Agardite-(Ce)
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Agardite is a mineral group consisting of agardite-(Y), agardite-(Ce), agardite-(Nd), and agardite-(La). They comprise a group of minerals that are hydrous hydrated
arsenate The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. The four oxygen atoms orien ...
s of
rare-earth element The rare-earth elements (REE), also called the rare-earth metals or rare earths, and sometimes the lanthanides or lanthanoids (although scandium and yttrium, which do not belong to this series, are usually included as rare earths), are a set o ...
s (REE) and
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
, with the general chemical formula (REE,Ca)Cu6(AsO4)3(OH)6·3H2O.
Yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
,
cerium Cerium is a chemical element; it has Chemical symbol, symbol Ce and atomic number 58. It is a hardness, soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it ...
,
neodymium Neodymium is a chemical element; it has Symbol (chemistry), symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth element, rare-earth metals. It is a hard (physics), hard, sli ...
,
lanthanum Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements bet ...
, as well as trace to minor amounts of other REEs, are present in their structure. Agardite-(Y) is probably the most often found representative. They form needle-like yellow-green (variably hued) crystals in the
hexagonal In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°. Regular hexagon A regular hexagon is d ...
crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices (an infinite array of discrete points). Space groups (symmetry groups ...
. Agardite minerals are a member of the
mixite Mixite is a rare copper bismuth arsenate mineral with formula: BiCu6(AsO4)3(OH)6·3(H2O). It crystallizes in the Hexagonal (crystal system), hexagonal crystal system typically occurring as radiating acicular prisms and massive encrustations. The ...
structure group, which has the general chemical formula Cu2+6''A''(''T''O4)3(OH)6·3H2O, where ''A'' is a REE, Al, Ca, Pb, or Bi, and ''T'' is P or As. In addition to the four agardite minerals, the other members of the mixite mineral group are calciopetersite, goudeyite,
mixite Mixite is a rare copper bismuth arsenate mineral with formula: BiCu6(AsO4)3(OH)6·3(H2O). It crystallizes in the Hexagonal (crystal system), hexagonal crystal system typically occurring as radiating acicular prisms and massive encrustations. The ...
, petersite-(Ce), petersite-(Y), plumboagardite, and zálesíite. Agardite-(Y) from the Bou Skour mine in Djebel Sarhro, Morocco was the first of the agardite-group minerals to be characterized. It was described by Dietrich in 1969 and was named after Jules Agard, a
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at the Bureau de Recherches Géologiques et Minières, Orléans, France. Agardite-group minerals have subsequently been found in
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, the
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, and the
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.Pemberton, H. Earl (1983), ''Minerals of California''; Van Nostrand Reinholt Press: 323.


See also

*
List of minerals This is a list of minerals which have Wikipedia articles. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a mineral speci ...


