Acid Rain
   HOME

TheInfoList



OR:

Acid rain is
rain Rain is a form of precipitation where water drop (liquid), droplets that have condensation, condensed from Water vapor#In Earth's atmosphere, atmospheric water vapor fall under gravity. Rain is a major component of the water cycle and is res ...
or any other form of
precipitation In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls from clouds due to gravitational pull. The main forms of precipitation include drizzle, rain, rain and snow mixed ("sleet" in Commonwe ...
that is unusually
acid An acid is a molecule or ion capable of either donating a proton (i.e. Hydron, hydrogen cation, H+), known as a Brønsted–Lowry acid–base theory, Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis ...
ic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid rain has a pH level lower than this and ranges from 4–5 on average. The more acidic the acid rain is, the lower its pH is. Acid rain can have harmful effects on plants, aquatic animals, and infrastructure. Acid rain is caused by emissions of
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
and nitrogen oxide, which react with the water molecules in the
atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
to produce acids. Acid rain has been shown to have adverse impacts on forests, freshwaters, soils, microbes, insects and aquatic life-forms. In
ecosystem An ecosystem (or ecological system) is a system formed by Organism, organisms in interaction with their Biophysical environment, environment. The Biotic material, biotic and abiotic components are linked together through nutrient cycles and en ...
s, persistent acid rain reduces tree bark durability, leaving flora more susceptible to environmental stressors such as drought, heat/cold and pest infestation. Acid rain is also capable of detrimenting soil composition by stripping it of nutrients such as calcium and magnesium which play a role in plant growth and maintaining healthy soil. In terms of human infrastructure, acid rain also causes paint to peel,
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
of steel structures such as bridges, and weathering of stone buildings and statues as well as having impacts on human health.Effects of Acid Rain – Human Health
. Epa.gov (June 2, 2006). Retrieved on 2013-02-09.
Some governments, including those in
Europe Europe is a continent located entirely in the Northern Hemisphere and mostly in the Eastern Hemisphere. It is bordered by the Arctic Ocean to the north, the Atlantic Ocean to the west, the Mediterranean Sea to the south, and Asia to the east ...
and
North America North America is a continent in the Northern Hemisphere, Northern and Western Hemisphere, Western hemispheres. North America is bordered to the north by the Arctic Ocean, to the east by the Atlantic Ocean, to the southeast by South Ameri ...
, have made efforts since the 1970s to reduce the release of sulfur dioxide and nitrogen oxide into the atmosphere through
air pollution Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
regulations. These efforts have had positive results due to the widespread research on acid rain starting in the 1960s and the publicized information on its harmful effects. The main source of sulfur and nitrogen compounds that result in acid rain are
anthropogenic Anthropogenic ("human" + "generating") is an adjective that may refer to: * Anthropogeny, the study of the origins of humanity Anthropogenic may also refer to things that have been generated by humans, as follows: * Human impact on the enviro ...
, but nitrogen oxides can also be produced naturally by
lightning Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
strikes and sulfur dioxide is produced by volcanic eruptions.


Definition

"Acid rain" is rain with a pH less than 5. "Clean" or unpolluted rain has a pH greater than 5 but still less than pH = 7 owing to the acidity caused by carbon dioxide acid according to the following reactions: : : A variety of natural and human-made sources contribute to the acidity. For example
nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
produced by electric discharge in the atmosphere such as
lightning Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
. The usual anthropogenic sources are
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
and nitrogen oxide. They react with water (as does carbon dioxide) to give solutions with pH < 5. Occasional pH readings in rain and fog water of well below 2.4 have been reported in industrialized areas.


History

Acid rain was first systematically studied in Europe in the 1960s, in the United States and Canada in 1970s, and in India in the late 1980s.


In Europe

The corrosive effect of polluted, acidic city air on limestone and marble was noted in the 17th century by John Evelyn, who remarked upon the poor condition of the Arundel marbles.E. S. de Beer, ed. '' The Diary of John Evelyn'', III, 1955 (September 19, 1667) p. 495. Since the
Industrial Revolution The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...
, emissions of sulfur dioxide and nitrogen oxides into the atmosphere have increased. In 1852, Robert Angus Smith was the first to show the relationship between acid rain and atmospheric pollution in
Manchester Manchester () is a city and the metropolitan borough of Greater Manchester, England. It had an estimated population of in . Greater Manchester is the third-most populous metropolitan area in the United Kingdom, with a population of 2.92&nbs ...
, England.Seinfeld, John H.; Pandis, Spyros N (1998)
Atmospheric Chemistry and Physics â€” From Air Pollution to Climate Change.
John Wiley and Sons, Inc.
Smith coined the term "acid rain" in 1872. In the late 1960s, scientists began widely observing and studying the phenomenon. At first, the main focus in this research lay on local effects of acid rain. Waldemar Christofer Brøgger was the first to acknowledge long-distance transportation of pollutants crossing borders from the United Kingdom to Norway – a problem systematically studied by Brynjulf Ottar in the 1970s. Ottar's work was strongly influenced by Swedish soil scientist Svante Odén, who had drawn widespread attention to Europe's acid rain problem in popular newspapers and wrote a landmark paper on the subject in 1968.


