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Anthodites (
Greek Greek may refer to: Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group *Greek language, a branch of the Indo-European language family **Proto-Greek language, the assumed last common ancestor of all kno ...
ἄνθος ''ánthos'', "flower", ''-ode'', adjectival combining form, ''-ite'' adjectival suffix) are
speleothem A speleothem (; ) is a geological formation made by mineral deposits that accumulate over time in natural caves. Speleothems most commonly form in calcareous caves due to carbonate dissolution reactions. They can take a variety of forms, depen ...
s (cave formations) composed of long needle-like crystals situated in clusters which radiate outward from a common base. The "needles" may be quill-like or feathery. Most anthodites are made of the mineral
aragonite Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation fr ...
(a variety of
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
, CaCO3), although some are composed of
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate Hydrate, dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk ...
(CaSO4·2H2O). The term ''anthodite'' is first cited in the scientific literature in 1965 by Japanese researcher N. Kashima, who described "flower-like dripstone" composed of "an alternation of calcite and aragonite".


Structure, composition and appearance

The individual crystals of anthodites develop in a form described as "acicular" (needle-like) and often branch out as they grow. They usually grow downward from a cave's ceiling. Aragonite crystals are contrasted with those made of calcite (another variety of calcium carbonate) in that the latter tend to be stubby or dog-tooth-like ("rhombohedral", rather than acicular). Anthodites often have a solid core of aragonite and may have
huntite Huntite is a carbonate mineral with the chemical formula Mg3Ca(CO3)4. Huntite crystallizes in the trigonal system and typically occurs as platy crystals and powdery masses. For most of recorded history its main use was as a white pigment. Today ...
or
hydromagnesite Hydromagnesite is a hydrated magnesium carbonate mineral with the formula . It generally occurs associated with the weathering products of magnesium containing minerals such as serpentine group, serpentine or brucite. It occurs as incrustations a ...
deposited near the ends of the branches. Anthodite crystals vary in size from less than a millimeter to about a meter, but are commonly between 1 and 20 millimeters in length.


Occurrence

Anthodites may occur sporadically throughout some limestone caves, but may be spectacularly abundant in others, with clean white crystals growing all over the calcite or other rock surfaces. Examples of sites with abundant anthodite displays include Carlsbad Caverns, Craighead Caverns,
Skyline Caverns Skyline Caverns is a series of geologic caves and a tourist attraction located in Warren County, Virginia, south of Front Royal, Virginia, Front Royal. The caverns were discovered by Walter S. Amos, a retired geologist and mineralogist from Winc ...
in the United States and the Grotte de Moulis in France. Anthodites can also be found in the National Monument of Timpanogos Cave, American Fork, Utah.


Types

Among the "quill-like" varieties of anthodite is sometimes included the "sea urchin-like" formation known as '' flos ferri'', although othersShaw, T. (1992), ''History of Cave Science: The Exploration and Study of Limestone Caves to 1900'', 2nd ed., Sydney Speleological Society, Broadway, NSW, Australia. have considered them a slender variety of
helictite A helictite is a speleothem (cave-formed mineral) found in a Solution cave, limestone cave that changes its axis from the vertical at one or more stages during its growth. Helictites have a curving or angular form that looks as if they were gro ...
. Among the "feathery" varieties of anthodite is "
frostwork In geology, frostwork is a type of speleothem with acicular ("needle-like") growths almost always composed of aragonite (a polymorph of calcite) or calcite replaced aragonite.Hill, C. and Forti, P. (1997), ''Cave Minerals of the World'', Nationa ...
", a type of speleothem consisting of "bushes" of fine acicular aragonite crystals in radiating clusters. Their appearance is often compared to that of a cactus or thistle plant. In its composite
stalagmite A stalagmite (, ; ; ) is a type of rock formation that rises from the floor of a cave due to the accumulation of material deposited on the floor from ceiling drippings. Stalagmites are typically composed of calcium carbonate, but may consist ...
form, frostwork may possess spiny limbs like a miniature fir tree. The term was first used by cave guides at
Wind Cave Wind Cave National Park is a national park of the United States located north of the town of Hot Springs in western South Dakota. Established on January 3, 1903 by President Theodore Roosevelt, it was the sixth national park in the U.S. and t ...
in South Dakota, USA, during the 1890s to describe speleothems which looked like ice "frostwork".


Anthodite-like formations

*
Helictite A helictite is a speleothem (cave-formed mineral) found in a Solution cave, limestone cave that changes its axis from the vertical at one or more stages during its growth. Helictites have a curving or angular form that looks as if they were gro ...
s are curved or angular twig-like lateral projections of
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
, which appear to defy gravity. Rather than radial clusters, helictites often occur in tangled masses. The "twigs" have a tiny central canal. * Cave flowers (also known as "gypsum flowers" or "oulopholites") consist of gypsum or
epsomite Epsomite, Epsom salt, or magnesium sulfate heptahydrate, is a hydrous magnesium sulfate mineral with formula . Physical properties Epsomite crystallizes in the orthorhombic system. The normal form is as massive encrustations, while acicula ...
. In contrast to anthodites, the needles or "petals" of cave flowers grow from the attached end. *
Cave cotton Caves or caverns are natural voids under the Earth's Planetary surface, surface. Caves often form by the weathering of rock and often extend deep underground. Exogene caves are smaller openings that extend a relatively short distance undergrou ...
(also called "gypsum cotton") is very thin, flexible filaments of gypsum or epsomite projecting from a cave wall.


References

Speleothems