilib ...
of lead permitted its use on a wide scale throughout human history. Lead was one of the first to be made into sheet metal for architectural purposes.
Water pipes were frequently constructed of lead, until its health hazards were publicised in the late 19th century.
Lead is not subject to rust and has been a popular
roofing material for centuries, being used for roofing, flashing, gutters, downspouts, and conductor heads. Lead was best suited for low-pitched roofs, as steep roofs experienced creep. Lead roofs in regions with large temperature fluctuations, such as the
mid-Atlantic states, experienced deterioration from constant expansion and contraction, called fatigue. Beginning in the 19th century, a roofing material called “
terne” or “terneplate” was used, consisting of sheet iron or sheet steel coated with a lead-tin
alloy
An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
. It is frequently confused with
tinplate.
Lead
came was also frequently used for window panes in skylights and stained glass. It was also used for small pieces of sculpture and garden ornamentation. Lead was frequently added to paint, with red lead used as an anti-corrosive pigment for iron, and white lead used as paint for wooden houses.
Lead-based paint was one of the most durable materials developed as a protective exterior coating. The use of lead paint has been restricted on most buildings, due to concerns of
lead poisoning
Lead poisoning, also known as plumbism and saturnism, is a type of metal poisoning caused by lead in the body. Symptoms may include abdominal pain, constipation, headaches, irritability, memory problems, infertility, numbness and paresthesia, t ...
.
Tin
Tin is too soft to be used by itself for architectural purposes so it generally falls into two categories: the alloying of tin with other metals such as
copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
to form
bronze
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
, and the coating of tin on harder metals, such as tinplated iron or steel. Architectural bronzes usually contain about 90% copper and 10% tin, although the content may vary widely. The term “
tin ceiling” is a misnomer and early manufacturers did not use the name. However, persons who worked with sheet metal were called tinsmiths, so the term could have sprung from this title.
Tinplate was a type of architectural material consisting of sheet iron or steel coated with tin. “Tin roofs,” a type of tinplate, was originally used for armor but eventually as a roofing material. Tinplate was also used for decoration, such as ornamental windows, door lintels and
tin ceilings. Ornamental stamped metal made from tinplate was an affordable alternative to
plasterwork
Plasterwork is construction or ornamentation done with plaster, such as a layer of plaster on an interior or exterior wall structure, or plaster Molding (decorative), decorative moldings on ceilings or walls. This is also sometimes called parge ...
. Although tinplate is still available today for ceilings, roofing and flashing, it is generally considered expensive since the initial cost is more than that for common modern roofing types such as
asphalt shingles or built-up roofs. A well-maintained tinplate roof or ceiling typically lasts several times longer than modern materials, and is more economical when the longer lifespan is taken into account.
Zinc
Pure
zinc
Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
was used for roofing in Belgium, France and Germany, where it replaced more expensive copper and lead in roofing. Starting in the 1820s, Belgian sheet zinc was imported in America, used by builders in New York City and elsewhere. Pure zinc is subject to creep at ordinary temperatures.
Zinc-coated metals were first
patented in 1837, separately by M. Sorel in France and H. W. Crawford in England. The methods employed a “hot dipping” process to coat sheet iron with zinc. By 1839 “galvanized” sheet iron roofing was being used in New York City. The Merchant's Exchange in Manhattan was one of the first buildings to have both a galvanized roof and galvanized gutters. Some galvanized sheet roofing was pressed with designs, a popular technique in the Victorian era.
Zinc was also cast for sculptures and decorative elements in Germany and Austria as early as 1832. Decorative architectural elements were frequently cast in zinc, since it molded readily, was inexpensive compared to stone, and could be painted to imitate more expensive metals. Stamped swags, rosettes,
fleur-de-lis
The ''fleur-de-lis'', also spelled ''fleur-de-lys'' (plural ''fleurs-de-lis'' or ''fleurs-de-lys''), is a common heraldic charge in the (stylized) shape of a lily (in French, and mean and respectively). Most notably, the ''fleur-de-lis'' ...
and acanthus leaves provided popular decorative ornamentation of both exteriors and interiors by the late 19th century.
Zinc oxide
Zinc oxide is an inorganic compound with the Chemical formula, formula . It is a white powder which is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, Zinc metabolism, food supplements, rubbe ...
paints were nontoxic and resistant to
pollution
Pollution is the introduction of contaminants into the natural environment that cause harm. Pollution can take the form of any substance (solid, liquid, or gas) or energy (such as radioactivity, heat, sound, or light). Pollutants, the component ...
. They became commercially successful and readily available in America in about 1850 and used widely starting around the 1870s. They had the added benefit of being good rust inhibitors on iron and steel.