In the United States

The earliest report about acid rain in the United States came from chemical evidence gathered from Hubbard Brook Valley; public awareness of acid rain in the US increased in the 1970s after ''
The New York Times ''The New York Times'' (''NYT'') is an American daily newspaper based in New York City. ''The New York Times'' covers domestic, national, and international news, and publishes opinion pieces, investigative reports, and reviews. As one of ...
'' reported on these findings. In 1972, a group of scientists, including Gene Likens, discovered the rain that was deposited at White Mountains of New Hampshire was acidic. The pH of the sample was measured to be 4.03 at Hubbard Brook. The Hubbard Brook Ecosystem Study followed up with a series of research studies that analyzed the environmental effects of acid rain. The alumina from soils neutralized acid rain that mixed with stream water at Hubbard Brook. The result of this research indicated that the
chemical reaction A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, ...
between acid rain and aluminium leads to an increasing rate of soil weathering. Experimental research examined the effects of increased acidity in streams on ecological species. In 1980, scientists modified the acidity of Norris Brook, New Hampshire, and observed the change in species' behaviors. There was a decrease in species diversity, an increase in community dominants, and a reduction in the food web complexity. In 1980, the US Congress passed an Acid Deposition Act. This Act established an 18-year assessment and research program under the direction of the National Acidic Precipitation Assessment Program (NAPAP). NAPAP enlarged a network of monitoring sites to determine how acidic precipitation was, seeking to determine long-term trends, and established a network for dry deposition. Using a statistically based sampling design, NAPAP quantified the effects of acid rain on a regional basis by targeting research and surveys to identify and quantify the impact of acid precipitation on freshwater and terrestrial ecosystems. NAPAP also assessed the effects of acid rain on historical buildings, monuments, and building materials. It also funded extensive studies on atmospheric processes and potential control programs. From the start, policy advocates from all sides attempted to influence NAPAP activities to support their particular policy advocacy efforts, or to disparage those of their opponents. For the US Government's scientific enterprise, a significant impact of NAPAP were lessons learned in the assessment process and in environmental research management to a relatively large group of scientists, program managers, and the public. In 1981, the
National Academy of Sciences The National Academy of Sciences (NAS) is a United States nonprofit, NGO, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the ...
was looking into research about the controversial issues regarding acid rain. President Ronald Reagan dismissed the issues of acid rain until his personal visit to Canada and confirmed that the Canadian border suffered from the drifting pollution from smokestacks originating in the US Midwest. Reagan honored the agreement to Canadian Prime Minister
Pierre Trudeau Joseph Philippe Pierre Yves Elliott Trudeau (October 18, 1919 â€“ September 28, 2000) was a Canadian politician, statesman, and lawyer who served as the 15th prime minister of Canada from 1968 to 1979 and from 1980 to 1984. Between his no ...
's enforcement of anti-pollution regulation. In 1982, Reagan commissioned William Nierenberg to serve on the National Science Board. Nierenberg selected scientists including Gene Likens to serve on a panel to draft a report on acid rain. In 1983, the panel of scientists came up with a draft report, which concluded that acid rain is a real problem and solutions should be sought. White House
Office of Science and Technology Policy The Office of Science and Technology Policy (OSTP) is a department of the United States government, part of the Executive Office of the President of the United States, Executive Office of the President (EOP), established by United States Congres ...
reviewed the draft report and sent Fred Singer's suggestions of the report, which cast doubt on the cause of acid rain. The panelists revealed rejections against Singer's positions and submitted the report to Nierenberg in April. In May 1983, the House of Representatives voted against legislation controlling sulfur emissions. There was a debate about whether Nierenberg delayed the release of the report. Nierenberg denied the saying about his suppression of the report and stated that it was withheld after the House's vote because it was not ready to be published. In 1991, the US National Acid Precipitation Assessment Program (NAPAP) provided its first assessment of acid rain in the United States. It reported that 5% of New England Lakes were acidic, with sulfates being the most common problem. They noted that 2% of the lakes could no longer support Brook Trout, and 6% of the lakes were unsuitable for the survival of many minnow species. Subsequent ''Reports to Congress'' have documented chemical changes in soil and freshwater ecosystems, nitrogen saturation, soil nutrient decreases, episodic acidification, regional haze, and damage to historical monuments. Meanwhile, in 1990, the US Congress passed a series of amendments to the Clean Air Act. Title IV of these amendments established a
cap and trade Carbon emission trading (also called carbon market, emission trading scheme (ETS) or cap and trade) is a type of emissions trading scheme designed for carbon dioxide (CO2) and other greenhouse gases (GHGs). A form of carbon price, carbon pricing ...
system designed to control emissions of sulfur dioxide and nitrogen oxides.John Bachmann, David Calkins, Margo Oge
"Cleaning the Air We Breathe: A Half Century of Progress."
EPA Alumni Association. September 2017. Pages 26–27.
Both these emissions proved to cause a significant problem for U.S. citizens and their access to healthy, clean air. Title IV called for a total reduction of about 10 million tons of SO2 emissions from power plants, close to a 50% reduction. It was implemented in two phases. Phase I began in 1995 and limited sulfur dioxide emissions from 110 of the largest power plants to 8.7 million tons of sulfur dioxide. One power plant in New England (Merrimack) was in Phase I. Four other plants (Newington, Mount Tom, Brayton Point, and Salem Harbor) were added under other program provisions. Phase II began in 2000 and affects most of the power plants in the country. During the 1990s, research continued. On March 10, 2005, the EPA issued the Clean Air Interstate Rule (CAIR). This rule provides states with a solution to the problem of power plant pollution that drifts from one state to another. CAIR will permanently cap emissions of SO2 and NOx in the eastern United States. When fully implemented, CAIR will reduce SO2 emissions in 28 eastern states and the District of Columbia by over 70% and NOx emissions by over 60% from 2003 levels. Overall, the program's cap and trade program has been successful in achieving its goals. Since the 1990s, SO2 emissions have dropped 40%, and according to the Pacific Research Institute, acid rain levels have dropped 65% since 1976.'Cap-and-trade' model eyed for cutting greenhouse gases
,
San Francisco Chronicle The ''San Francisco Chronicle'' is a newspaper serving primarily the San Francisco Bay Area of Northern California. It was founded in 1865 as ''The Daily Dramatic Chronicle'' by teenage brothers Charles de Young and M. H. de Young, Michael H. ...
, December 3, 2007.
Conventional regulation was used in the European Union, which saw a decrease of over 70% in SO2 emissions during the same period. In 2007, total SO2 emissions were 8.9 million tons, achieving the program's long-term goal ahead of the 2010 statutory deadline. In 2007 the EPA estimated that by 2010, the overall costs of complying with the program for businesses and consumers would be $1 billion to $2 billion a year, only one-fourth of what was initially predicted. Forbes says: "In 2010, by which time the cap and trade system had been augmented by the George W. Bush administration's Clean Air Interstate Rule, SO2 emissions had fallen to 5.1 million tons." The term citizen science can be traced back as far as January 1989 to a campaign by the Audubon Society to measure acid rain. Scientist Muki Haklay cites in a policy report for the Wilson Center entitled 'Citizen Science and Policy: A European Perspective' a first use of the term 'citizen science' by R. Kerson in the magazine
MIT Technology Review ''MIT Technology Review'' is a bimonthly magazine wholly owned by the Massachusetts Institute of Technology. It was founded in 1899 as ''The Technology Review'', and was re-launched without "''The''" in its name on April 23, 1998, under then pu ...
from January 1989. Quoting from the Wilson Center report: "The new form of engagement in science received the name "citizen science". The first recorded example of using the term is from 1989, describing how 225 volunteers across the US collected rain samples to assist the Audubon Society in an acid-rain awareness-raising campaign. The volunteers collected samples, checked for acidity, and reported to the organization. The information was then used to demonstrate the full extent of the phenomenon."


