Afterdamp is the toxic mixture of gases left in a mine following an explosion caused by
methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
-rich
firedamp, which itself can initiate a much larger explosion of
coal dust. The term is etymologically and practically related to other terms for underground mine gases—such as
firedamp,
white damp, and
black damp, with afterdamp being composed, rather, primarily by
carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
,
carbon monoxide
Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the si ...
and
nitrogen
Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, with highly toxic
stinkdamp-constituent
hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
possibly also present. However, the high content of carbon monoxide is the component that kills, preferentially combining with
haemoglobin
Hemoglobin (haemoglobin, Hb or Hgb) is a protein containing iron that facilitates the transportation of oxygen in red blood cells. Almost all vertebrates contain hemoglobin, with the sole exception of the fish family Channichthyidae. Hemoglobi ...
in the blood and thus depriving victims of
oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
. Globally, afterdamp has caused many of the casualties in disasters of pit coalfields, including British, such as the
Senghenydd colliery disaster. Such disasters continue to afflict working mines, for instance in mainland China.
Etymology
The meaning of "damp" in this term, while most commonly understood to imply humidity, presents evidence of having been separated from that newer, irrelevant meaning at least by the first decade of the 18th century, where the original relevant meaning of "vapor" derives from a Proto-Germanic origin, ''dampaz'', which gave rise to its immediate English predecessor, the Middle Low German ''damp'' (with no record of an Old English intermediary). The proto-Germanic ''dampaz'' gave rise to many other cognates, including the Old High German ''damph'', the Old Norse ''dampi'', and the modern German ''Dampf'', the last of which still translates as "vapor".
Detection
Animal sentinels, such as
mice
A mouse (: mice) is a small rodent. Characteristically, mice are known to have a pointed snout, small rounded ears, a body-length scaly tail, and a high breeding rate. The best known mouse species is the common house mouse (''Mus musculus' ...
or
canaries, are more sensitive to carbon monoxide than humans, so will give a warning to miners. Canaries were introduced into British collieries in the 1890s by
John Scott Haldane, the noted physiologist.
Gas detectors are available now which detect toxic gases such as carbon monoxide at very low levels. They are widely available to protect domestic premises. The levels of gas detection depend on the methods used.
See also
*
Firedamp
*
Blackdamp
*
Stinkdamp
*
Whitedamp
*
Glossary of coal mining terminology
References
Further reading
* J S Haldane and
J G Priestley, ''Respiration'', Oxford University Press, 2nd ed. (1935)
{{Damp
Mine safety
Carbon dioxide
Carbon monoxide