During the early decades of the 20th century, the use of pure zinc roofing and ornament decreased in use in the US. It is now gaining popularity in its pure form (99.95%)for building materials. Typically, architectural grade zinc is 99.995 percent pure zinc with trace amounts of titanium, to reduce coefficient of thermal expansion and improve tensile strength and hardness, and copper to improve workability. Exact alloy composition is subject to manufacturer and is a color determinant in zinc's final
patina. Over time, zinc develops its distinctive patina, transforming from a shiny silver to a matte bluish-grey. Pre patinated finishes are available from certain manufacturers to expedite the natural patination process. Applying a clear protective coating to brass surfaces can inhibit oxidation and reduce the rate of patina development, helping to maintain the original appearance. Zinc is still used in alloys such as
brass
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
and
nickel silver, and in the
electroplating
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the redox, reduction of cations of that metal by means of a direct current, direct electric cur ...
of steel as well. Today,
galvanized steel and pure zinc material, usually Double Locked Standing Seam panels, are used for roofing a variety of buildings. Creep has been reduced by the introduction of
titanium in most architectural zinc available in North America. Galvanized nails and sheet metal ducts are also common.
Architectural grade zinc is 90 to 95% recycled. Replacement costs are negligible with a long lifetime of 80 to 100 years for zinc roofing and 200 to 300 years for wall systems. This long-life durability is a key component in durability. At the end of its service life, zinc building products can be recycled indefinitely without loss to chemical or physical properties. The use of architectural grade zinc can help building qualify for
LEED certification due to its high recycled content and sustainability.
Copper and its alloys
Copper
Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
is a very durable metal, withstanding
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
when forming a bluish-green
patina that variably consists of copper
carbonates,
sulfates
The sulfate or sulphate ion is a Polyatomic ion, polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salt (chemistry), ...
,
sulfides, and
chloride
The term chloride refers to a compound or molecule that contains either a chlorine anion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). The pr ...
s. Sheet copper used as roofing is lighter than wooden shingles and much lighter than slate, tile, or lead. Roofing copper can be folded readily into waterproof seams, or shaped over curved frameworks for
cupolas and domes.
The initial cost of copper was traditionally high, but its length of service more than compensated for the price. Copper could also be shaped to the bends and angles around chimneys and at roof edges and dormers. All nails, screws, bolts, and cleats used with sheet copper must be made of copper or a copper alloy, otherwise galvanic action between the dissimilar metals would occur, causing deterioration.
Copper was also used for decorative purposes, including architectural ornaments, siding, ceilings or sculptures. One famous example is the
Statue of Liberty
The Statue of Liberty (''Liberty Enlightening the World''; ) is a colossal neoclassical sculpture on Liberty Island in New York Harbor, within New York City. The copper-clad statue, a gift to the United States from the people of French Thir ...
.
Copper alloys used in architecture include
bronze
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
, an alloy of copper and tin, and
brass
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
, an alloy of copper and zinc.
Nickel and its alloys
Although somewhat rare,
nickel has been used for plating architectural details. Nickel is most frequently used for building components in the form of alloys:
nickel silver,
Monel metal, and
stainless steel
Stainless steel, also known as inox, corrosion-resistant steel (CRES), or rustless steel, is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Stainless steel's resistance to corrosion comes from its chromi ...
.
Nickel silver was originally called “German Silver,” until World War I. It has been called “white brass” but probably should be termed “nickel brass,” because it generally contains 75% copper, 20% nickel, and 5% zinc. Different percentages result in a range of colors, including silvery-white, yellow, slight blue, green or pink. Nickel silver hardware was popular in the US during the
Art Deco
Art Deco, short for the French (), is a style of visual arts, architecture, and product design that first Art Deco in Paris, appeared in Paris in the 1910s just before World War I and flourished in the United States and Europe during the 1920 ...
and Depression Modern periods. Architects and designers preferred nickel silver because it could take and retain appropriate finishes, and it resisted corrosion.
Monel metal is an alloy of approximately two-thirds nickel and one-third copper. It is similar to platinum in color. Monel pioneered many of the present uses of stainless steel. The first architectural use of Monel was for roofing the
Pennsylvania Railroad Terminal in New York City in 1909. In 1936, the copper roof on the
New York City Public Library at Fifth Avenue and 42nd Street was replaced with a Monel metal roof. Its advantages as a roofing material included its ability to be brazed, welded, or soldered in place to provide a watertight, continuous cover. Monel was popular during the Art Deco periods. During World War II large quantities of nickel and copper were diverted to the war effort, and the supply of Monel was greatly reduced. Following the war, stainless steel and aluminium replaced Monel because of lower production costs.
Iron and its alloys
Iron has become an important architectural building component. It has been used in four common forms: wrought iron, cast iron, sheet iron, and steel.
Wrought iron was used for minor structural and decorative elements starting in the 18th century. Until the mid-19th century, the use of wrought iron in buildings was generally limited to small items such as tie rods, straps, nails, and hardware, or to decorative ironwork in balconies, railings fences and gates. Around 1850 its structural use became more widespread as iron mills began to roll rails, bulb-tees, and eventually I-beams. It was also used for decorative purposes, such as ornamental balconies or hardware. Since wrought iron is handmade, no two pieces are identical.
