Arakiite
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Arakiite (
IMA IMA or Ima may refer to: Education * Indian Military Academy, Dehradun * Instituto Miguel Ángel, a school in Mexico City Galleries and museums * Indianapolis Museum of Art, Indiana, US * Institut du Monde Arabe, Paris, France * Islamic Mus ...
symbol A symbol is a mark, Sign (semiotics), sign, or word that indicates, signifies, or is understood as representing an idea, physical object, object, or wikt:relationship, relationship. Symbols allow people to go beyond what is known or seen by cr ...
: Ark) is a rare mineral with the formula (Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As3+O3)(As5+O4)2(OH)23. It is both
arsenate The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. The four oxygen atoms orien ...
and
arsenite In chemistry, an arsenite is a chemical compound containing an arsenic oxyanion where arsenic has oxidation state +3. Note that in fields that commonly deal with groundwater chemistry, arsenite is used generically to identify soluble AsIII anions ...
mineral, a combination that is rare in the world of minerals. Arakiite is stoichiometrically similar to hematolite. It is one of many rare minerals coming from the famous
Långban Långban is a mining area in Värmland in Sweden. It belongs to Filipstad Municipality, with the nearest city being Filipstad, 21 km south. It was systematically mined through 1711–1972, but has traces from the 15th century. It is the birt ...
manganese
skarn Skarns or tactites are coarse-grained metamorphic rocks that form by replacement of carbonate-bearing rocks during regional or contact metamorphism and metasomatism. Skarns may form by metamorphic recrystallization of impure carbonate protoliths, ...
deposit in Sweden. Other minerals bearing both arsenite and zinc include kraisslite and mcgovernite. The mineral crystallizes in the
monoclinic crystal system In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic sy ...
in space group ''Cc''.


References

Zinc minerals Manganese(II) minerals Iron(III) minerals Arsenate minerals Monoclinic minerals Minerals in space group 9 Minerals described in 2000 {{mineral-stub