A bubble is a
globule of a
gas
Gas is a state of matter that has neither a fixed volume nor a fixed shape and is a compressible fluid. A ''pure gas'' is made up of individual atoms (e.g. a noble gas like neon) or molecules of either a single type of atom ( elements such as ...
substance in a liquid. In the opposite case, a globule of a liquid in a gas, is called a
drop.
Due to the
Marangoni effect
The Marangoni effect (also called the Gibbs–Marangoni effect) is the mass transfer along an Interface (chemistry), interface between two phases due to a gradient of the surface tension. In the case of temperature dependence, this phenomenon may ...
, bubbles may remain intact when they reach the surface of the immersive substance.
Common examples
Bubbles are seen in many places in everyday life, for example:
* As spontaneous
nucleation
In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically def ...
of supersaturated
carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
in
soft drink
A soft drink (see #Terminology, § Terminology for other names) is a class of non-alcoholic drink, usually (but not necessarily) Carbonated water, carbonated, and typically including added Sweetness, sweetener. Flavors used to be Natural flav ...
s
* As
vapor
In physics, a vapor (American English) or vapour (Commonwealth English; American and British English spelling differences#-our, -or, see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature,R ...
in boiling water
* As
air
An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
mixed into agitated water, such as below a waterfall
* As
sea foam
Sea foam, ocean foam, beach foam, or spume is a type of foam created by the agitation of seawater, particularly when it contains higher concentrations of dissolved organic matter (including proteins, lignins, and lipids) derived from sources s ...
* As a
soap bubble
A soap bubble (commonly referred to as simply a bubble) is an extremely thin soap film, film of soap or detergent and water enclosing air that forms a hollow sphere with an iridescent surface. Soap bubbles usually last for only a few seconds b ...
* As given off in chemical reactions, e.g., baking soda + vinegar
* As a gas trapped in
glass
Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...
during its manufacture
* As the indicator in a
spirit level
A spirit level, bubble level, or simply a level, is an Measuring instrument, instrument designed to indicate whether a surface is Horizontal plane, horizontal (level) or vertical direction, vertical (plumb-bob, plumb).
Two basic designs exis ...
* As
bubble gum
Bubble gum (or bubblegum) is a type of chewing gum, designed to be inflated out of the mouth as a bubble.
Composition
In modern chewing gum, if natural rubber such as chicle is used, it must pass several purity and cleanliness tests. However, ...
Physics and chemistry
Bubbles form and coalesce into globular shapes because those shapes are at a lower energy state. For the physics and chemistry behind it, see
nucleation
In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically def ...
.
Appearance
Bubbles are visible because they have a different
refractive index
In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...
(RI) than the surrounding substance. For example, the RI of air is approximately 1.0003 and the RI of water is approximately 1.333.
Snell's Law
Snell's law (also known as the Snell–Descartes law, the ibn-Sahl law, and the law of refraction) is a formula used to describe the relationship between the angles of incidence and refraction, when referring to light or other waves passing th ...
describes how electromagnetic waves change direction at the interface between two mediums with different RI; thus bubbles can be identified from the accompanying
refraction
In physics, refraction is the redirection of a wave as it passes from one transmission medium, medium to another. The redirection can be caused by the wave's change in speed or by a change in the medium. Refraction of light is the most commo ...
and
internal reflection
In physics, total internal reflection (TIR) is the phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflect ...
even though both the immersed and immersing mediums are transparent.
The above explanation only holds for bubbles of one medium submerged in another medium (e.g. bubbles of gas in a soft drink); the volume of a
membrane bubble
A soap bubble (commonly referred to as simply a bubble) is an extremely thin film of soap or detergent and water enclosing air that forms a hollow sphere with an iridescent surface. Soap bubbles usually last for only a few seconds before burst ...
(e.g. soap bubble) will not distort light very much, and one can only see a membrane bubble due to
thin-film diffraction and
reflection.
