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Nickel silver, maillechort, German silver, argentan, new silver, nickel brass, albata, or alpacca is a
cupronickel Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other metals added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent. ( Monel is a n ...
(
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
with
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
)
alloy An alloy is a mixture of chemical elements of which in most cases at least one is a metal, metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Metallic alloys often have prop ...
with the addition of
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the element
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
. It is named for its silvery appearance, which can make it attractive as a cheaper and more durable substitute. It is also well suited for being
plated Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderab ...
with silver. A naturally occurring ore composition in China was smelted into the alloy known as or () ('white copper' or
cupronickel Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other metals added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent. ( Monel is a n ...
). The name ''German Silver'' refers to the artificial recreation of the natural ore composition by German metallurgists. All modern, commercially important, nickel silvers (such as those standardized under
ASTM ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and s ...
B122) contain zinc and are sometimes considered a subset of
brass Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally copper and zinc. I ...
.


History

Nickel silver was first used in
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
, where it was
smelted Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead and zinc. Sm ...
from readily available unprocessed ore. During the
Qing dynasty The Qing dynasty ( ), officially the Great Qing, was a Manchu-led Dynasties of China, imperial dynasty of China and an early modern empire in East Asia. The last imperial dynasty in Chinese history, the Qing dynasty was preceded by the ...
, it was "smuggled into various parts of the
East Indies The East Indies (or simply the Indies) is a term used in historical narratives of the Age of Discovery. The ''Indies'' broadly referred to various lands in Eastern world, the East or the Eastern Hemisphere, particularly the islands and mainl ...
", despite a government ban on the export of nickel silver. It became known in the West from imported wares called (
Mandarin Mandarin or The Mandarin may refer to: Language * Mandarin Chinese, branch of Chinese originally spoken in northern parts of the country ** Standard Chinese or Modern Standard Mandarin, the official language of China ** Taiwanese Mandarin, Stand ...
) or (
Cantonese Cantonese is the traditional prestige variety of Yue Chinese, a Sinitic language belonging to the Sino-Tibetan language family. It originated in the city of Guangzhou (formerly known as Canton) and its surrounding Pearl River Delta. While th ...
) (
Radical 106 or radical white () meaning "white" is one of the 23 Kangxi radicals (214 radicals in total) composed of 5 strokes. In the ''Kangxi Dictionary'', there are 109 characters (out of 49,030) to be found under this radical. is also the ...
, literally "white copper"), for which the silvery metal colour was used to imitate
sterling silver Sterling silver is an alloy composed mass fraction (chemistry), by weight of 92.5% silver and 7.5% other metals, usually copper. The sterling silver silver standards, standard has a minimum millesimal fineness of 925. ''Fineness, Fine silver'' ...
. According to
Berthold Laufer Berthold Laufer (October 11, 1874 – September 13, 1934) was a German anthropologist and historical geographer with an expertise in East Asian languages. The American Museum of Natural History calls him "one of the most distinguished sinologists ...
, it was identical to ''khar sini'', one of the seven metals recognized by
Jābir ibn Hayyān Jabir (Arabic: جابر ) is an Arabic surname or male given name, which means "comforter".''Behind The Name''"Jabir" Retrieved on 8 January 2016. Alternative spellings include Djābir, Jaber, Jābir, Gabir, and Geber. The name may refer to: Giv ...
. In Europe, consequently, it was at first called , which is about the way is pronounced in the Cantonese dialect. The earliest European mention of occurs in the year 1597. From then until the end of the eighteenth century there are references to it as having been exported from Canton to Europe. German artificial recreation of the natural ore composition, however, began to appear from about 1750 onward. In 1770, the
Suhl Suhl () is a city in Thuringia, Germany, located SW of Erfurt, NE of Würzburg and N of Nuremberg. With its 37,000 inhabitants, it is the smallest of the six urban districts within Thuringia. Together with its northern neighbour-town Zella ...
metalworks were able to produce a similar alloy. In 1823, a German competition was held to perfect the production process: the goal was to develop an alloy that possessed the closest visual similarity to silver. The brothers Henniger in
Berlin Berlin ( ; ) is the Capital of Germany, capital and largest city of Germany, by both area and List of cities in Germany by population, population. With 3.7 million inhabitants, it has the List of cities in the European Union by population withi ...
and
Ernst August Geitner Ernst is both a surname and a given name, the German, Dutch, and Scandinavian form of Ernest. Notable people with the name include: Surname * Adolf Ernst (1832–1899) German botanist known by the author abbreviation "Ernst" * Anton Ernst (born ...
in Schneeberg independently achieved this goal. The manufacturer Berndorf (founded in 1843) named the trademark brand ''Alpacca'', which became widely known in northern Europe for nickel silver. In 1830, the German process of manufacture was introduced into England, while exports of from China gradually stopped. In 1832, a form of German silver was also developed in
Birmingham, England Birmingham ( ) is a city and metropolitan borough in the metropolitan county of West Midlands, within the wider West Midlands region, in England. It is the largest local authority district in England by population and the second-largest cit ...
. After the modern process for the production of electroplated nickel silver was patented in 1840 by
George Richards Elkington George Richards Elkington (17 October 1801 – 22 September 1865) was a manufacturer from Birmingham, England. He patented the first commercial electroplating process. Biography Elkington was born in Birmingham, the son of a spectacle manuf ...
and his cousin Henry Elkington in Birmingham, the development of electroplating caused nickel silver to become widely used. It formed an ideal, strong and bright substrate for the plating process. It was also used unplated in applications such as cutlery.


