Anorthite
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Anorthite (< ''an'' 'not' + ''ortho'' 'straight') is the
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
endmember An endmember (also end-member or end member) in mineralogy is a mineral that is at the extreme end of a mineral series in terms of purity of its chemical composition. Minerals often can be described as solid solutions with varying compositions of ...
of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is Ca Al2 Si2O8. Anorthite is found in
igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
s.


Mineralogy

Anorthite is the calcium-rich endmember of the plagioclase
solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...
series, the other endmember being
albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...
(NaAlSi3O8). Pure anorthite, containing no sodium, is rare on Earth. Anorthite also refers, however, to plagioclase compositions with more than 90 molecular percent of the anorthite endmember (and up to 10 molecular percent of the albite endmember). The composition of plagioclases is often expressed as a molar percentage of An%, or (for a specific quantity) Ann, where n = Ca/(Ca + Na) × 100. This equation predominantly works in a terrestrial context; exotic locales and in particular Lunar rocks may need to account for other cations, such as Fe2+, to explain differences between optically and structurally derived An% data observed in Lunar anorthites. At standard pressure, pure anorthite (An100) melts at 1550 ± 2 °C (2822 °F).


Occurrence

Anorthite is a compositional variety of plagioclase. It occurs in mafic
igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...
. It also occurs in metamorphic rocks of granulite facies, in metamorphosed
carbonate rock Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and Dolomite (rock), dolomite rock (also kn ...
s, and corundum deposits. Its type localities are Monte Somma and Valle di Fassa,
Italy Italy, officially the Italian Republic, is a country in Southern Europe, Southern and Western Europe, Western Europe. It consists of Italian Peninsula, a peninsula that extends into the Mediterranean Sea, with the Alps on its northern land b ...
. It was first described in 1823. It is more rare in surficial rocks than it normally would be due to its high weathering potential in the Goldich dissolution series. It also makes up much of the lunar highlands; the
Genesis Rock The Genesis Rock (sample 15415) is a sample of Moon rock retrieved by Apollo 15 astronauts James Irwin and David Scott in 1971 during the second lunar extravehicular activity, EVA, at Spur (lunar crater), Spur crater on Earth's Moon. With a mass ...
, collected during the 1971
Apollo 15 Apollo 15 (July 26August 7, 1971) was the ninth crewed mission in the Apollo program and the fourth Moon landing. It was the first List of Apollo missions#Alphabetical mission types, J mission, with a longer stay on the Moon and a greate ...
mission, is made of
anorthosite Anorthosite () is a phaneritic, intrusive rock, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic ...
, a rock composed largely of anorthite. Anorthite was discovered in samples from
comet A comet is an icy, small Solar System body that warms and begins to release gases when passing close to the Sun, a process called outgassing. This produces an extended, gravitationally unbound atmosphere or Coma (cometary), coma surrounding ...
Wild 2, and the mineral is an important constituent of Ca-Al-rich inclusions in rare varieties of chondritic meteorites.


See also

* List of minerals * Lunar highlands * Lunar regolith


References

{{Reflist Tectosilicates Calcium minerals Feldspar Triclinic minerals Gemstones Minerals in space group 2