Aluminium telluride is an

inorganic An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inor ...

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

aluminium Aluminium (or aluminum in North American English) is a chemical element; it has chemical symbol, symbol Al and atomic number 13. It has a density lower than that of other common metals, about one-third that of steel. Aluminium has ...

and

tellurium Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally fou ...

with the

chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ...

Al₂Te₃.

Preparation

Aluminium telluride can be obtained by direct combination of aluminium metal with elemental tellurium at . :

Properties

Aluminium telluride is a very air-sensitive dark grey to black solid. It has a

band gap In solid-state physics and solid-state chemistry, a band gap, also called a bandgap or energy gap, is an energy range in a solid where no electronic states exist. In graphs of the electronic band structure of solids, the band gap refers to t ...

of 2.4 eV. The compound decomposes in humid air. In its pure form, it occurs in at least two phases. The orange-red low-temperature (α) modification transforms into the yellow high-temperature (β) form at . The conversion from β- to α-Al₂Te₃, which is associated with such a small enthalpy change that it cannot be observed with

differential thermal analysis Differential thermal analysis (DTA) is a thermoanalytic technique that is similar to differential scanning calorimetry. In DTA, the material under study and an inert reference are made to undergo identical thermal cycles, (i.e., same cooling or ...

, takes place after prolonged annealing just below the conversion point. The α form crystallizes in the

monoclinic crystal system In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic sy ...

with the lattice constants a = 13.885 Å, b = 7.189 Å, c = 4.246 Å, p = 90.21° and an additional

superstructure A superstructure is an upward extension of an existing structure above a baseline. This term is applied to various kinds of physical structures such as buildings, bridges, or ships. Aboard ships and large boats On water craft, the superstruct ...

. The β form has a monoclinic crystal structure with

space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...

P2₁/c and the lattice constants a = 7.181(1) Å, b = 12.848(3) Å, c = 14.167(3) Å, and b= 90.04(2)°. This form represents a separate structure type. The tellurium atoms form a hexagonal dense packing parallel to the (001) plane; one-third of the tetrahedral vacancies are occupied by aluminium atoms, whereby the tetrahedral vacancies are occupied in such a way that a layered structure is formed. Some sources also report another form of the defect

wurtzite Wurtzite is a zinc and iron sulfide mineral with the chemical formula , a less frequently encountered Polymorphism (materials science), structural polymorph form of sphalerite. The iron content is variable up to eight percent.Palache, Charles, H ...

type.

Uses

Aluminium telluride is used in the

semiconductor industry The semiconductor industry is the aggregate of companies engaged in the design and fabrication of semiconductors and semiconductor devices, such as transistors and integrated circuits. Its roots can be traced to the invention of the transistor ...

. It can also be used to produce hydrogen telluride by reacting with

hydrogen chloride The Chemical compound, compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hyd ...

. :

References

{{Tellurides Aluminium compounds Tellurides