Applications
Nucleation can be intentionally induced, for example, to create a
bubblegram
A bubblegram (also known as laser crystal, Subsurface Laser Engraving, 3D crystal engraving or vitrography) is a solid block of glass or transparent plastic that has been exposed to laser beams to generate three-dimensional space, three-dimensi ...
in a solid.
In medical
ultrasound
Ultrasound is sound with frequency, frequencies greater than 20 Hertz, kilohertz. This frequency is the approximate upper audible hearing range, limit of human hearing in healthy young adults. The physical principles of acoustic waves apply ...
imaging, small encapsulated bubbles called
contrast agent
A contrast agent (or contrast medium) is a substance used to increase the contrast of structures or fluids within the body in medical imaging. Contrast agents absorb or alter external electromagnetism or ultrasound, which is different from radiop ...
are used to enhance the contrast.
In thermal
inkjet
Inkjet printing is a type of printer (computing), computer printing that recreates a digital image by propelling droplets of ink onto paper or plastic substrates. Inkjet printers were the most commonly used type of printer in 2008, and range f ...
printing, vapor bubbles are used as actuators. They are occasionally used in other
microfluidics
Microfluidics refers to a system that manipulates a small amount of fluids (10−9 to 10−18 liters) using small channels with sizes of ten to hundreds of micrometres. It is a multidisciplinary field that involves molecular analysis, molecular bi ...
applications as actuators.
The violent collapse of bubbles (
cavitation
Cavitation in fluid mechanics and engineering normally is the phenomenon in which the static pressure of a liquid reduces to below the liquid's vapor pressure, leading to the formation of small vapor-filled cavities in the liquid. When sub ...
) near solid surfaces and the resulting impinging jet constitute the mechanism used in
ultrasonic cleaning
Ultrasonic cleaning is a process that uses ultrasound (usually from 20 to 40 kHz) to agitate a fluid, with a cleaning effect. Ultrasonic cleaners come in a variety of sizes, from small desktop units with an internal volume of less than , to large ...
. The same effect, but on a larger scale, is used in focused energy weapons such as the
bazooka
The Bazooka () is a Man-portable anti-tank systems, man-portable recoilless Anti-tank warfare, anti-tank rocket launcher weapon, widely deployed by the United States Army, especially during World War II. Also referred to as the "stovepipe", th ...
and the
torpedo
A modern torpedo is an underwater ranged weapon launched above or below the water surface, self-propelled towards a target, with an explosive warhead designed to detonate either on contact with or in proximity to the target. Historically, such ...
.
Pistol shrimp
Alpheidae (also known as the snapping shrimp, pistol shrimp or alpheid shrimp) is a family within the shrimp infraorder Caridea characterized by having asymmetrical claws, the larger of which is typically capable of producing a loud snapping sou ...
also uses a collapsing cavitation bubble as a weapon. The same effect is used to treat
kidney stones
Kidney stone disease (known as nephrolithiasis, renal calculus disease, or urolithiasis) is a crystallopathy and occurs when there are too many minerals in the urine and not enough liquid or hydration. This imbalance causes tiny pieces of cr ...
in a
lithotripter. Marine mammals such as
dolphins
A dolphin is an aquatic mammal in the cetacean clade Odontoceti (toothed whale). Dolphins belong to the families Delphinidae (the oceanic dolphins), Platanistidae (the Indian river dolphins), Iniidae (the New World river dolphins), Pontopori ...
and
whales
Whales are a widely distributed and diverse group of fully Aquatic animal, aquatic placental mammal, placental marine mammals. As an informal and Colloquialism, colloquial grouping, they correspond to large members of the infraorder Cetacea ...
use bubbles for entertainment or as hunting tools.
Aerators cause the dissolution of gas in the liquid by injecting bubbles.
