Riebeckite is a

sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...

-rich member of the

amphibole Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...

group of

silicate mineral Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dio ...

s, chemical formula Na₂(Fe²⁺₃Fe³⁺₂)Si₈O₂₂(OH)₂. It forms a

solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...

series with magnesioriebeckite. It crystallizes in the

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three Vector (geometric), vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in t ...

system, usually as long

prismatic An optical prism is a transparent optics, optical element with flat, polished surfaces that are designed to refraction, refract light. At least one surface must be angled—elements with two parallel surfaces are ''not'' prisms. The most fami ...

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

s showing a diamond-shaped cross section, but also in fibrous, bladed, acicular, columnar, and radiating forms. Its

Mohs hardness The Mohs scale ( ) of mineral hardness is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fair ...

is 5.0–6.0, and its

specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...

is 3.0–3.4.

Cleavage Cleavage may refer to: Science * Cleavage (crystal), the way in which a crystal or mineral tends to split * Cleavage (embryo), the division of cells in an early embryo * Cleavage (geology), foliation of rock perpendicular to stress, a result of ...

is perfect, two directions in the shape of a

diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Diamond is tasteless, odourless, strong, brittle solid, colourless in pure form, a poor conductor of e ...

; fracture is uneven, splintery. It is often translucent to nearly opaque.

Name and discovery

Riebeckite was first described in 1888 for an occurrence on

Socotra Island Socotra, locally known as Saqatri, is a Yemeni island in the Indian Ocean. Situated between the Guardafui Channel and the Arabian Sea, it lies near major shipping routes. Socotra is the largest of the six islands in the Socotra archipelago as ...

, Aden Governorate,

Yemen Yemen, officially the Republic of Yemen, is a country in West Asia. Located in South Arabia, southern Arabia, it borders Saudi Arabia to Saudi Arabia–Yemen border, the north, Oman to Oman–Yemen border, the northeast, the south-eastern part ...

, and named for German explorer Emil Riebeck (1853–1885). The mineral is also known as crocidolite.

Occurrence

Riebeckite typically forms dark-blue elongated to fibrous crystals in highly alkali

granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...

syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). It is considered a felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...

volcanics Volcanic rocks (often shortened to volcanics in scientific contexts) are rocks formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and met ...

, granite

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...

s and

schist Schist ( ) is a medium-grained metamorphic rock generally derived from fine-grained sedimentary rock, like shale. It shows pronounced ''schistosity'' (named for the rock). This means that the rock is composed of mineral grains easily seen with a l ...

. It occurs in

banded iron formation Banded iron formations (BIFs; also called banded ironstone formations) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness and e ...

s as the

asbestiform Asbestiform is a crystal habit. It describes a mineral that grows in a fibrous aggregate of high tensile strength, flexible, long, and thin crystals that readily separate.Committee on Asbestos: Selected Health Effects, 2006, ''Asbestos: Selected Ca ...

variety ''crocidolite'' (blue

asbestos Asbestos ( ) is a group of naturally occurring, Toxicity, toxic, carcinogenic and fibrous silicate minerals. There are six types, all of which are composed of long and thin fibrous Crystal habit, crystals, each fibre (particulate with length su ...

). It occurs in association with

aegirine Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine– augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite se ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatit ...

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicat ...

arfvedsonite Arfvedsonite () or ''soda hornblende'' (partiellement obsolète) is a sodium amphibole mineral with composition: aNa2] Fe2+)4Fe3+(OH)2, Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black t ...

igneous rock Igneous rock ( ), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava. The magma can be derived from partial ...

s; with

tremolite Tremolite is a member of the amphibole group of silicate minerals with composition Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz, and occurs in two distinct forms, crystals and fib ...

, ferro-

actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite i ...

metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...

s; and with

grunerite Grunerite is a mineral of the amphibole group of minerals with formula Fe7 Si8 O22( OH)2. It is the iron endmember of the grunerite- cummingtonite series. It forms as fibrous, columnar or massive aggregates of crystals. The crystals are monoclin ...

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...

stilpnomelane Stilpnomelane is a phyllosilicate mineral. It has the chemical formula . Stilpnomelane occurs associated with banded iron formations. It is a metamorphic mineral associated with the blueschist and greenschist facies. It was first described in 18 ...

ankerite Ankerite, also known as '' brown spar''礦物學名詞: (俄英中对照試用本) Mineralogical Terminology (Russian-English-Chinese version). — Beijing: 中國科学院. 編譯出版委員会 Compilation and Publication Committee of Chinese A ...

siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly ...

