Ammonium pertechnetate is a chemical compound with the formula NH
4TcO
4. It is the ammonium salt of
pertechnetic acid. The most common form uses
99Tc.
The compound is readily soluble in aqueous solutions forming
ammonium
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternar ...
and
pertechnetate
The pertechnetate ion () is an oxyanion with the chemical formula . It is often used as a convenient water-soluble source of isotopes of the radioactive element technetium (Tc). In particular it is used to carry the 99mTc isotope (half-life 6 hou ...
ions.
It can be synthesized by the reaction of
pertechnetic acid and
ammonium nitrate
Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It ...
:
:HTcO
4 + NH
4NO
3 → NH
4TcO
4 + HNO
3
It thermally decomposes under inert atmosphere at 700 °C to
technetium dioxide:
:NH
4TcO
4 → TcO
2 + 2 H
2O + 1/2 N
2
References
{{Technetium compounds
Pertechnetates