Bubbles are used by
chemical
A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combin ...
and
metallurgic engineer
Engineers, as practitioners of engineering, are professionals who Invention, invent, design, build, maintain and test machines, complex systems, structures, gadgets and materials. They aim to fulfill functional objectives and requirements while ...
in processes such as distillation, absorption, flotation and spray drying. The complex processes involved often require consideration for mass and heat transfer and are modeled using
fluid dynamics
In physics, physical chemistry and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids – liquids and gases. It has several subdisciplines, including (the study of air and other gases in motion ...
.
The
star-nosed mole
The star-nosed mole (''Condylura cristata'') is a small semiaquatic mole (animal), mole found in moist, low elevation areas in the northeastern parts of North America. It is the only Extant taxon, extant member of the tribe Condylurini and genu ...
and the
American water shrew can smell underwater by rapidly breathing through their nostrils and creating a bubble.
Research on
the origin of life on Earth suggests that bubbles may have played an integral role in confining and concentrating
precursor molecules for life, a function currently performed by
cell membranes
The cell membrane (also known as the plasma membrane or cytoplasmic membrane, and historically referred to as the plasmalemma) is a biological membrane that separates and protects the interior of a cell from the outside environment (the extra ...
.
Bubble laser
An ordinary Bubble_(physics), bubble can serve as an optofluidics, optofluidic laser. These bubble lasers have been made of dye-doped soap solutions and Liquid crystal#Smectic_phases, smectic liquid crystal. In a bubble laser, the bubble itself se ...
s use bubbles as the optical resonator. They can be used as highly sensitive pressure sensors.
Pulsation
When bubbles are disturbed (for example when a gas bubble is injected underwater), the wall oscillates. Although it is often visually masked by much larger deformations in shape, a component of the oscillation changes the bubble volume (i.e. it is pulsation) which, in the absence of an externally-imposed sound field, occurs at the bubble's
natural frequency
Natural frequency, measured in terms of '' eigenfrequency'', is the rate at which an oscillatory system tends to oscillate in the absence of disturbance. A foundational example pertains to simple harmonic oscillators, such as an idealized spring ...
. The pulsation is the most important component of the oscillation, acoustically, because by changing the gas volume, it changes its pressure, and leads to the emission of sound at the bubble's natural frequency. For air bubbles in water, large bubbles (negligible
surface tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension (physics), tension is what allows objects with a higher density than water such as razor blades and insects (e.g. Ge ...
and
thermal conductivity
The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1.
Heat transfer occurs at a lower rate in materials of low ...
) undergo
adiabatic pulsations, which means that no heat is transferred either from the liquid to the gas or vice versa. The natural frequency of such bubbles is determined by the equation:
[Leighton, Timothy G., The Acoustic Bubble (Academic, London, 1994).]
:
where:
*
is the
specific heat ratio
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure () to heat capacity at constant volu ...
of the gas
*
is the
steady state
In systems theory, a system or a process is in a steady state if the variables (called state variables) which define the behavior of the system or the process are unchanging in time. In continuous time, this means that for those properties ''p' ...
radius
*
is the steady state
pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and eve ...
*
is the
mass
Mass is an Intrinsic and extrinsic properties, intrinsic property of a physical body, body. It was traditionally believed to be related to the physical quantity, quantity of matter in a body, until the discovery of the atom and particle physi ...
density
Density (volumetric mass density or specific mass) is the ratio of a substance's mass to its volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' (or ''d'') can also be u ...
of the surrounding liquid
For air bubbles in water, smaller bubbles undergo
isothermal
An isothermal process is a type of thermodynamic process in which the temperature ''T'' of a system remains constant: Δ''T'' = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and a change in the sys ...
pulsations. The corresponding equation for small bubbles of surface tension σ (and negligible liquid
viscosity
Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for e ...
) is
:
Excited bubbles trapped underwater are the major source of liquid
sound
In physics, sound is a vibration that propagates as an acoustic wave through a transmission medium such as a gas, liquid or solid.