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

, chalcedonic

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

in iron formations.

Riebeckite granite

The riebeckite

known as ''ailsite'', found on the island of

Ailsa Craig Ailsa Craig (; ) is an island of in the outer Firth of Clyde, west of mainland Scotland, upon which microgranite has long been quarried to make curling stones. The now-uninhabited island comprises the remains of a magmatic pluton formed d ...

in western

Scotland Scotland is a Countries of the United Kingdom, country that is part of the United Kingdom. It contains nearly one-third of the United Kingdom's land area, consisting of the northern part of the island of Great Britain and more than 790 adjac ...

, is prized for its use in the manufacture of

curling Curling is a sport in which players slide #Curling stone, stones on a sheet of ice toward a target area that is segmented into four concentric circles. It is related to bowls, boules, and shuffleboard. Two teams, each with four players, take t ...

stones. Riebeckite granite was used for the facing stones of the

Canton Viaduct Canton Viaduct is a blind arcade cavity wall in Canton, Massachusetts, built in 1834–35 for the Boston and Providence Railroad. At its completion, it was the longest () and tallest () railroad viaduct in the world; today, it is the last surv ...

from Moyles Quarry (a.k.a. Canton Viaduct Quarry) now part of

Borderland State Park Borderland State Park is an American history and nature preserve with public recreational features located in the towns of Easton and Sharon, Massachusetts. The state park encompasses surrounding the Ames Mansion, which was built in 1910. The ...

Massachusetts Massachusetts ( ; ), officially the Commonwealth of Massachusetts, is a U.S. state, state in the New England region of the Northeastern United States. It borders the Atlantic Ocean and the Gulf of Maine to its east, Connecticut and Rhode ...

, US. The commonwealth's name is even taken from an Algonquian word for the

Great Blue Hill Great Blue Hill is a hill of 635 feet (194 m) located within the Blue Hills Reservation in Milton, Randolph and Canton, Massachusetts, about south of downtown Boston. It is the highest point in Norfolk County and the Greater Boston area. ...

, which got its color from this form of granite.

Crocidolite (fibrous riebeckite)

The fibrous forms of riebeckite are known as ''crocidolite'' and are one of the six recognised types of

. Often referred to as blue asbestos, it is considered the most hazardous. The association between blue asbestos and

mesothelioma Mesothelioma is a type of cancer that develops from the thin layer of tissue that covers many of the internal organs (known as the mesothelium). The area most commonly affected is the lining of the lungs and chest wall. Less commonly the lini ...

was established by J. C. Wagner, C. A. Sleggs, and P. Marchand by 1960. Crocidolite asbestos was mined in

South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...

Bolivia Bolivia, officially the Plurinational State of Bolivia, is a landlocked country located in central South America. The country features diverse geography, including vast Amazonian plains, tropical lowlands, mountains, the Gran Chaco Province, w ...

, and

Wittenoom, Western Australia Wittenoom is a former town and a declared contaminated site, north-north-east of Perth, in the Hamersley Range in the Pilbara region of Western Australia. The declared contaminated site comprises , making it the largest contaminated site in t ...

. Bolivian crocidolite was used in approximately 13 billion

Kent Kent is a Ceremonial counties of England, ceremonial county in South East England. It is bordered by Essex across the Thames Estuary to the north, the Strait of Dover to the south-east, East Sussex to the south-west, Surrey to the west, and Gr ...

Micronite cigarette filters, manufactured from March 1952 until at least May 1956 by the

Lorillard Tobacco Company Lorillard Tobacco Company was an American tobacco company that marketed cigarettes under the brand names Newport (cigarette), Newport, Maverick (cigarette), Maverick, Old Gold (cigarette), Old Gold, Kent (cigarette), Kent, True (cigarette), True, ...

(now part of the

R. J. Reynolds Tobacco Company The R. J. Reynolds Tobacco Company (RJR) is an American tobacco manufacturing company based in Winston-Salem, North Carolina. Founded by namesake R. J. Reynolds in 1875, it is the largest tobacco company in the United States. The company is a w ...

). Blue asbestos was also used to similar effect, and hazard, in early gas masks.

References

External links