Actinium(III) fluoride (AcF
3) is an
inorganic compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''.
Inorgan ...
, a salt of
actinium
Actinium is a chemical element; it has chemical symbol, symbol Ac and atomic number 89. It was discovered by Friedrich Oskar Giesel in 1902, who gave it the name ''emanium''; the element got its name by being wrongly identified with a substa ...
and
fluorine
Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
.
Synthesis
Actinium fluoride can be prepared in solution or by a solid-state reaction. In the first method,
actinium hydroxide is treated with
hydrofluoric acid
Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ...
and the product precipitates:
[
]
:
In the solid-state reaction, actinium metal is treated with
hydrogen fluoride
Hydrogen fluoride (fluorane) is an Inorganic chemistry, inorganic compound with chemical formula . It is a very poisonous, colorless gas or liquid that dissolves in water to yield hydrofluoric acid. It is the principal industrial source of fluori ...
gas at 700 °C in a platinum crucible.
[Meyer, Gerd and Morss, Lester R. (1991) ''Synthesis of lanthanide and actinide compounds.'' Springer. . pp. 87–88]
Properties
Actinium fluoride is a white solid that reacts with ammonia at 900–1000 °C to yield an actinium oxyfluoride:
:
While lanthanum oxyfluoride is easily formed by heating
lanthanum fluoride
Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is .
The LaF3 structure
Bonding is ionic with lanthanum highly coordinated. The cation sits at the center of a trigonal prism. Nine fluorine ...
in air, a similar treatment merely melts actinium fluoride and does not yield AcOF.
References
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Actinium compounds
Fluorides
Actinide halides