Uses

Nickel silver first became popular as a base metal for silver-plated
cutlery Cutlery (also referred to as silverware, flatware, or tableware) includes any hand implement used in preparing, serving, and especially eating food in Western culture. A person who makes or sells cutlery is called a cutler. While most cutlers ...
and other silverware, notably the
electroplate Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be ...
d wares called EPNS (electroplated nickel silver). It is used in
zippers A zipper (N. America), zip, zip fastener (UK), formerly known as a clasp locker, is a commonly used device for binding together two edges of fabric or other flexible material. Used in clothing (e.g. jackets and jeans), luggage and other bags, ...
, costume
jewelry Jewellery (or jewelry in American English) consists of decorative items worn for personal adornment such as brooches, ring (jewellery), rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the ...
, for making musical instruments (e.g.,
flutes The flute is a member of a family of musical instruments in the woodwind group. Like all woodwinds, flutes are aerophones, producing sound with a vibrating column of air. Flutes produce sound when the player's air flows across an opening. In th ...
,
clarinet The clarinet is a Single-reed instrument, single-reed musical instrument in the woodwind family, with a nearly cylindrical bore (wind instruments), bore and a flared bell. Clarinets comprise a Family (musical instruments), family of instrume ...
s), and is preferred for the track in electric
model railway Railway modelling (UK, Australia, New Zealand, and Ireland) or model railroading (US and Canada) is a hobby in which rail transport systems are Model building, modelled at a reduced Scale (ratio), scale. The scale models include locomotives ...
layouts, as its
oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...
is conductive. Better quality
keys Key, Keys, The Key or The Keys may refer to: Common uses * Key (cryptography), a piece of information needed to encode or decode a message * Key (instrument), a component of a musical instrument * Key (lock), a device used to operate a lock * ...
and lock cylinder pins are made of nickel silver for durability under heavy use. The alloy has been widely used in the production of
coin A coin is a small object, usually round and flat, used primarily as a medium of exchange or legal tender. They are standardized in weight, and produced in large quantities at a mint in order to facilitate trade. They are most often issued by ...
s (e.g.
Portuguese escudo The Portuguese escudo (, ) was the currency of Portugal replacing the ''real'' on 22 May 1911 and was in use until the introduction of the euro on 1 January 2002. The escudo was subdivided into 100 . The word literally means shield; like other ...
and the former
GDR East Germany, officially known as the German Democratic Republic (GDR), was a country in Central Europe from its formation on 7 October 1949 until its reunification with West Germany (FRG) on 3 October 1990. Until 1989, it was generally vie ...
marks Marks may refer to: Business * Mark's, a Canadian retail chain * Marks & Spencer, a British retail chain * Collective trade marks A collective trademark, collective trade mark, or collective mark is a trademark owned by an organization (such ...
). Its industrial and technical uses include marine fittings and plumbing fixtures for its corrosion resistance, and heating coils for its high electrical resistance. In the nineteenth century, particularly after 1868, North American
Plains Indian Plains Indians or Indigenous peoples of the Great Plains and Canadian Prairies are the Native American tribes and First Nations peoples who have historically lived on the Interior Plains (the Great Plains and Canadian Prairies) of North ...
metalsmiths were able to easily acquire sheets of German silver. They used them to cut, stamp, and cold hammer a wide range of accessories and also horse gear. Presently, Plains metalsmiths use German silver for pendants, pectorals, bracelets, armbands, hair plates, ''conchas'' (oval decorative plates for belts), earrings, belt buckles, necktie slides, stickpins, '' dush-tuhs'', and
tiara A tiara (, ) is a head ornament adorned with jewels. Its origins date back to ancient Greco-Roman world. In the late 18th century, the tiara came into fashion in Europe as a prestigious piece of jewelry to be worn by women at formal occasions ...
s. Nickel silver is the metal of choice among contemporary
Kiowa Kiowa ( ) or Cáuigú () people are a Native Americans in the United States, Native American tribe and an Indigenous people of the Great Plains of the United States. They migrated southward from western Montana into the Rocky Mountains in Colora ...
and Pawnee in
Oklahoma Oklahoma ( ; Choctaw language, Choctaw: , ) is a landlocked U.S. state, state in the South Central United States, South Central region of the United States. It borders Texas to the south and west, Kansas to the north, Missouri to the northea ...
. Many of the metal fittings on modern higher-end equine harness and