Cast iron
Cast iron is a class of iron–carbon alloys with a carbon content of more than 2% and silicon content around 1–3%. Its usefulness derives from its relatively low melting temperature. The alloying elements determine the form in which its car ...
was a major 19th century building material of the
Industrial Revolution
The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...
. Although brittle, it is remarkably strong in compression. It was frequently used for structural purposes, such as columns, building fronts, domes and light courts. Decorative uses have included stairs, elevators, lintels, grilles, verandas, balconies, railings, fences, streetlights, and tombs. The
Bradbury Building is an example of extensive decorative cast iron. Today, cast iron is used for plumbing fixtures and piping in new construction, and its structural and decorative use is used occasionally through historic preservation practices.
Sheet iron can be subject to rapid corrosion, forming rust. Sheet iron was used throughout the 19th century, although it is not clear how widespread sheet iron roofs became. Pressed decorative sheet iron used for ceilings was frequently called a “
tin ceiling,” which was actually sheets of iron dipped in molten tin to prevent them from rusting.
Steel
Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...
was introduced to the construction industry at the end of the 19th century. The development of structural steel in the mid-19th century allowed construction of tall buildings. Builders and manufacturers turned to steel, which was stronger than cast iron in compression and wrought iron in tension. When the
Bessemer process
The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is steelmaking, removal of impurities and undesired eleme ...
was developed in England in 1856, and the open-hearth process was invented, steel was produced in a quantity that allowed it to be economical. Bridges, railroad companies, and skyscrapers were among the first large-scale uses of structural steel. Although iron and steel are not combustible, they lose strength in a fire if they are not protected from the heat. Almost all structural steel must be “fireproofed” in some manner, utilizing a cladding of
terra-cotta, tile, plaster-poured concrete, sprayed concrete, or sprayed
insulation. Ferro concrete, also called
reinforced concrete
Reinforced concrete, also called ferroconcrete or ferro-concrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ...
, was developed in the late 19th century when steel wire was added to concrete.
Decorative steels used in buildings include:
*
Stainless steel
Stainless steel, also known as inox, corrosion-resistant steel (CRES), or rustless steel, is an iron-based alloy that contains chromium, making it resistant to rust and corrosion. Stainless steel's resistance to corrosion comes from its chromi ...
, a chromium-nickel steel, developed between 1903 and 1912. Its most important property is its resistance to corrosion. It contains about 18% chromium and 8-12% nickel. Stainless steel is expensive, so it was used primarily as a nonstructural metal or where there is a high potential for corrosion. One of the most extensive early uses of stainless steel was in the
Chrysler Building.
* Copper-bearing steels, containing from .15% to .25% copper, develop increased resistance to atmospheric corrosion, when compared to ordinary steel, by forming a protective oxide coating, having a uniform deep brown color and texture.
Eero Saarinen experimented with the material in the
John Deere
Deere & Company, Trade name, doing business as John Deere (), is an American corporation that manufactures agricultural machinery, heavy equipment, forestry machinery, diesel engines, drivetrains (axles, Transmission (mechanical device), transmi ...
building in 1964.
Aluminium
Much like copper,
Aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
is highly resistant to
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
. It also has the added benefit of being a third lighter than steel with comparable strength. Aluminium can also be easily and repeatedly recycled. It has been estimated that of the estimated 900 million tonnes of aluminium produced since 1880, three quarters is still in productive use, 35% of which is in building construction.
Aluminium
Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...
was unavailable at reasonable cost or in sufficient quantities for general architectural use until after the beginning of the 20th century. Architectural use of aluminum increased in the 1920s, mainly for decorative detailing. It was used for roofing, flashing, gutters, downspouts, wall panels, and spandrels. Art Deco designs frequently used aluminum for ornamental features. The first extensive use of aluminum in construction was the
Empire State Building
The Empire State Building is a 102-story, Art Deco-style supertall skyscraper in the Midtown South neighborhood of Manhattan, New York City, United States. The building was designed by Shreve, Lamb & Harmon and built from 1930 to 1931. Its n ...
, where the entire tower portion is aluminum, as well as many decorative features, such as the entrances, elevator doors, ornamental trim, and some 6,000 window
spandrels. Today, aluminum is used frequently in construction except major structural members.
[Gayle & Waite (1980), pp 84-88.]
See also
*
Building materials
References
{{reflist
Sources
* Gayle, Margot and Waite, John G. (1980), ''Metals in America's Historic Buildings: Uses and Preservation Treatments'', Washington: U.S. Dept. of the Interior, Heritage Conservation and Recreation.
Architectural history
Building materials
Construction
Metalworking
Sculpture materials