In human physiology and psychology, sound is the ''reception'' of such waves and their ''perception'' by the br ...
s, such as inside our knuckles during knuckle cracking, and when a
rain
Rain is a form of precipitation where water drop (liquid), droplets that have condensation, condensed from Water vapor#In Earth's atmosphere, atmospheric water vapor fall under gravity. Rain is a major component of the water cycle and is res ...
droplet
A drop or droplet is a small column of liquid, bounded completely or almost completely by free surfaces. A drop may form when liquid accumulates at the end of a tube or other surface boundary, producing a hanging drop called a pendant drop. Dro ...
impacts a surface of water.
Physiology and medicine
Injury by bubble formation and growth in body tissues is the mechanism of
decompression sickness
Decompression sickness (DCS; also called divers' disease, the bends, aerobullosis, and caisson disease) is a medical condition caused by dissolved gases emerging from Solution (chemistry), solution as bubbles inside the body tissues during D ...
, which occurs when supersaturated dissolved inert gases leave the solution as bubbles during
decompression. The damage can be due to mechanical deformation of tissues due to bubble growth in situ, or by blocking
blood vessel
Blood vessels are the tubular structures of a circulatory system that transport blood throughout many Animal, animals’ bodies. Blood vessels transport blood cells, nutrients, and oxygen to most of the Tissue (biology), tissues of a Body (bi ...
s where the bubble has lodged.
Arterial gas embolism
An air embolism, also known as a gas embolism, is a blood vessel blockage caused by one or more bubbles of air or other gas in the circulatory system. Air can be introduced into the circulation during surgical procedures, lung over-expansi ...
can occur when a gas bubble is introduced to the circulatory system and lodges in a blood vessel that is too small for it to pass through under the available pressure difference. This can occur as a result of
decompression after hyperbaric exposure, a
lung overexpansion injury, during
intravenous fluid administration, or during
surgery
Surgery is a medical specialty that uses manual and instrumental techniques to diagnose or treat pathological conditions (e.g., trauma, disease, injury, malignancy), to alter bodily functions (e.g., malabsorption created by bariatric surgery s ...
.
In foods
Foods containing bubbles includes bread, cakes, cereals and
chocolate
Chocolate is a food made from roasted and ground cocoa beans that can be a liquid, solid, or paste, either by itself or to flavoring, flavor other foods.
Cocoa beans are the processed seeds of the cacao tree (''Theobroma cacao''); unprocesse ...
, and drinks including beer, champagne, mineral water and soft drinks, as well as more experimental applications in foams as made by chefs.
See also
*
Antibubble
An antibubble is a droplet of liquid surrounded by a thin film of gas, as opposed to a gas Liquid bubble, bubble, which is a sphere of gas surrounded by a liquid. Antibubbles are formed when liquid drops or flows turbulently into the same or an ...
*
Bubble fusion
Bubble fusion is the non-technical name for a nuclear fusion reaction hypothesized to occur inside extraordinarily large collapsing gas bubbles created in a liquid during acoustic cavitation. The more technical name is sonofusion.
The term was c ...
*
Bubble sensor
*
Foam
Foams are two-phase materials science, material systems where a gas is dispersed in a second, non-gaseous material, specifically, in which gas cells are enclosed by a distinct liquid or solid material. Note, this source focuses only on liquid ...
*
Minnaert resonance
*
Nanobubble
*
Sonoluminescence
Sonoluminescence is the emission of light from imploding bubbles in a liquid when excited by sound.
Sonoluminescence was first discovered in 1934 at the University of Cologne. It occurs when a sound wave of sufficient intensity induces a gaseo ...
*
Underwater acoustics
Underwater acoustics (also known as hydroacoustics) is the study of the propagation of sound in water and the interaction of the mechanical waves that constitute sound with the water, its contents and its boundaries. The water may be in the oce ...
References
Sources
*
{{DEFAULTSORT:Liquid Bubble
Fluid mechanics