References

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Further reading

* Aufschluss 1977(5), 177–183. * Steen, H. (2005): Ein Neufund von Agardit-(Y) aus Rotenbach im Feldberggebiet (südlicher Schwarzwald). Der Erzgräber 19, 70–72. * Wittern: "Mineralfundorte in Deutschland", Schweizerbart (Stuttgart), 2001.*Wittern, A. (1995) Mineralien finden im Schwarzwald. * Lapis 1985(11), 31–32. * S. Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990 * Walenta, K. and Theye, T. (2004): Agardit-(Ce) von der Grube Clara im mittleren Schwarzwald. Aufschluss 55, 17–23. ith analysis of Johann material showing Nd > La * Emser Hefte 15(3), 2–40 (1994). * Heckmann, H. & Schertl, H.-P. (1990): Der Niederbergische Erzbergbau und seine Mineralien. Emser Hefte, 11 (2), 2–40. * Pekov, I. V., Chukanov, N. V., Zadov, A. E., Voudouris, P., Magganas, A. and Katerinopoulos, A. (2010) Agardite-(Nd), IMA 2010–056. CNMNC Newsletter No. 7, February 2010, page 30; Mineralogical Magazine, 75, 27–31. * Pekov, I. V., Chukanov, N. V., Zadov, A. E., Voudouris, P., Magganas, A., Katerinopoulos, A. (2011): Agardite-(Nd), NdCu6(AsO4)3(OH)6·3H2O from the Hilarion Mine, Lavrion, Greece: mineral description and chemical relations with other members of the agardite-zálesíite solid-solution system. Journal of Geosciences, 56, 249–255. * Ambrino, P., Brizio, P., Ciriotti, M. E., Finello, G., Marello, B. (2009). Minerali della pietra di Luserna. AMI. CD-ROM. * Piccoli, G. C., Maletto, G., Bosio, P., Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp. * Stara, P., Rizzo, R., Brizzi G., (1993): Sarrabus Miniere e Minerali. Edito a cura dell'EMSA e "varie associazioni mineralogiche", 208 pp. * Stara, P., Rizzo, R., Tanca, G. A. (1996): Iglesiente e Arburese. Miniere e Minerali. Edito a cura dell'EMSA e "varie associazioni mineralogiche", Volume 2, 192 pp. * Olmi F., Sabelli C., Santucci, A., Brizzi, G. (1995): I silicati e i vanadati di Ozieri (SS). Rivista Mineralogica Italiana, 2/1995, 145–160. * Vecchi, F., Rocchetti, I., Gentile, P. (2013): Die Mineralien des Granits von Predazzo, Provinz Trient, Italien. Mineralien-Welt, 24(6), 98–117. * Ricordo di Cristel Puecher da Roveda; F. Maiello, P. Ferretti; 2009*Rocchetti I., Gentile P. and Ferretti P. (2012): La Miniera di Frattasecca presso Malga Broi (Novaledo, Trentino-Alto Adige). Storia e nuove segnalazioni mineralogiche. Studi Trentini di Scienze Naturali, 92, p. 167–180. * Bortolozzi G., Blass G., Boscardin M., Rocchetti I. and Ferretti P. (2013): La Miniera di Cinquevalli (Valsugana, Trentino-Alto Adige): aggiornamento sulle specie accertate negli ultimi anni. Studi Trent. Sci. Nat., 93, p. 149–165. * Paolo Gasparetto, Erica Bittarello, Andrea Canal, Lara Casagrande, Marco E. Ciriotti, Bruno Fassina, Paolo Ferretti, Sergio Pegoraro, Fabio Tosato, Paolo Zammatteo (2014): I lavori minerari del Rio Ricet, Vignola, Falesina, Trento. Micro, 12, 50–123. * Senesi, F. & Sabelli, C. (1999): Gli arseniati degli antichi scavi di Valle S. Caterina (Campiglia Marittima). Rivista Mineralogica Italiana, 23(1), 51–55. * The Mineral Species of Japan (5th ed) Matsubara. * Yamada, S. (2004) Nihonsan-koubutsu Gojuon-hairetsu Sanchi-ichiranhyou (111 pp.). * Jimenez R., Joda L., Jorda R., Prado P. (2004) - Madrid: la mineria Metallica desde 1417 hasta nuestros dias. Bocamina, n°14, pp: 52–89. * Tanago, J. G., Lozano, P. L., Larios, A., La Iglesia, A. (2012) Stokesite crystals from La Cabrera, Madrid, Spain. Mineralogical Record 43: 499–508. * Collection of the Geominero Museum of Madrid; Tanago, J. G., Lozano, P. L., Larios, A., La Iglesia, A. (2012) Stokesite crystals from La Cabrera, Madrid, Spain. Mineralogical Record 43: 499–508. * Meisser, N. (2012): La minéralogie de l'uranium dans le massif des Aiguilles Rouges. Matér. Géol. Suisse, Sér. géotech. 96, 183 p. * Embrey & Symes, 1987, 40 – "Minerals of Cornwall and Devon"]; Peter G. Embrey (1978) Fourth Supplementary List of British Minerals. Mineralogical Magazine 42: 169–177. * Cooper & Stanley, 1990, 76 – "Minerals of the English Lake district". * Schultenite: Symes, R.F., Wirth, M., Mineral Mag. (1990), 54, p. 659. * Mineralien Welt 1/93:44. * Rocks & Minerals 83:1 pp. 65–69. * NBMG Spec. Pub. 31 Minerals of Nevada; Rocks & Minerals (2010) 85: 512–524. * Jensen, M. (1993): Update on the mineralogy of the Majuba Hill mine, Pershing County. Mineralogical Record. 24, 171–180. * Natural History Museum Vienna collection; Jensen, M. (1993): Update on the mineralogy of the Majuba Hill mine, Pershing County. Mineralogical Record. 24, 171–180. * R&M 77:5 p. 298–305. * Anthony, Bideaux, Bladh, Nichols: "Handbook of Mineralogy", Vol. 4, 2000. * Northrop, Minerals of New Mexico, 3rd Rev. Ed., 1996. * Micro Probe Volume VI Number 8; Rocks and Minerals, 66:6, p. 453.


External links


RRUFF Project
Calcium minerals Copper minerals Lanthanide minerals Arsenate minerals Hexagonal minerals Minerals in space group 176