tack Thermoproteati is a kingdom of archaea. Its synonym, "TACK", is an acronym for Thaumarchaeota (now Nitrososphaerota), Aigarchaeota, Crenarchaeota (now Thermoproteota), and Korarchaeota (now Thermoproteota), the first groups discovered. They ...
are of nickel silver. Early in the twentieth century, German silver was used by automobile manufacturers before the advent of steel sheet metal. For example, the famous
Rolls-Royce Silver Ghost The Rolls-Royce Silver Ghost name refers both to a car model and one specific car from that series. Originally named the "Tax horsepower#Britain, 40/50 h.p." the chassis was first made at Royce's Manchester works, with production moving t ...
of 1907 used German silver. After about 1920, it became widely used for pocketknife
bolster A bolster is a long narrow pillow or cushion filled with cotton, down or fibre. Bolsters are usually firm for back or arm support or for decorative application.Von Tobel, Jackie. "Neck Rolls and Bolsters." The Design Directory of Bedding. Lay ...
s, due to its machinability and corrosion resistance. Prior to this, the most common metal was
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
. Musical instruments, including the
flute The flute is a member of a family of musical instruments in the woodwind group. Like all woodwinds, flutes are aerophones, producing sound with a vibrating column of air. Flutes produce sound when the player's air flows across an opening. In th ...
, saxophone,
trumpet The trumpet is a brass instrument commonly used in classical and jazz musical ensemble, ensembles. The trumpet group ranges from the piccolo trumpet—with the highest Register (music), register in the brass family—to the bass trumpet, pitche ...
, and
French horn The French horn (since the 1930s known simply as the horn in professional music circles) is a brass instrument made of tubing wrapped into a coil with a flared bell. The double horn in F/B (technically a variety of German horn) is the horn most o ...
, string instrument frets, and electric guitar pickup parts, can be made of nickel silver. Many professional-level French horns are entirely made of nickel silver. Some saxophone manufacturers, such as
Keilwerth The Julius Keilwerth company is a German saxophone manufacturer, established in 1925. Company history Early history Julius Keilwerth first apprenticed for the Kohlert company in Graslitz, Czechoslovakia. After this apprenticeship, Julius Keilwe ...
, offer saxophones made of nickel silver (Shadow model); these are far rarer than traditional lacquered brass saxophones. Student-level flutes and piccolos are also made of silver-plated nickel silver, although upper-level models are likely to use
sterling silver Sterling silver is an alloy composed mass fraction (chemistry), by weight of 92.5% silver and 7.5% other metals, usually copper. The sterling silver silver standards, standard has a minimum millesimal fineness of 925. ''Fineness, Fine silver'' ...
. Nickel silver produces a bright and powerful sound quality; an additional benefit is that the metal is harder and more corrosion resistant than brass. Because of its hardness, it is used for most clarinet, flute, oboe and similar wind instrument keys, normally silver-plated. It is used to produce the tubes (called staples) onto which
oboe The oboe ( ) is a type of double-reed woodwind instrument. Oboes are usually made of wood, but may also be made of synthetic materials, such as plastic, resin, or hybrid composites. The most common type of oboe, the soprano oboe pitched in C, ...
reeds Reed or Reeds may refer to: Science, technology, biology, and medicine * Reed bird (disambiguation) * Reed pen, writing implement in use since ancient times * Reed (plant), one of several tall, grass-like wetland plants of the order Poales * Re ...
are tied. Many parts of brass instruments are made of nickel silver, such as tubes, braces or valve mechanism. Trombone slides of many manufacturers offer a lightweight nickel silver (LT slide) option for faster slide action and weight balance.Bach > Professional Bb Tenor Trombones > Viewing Model LT16M
. Bachbrass.com. Retrieved on 2013-12-19.
The material was used in the construction of the National tricone
resophonic guitar A resonator guitar or resophonic guitar (often generically called a "Dobro") is an acoustic guitar that produces sound by conducting string vibrations through the bridge to one or more spun metal cones (resonators), instead of to the guitar's ...
. The
frets A fret is any of the thin strips of material, usually metal wire, inserted laterally at specific positions along the Neck (music), neck or Fingerboard, fretboard of a stringed instrument. Frets usually extend across the full width of the Neck ( ...
of guitar, mandolin, banjo, bass, and related string instruments are typically nickel silver. Nickel silver is sometimes used as ornamentation on the
great highland bagpipe The great Highland bagpipe ( 'the great pipe') is a type of bagpipe native to Scotland, and the Scottish analogue to the great Irish warpipes. It has acquired widespread recognition through its usage in the British Armed Forces, British mili ...
. Nickel silver is also used in artworks. The Dutch sculptor Willem Lenssinck has made several pieces from German silver. Outdoors art made from this material easily withstands all kinds of weather.


