Aphthitalite is a potassium sulfate mineral with the chemical formula: (K,Na)₃Na(SO₄)₂. It was first described in 1835 for an occurrence on

Mount Vesuvius Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma- stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the shore. It is one of ...

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...

. The name is from the Greek άφθητος, "unalterable", and άλας, "salt", for its stability in air. It occurs as

fumarolic A fumarole (or fumerole) is a vent in the surface of the Earth or other rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcani ...

incrustations in volcanic environments, as small crystals and masses in

evaporite An evaporite () is a water- soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as oce ...

deposits and in

guano Guano (Spanish from qu, wanu) is the accumulated excrement of Seabird, seabirds or bats. As a manure, guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant ...

deposits. It occurs associated with thenardite,

jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct dur ...

sylvite Sylvite, or sylvine, is potassium chloride (KCl) in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite ( NaCl). The two are, in fact, isomorphous. Sylvite is colorless to white with shades of ...

and

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of ...

in fumaroles; with blodite, syngenite, mirabilite, picromerite,

borax Borax is a salt (chemistry), salt (ionic compound), a hydration (chemistry), hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a base (chemistry), basic aqueo ...

and

halite Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, ...

in evaporites; and with syngenite, whitlockite, monetite,

niter Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits. Historically, the term ''niter'' was not well differentiated from natron, both of w ...

and

gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and dr ...

in guano deposits.

References

Sulfate minerals Potassium minerals Sodium minerals Trigonal minerals Minerals in space group 164 {{sulfate-mineral-stub