Ammonium tetrathiotungstate is a
chemical compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
with the chemical formula .
Synthesis
Ammonium tetrathiotungstate can be obtained by the reaction of
tungstic acid
Tungstic acid refers to hydrated forms of tungsten trioxide, WO3. Both a monohydrate (WO3·H2O) and hemihydrate (WO3·1/2 H2O) are known. Molecular species akin to sulfuric acid, i.e. (HO)2WO2 are not observed.
The solid-state structure of ...
,
ammonia
Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...
, and
hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
in a water bath at 65-70°C:
::
Physical properties
Ammonium tetrathiotungstate forms yellow to orange crystals, soluble in water.
The compound decomposes under heat to produce
tungsten trisulfide at 170-280°C and
tungsten disulfide
Tungsten disulfide is an inorganic chemical compound composed of tungsten and sulfur with the chemical formula WS2. This compound is part of the group of materials called the transition metal dichalcogenides. It occurs naturally as the rare miner ...
at 260-500°C.
Uses
The compound is used in materials science and
catalysis
Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quick ...
.
References
{{ammonium salts
Ammonium compounds
Tungstates
Sulfur compounds