See also

*
Argentium sterling silver Argentium silver (patented in 1998) is a brand of modern tarnish-resistant silver alloys, containing either 93.5%, 94% or 96% silver. Argentium alloys replace some of the copper in the traditional sterling silver (92.5% silver + 7.5% copper) wit ...
*
Britannia silver Britannia silver is an alloy of silver containing 11 ozt 10 dwt (i.e. 11½ troy oz.) silver in the pound troy, equivalent to , or 95.833% by weight (mass) silver, the rest usually being copper. This standard was introduced in England by Act o ...
*
Britannia metal Britannia metal (also called britannium, Britannia ware, or Vickers White Metal (Cite
an
Cupronickel Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other metals added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent. ( Monel is a n ...
*
Sheffield plate Old Sheffield Plate (or OSP) is the material developed by Thomas Boulsover in the 1740s, a fusion of copper and sterling silver which could be made into a range of items normally made in solid silver. The material rapidly gained popularity as ...
* Nickel Directive *
List of named alloys This is a list of named alloys grouped alphabetically by the metal with the highest percentage. Within these headings, the alloys are also grouped alphabetically. Some of the main alloying elements are optionally listed after the alloy names. Al ...


References


External links

*
Silver's Sterling Qualities
{{DEFAULTSORT:Nickel Silver Chinese inventions Copper alloys Nickel alloys Economy of the Qing dynasty Silver