In Canada

Canadian Harold Harvey was among the first to research a "dead" lake. In 1971, he and R. J. Beamish published a report, "Acidification of the La Cloche Mountain Lakes", documenting the gradual deterioration of fish stocks in 60 lakes in Killarney Park in Ontario, which they had been studying systematically since 1966. In the 1970s and 80s, acid rain was a major topic of research at the Experimental Lakes Area (ELA) in Northwestern Ontario, Canada. Researchers added
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
to whole lakes in controlled ecosystem experiments to simulate the effects of acid rain. Because its remote conditions allowed for whole-ecosystem experiments, research at the ELA showed that the effect of acid rain on fish populations started at concentrations much lower than those observed in laboratory experiments. In the context of a food web, fish populations crashed earlier than when acid rain had direct toxic effects to the fish because the acidity led to crashes in
prey Predation is a biological interaction in which one organism, the predator, kills and eats another organism, its prey. It is one of a family of common feeding behaviours that includes parasitism and micropredation (which usually do not ki ...
populations (e.g. mysids). As experimental acid inputs were reduced, fish populations and lake ecosystems recovered at least partially, although invertebrate populations have still not completely returned to the baseline conditions. This research showed both that acidification was linked to declining fish populations and that the effects could be reversed if sulfuric acid emissions decreased, and influenced policy in Canada and the United States. In 1985, seven Canadian provinces (all except
British Columbia British Columbia is the westernmost Provinces and territories of Canada, province of Canada. Situated in the Pacific Northwest between the Pacific Ocean and the Rocky Mountains, the province has a diverse geography, with rugged landscapes that ...
,
Alberta Alberta is a Provinces and territories of Canada, province in Canada. It is a part of Western Canada and is one of the three Canadian Prairies, prairie provinces. Alberta is bordered by British Columbia to its west, Saskatchewan to its east, t ...
, and
Saskatchewan Saskatchewan is a Provinces and territories of Canada, province in Western Canada. It is bordered on the west by Alberta, on the north by the Northwest Territories, on the east by Manitoba, to the northeast by Nunavut, and to the south by the ...
) and the
federal government A federation (also called a federal state) is an entity characterized by a political union, union of partially federated state, self-governing provinces, states, or other regions under a #Federal governments, federal government (federalism) ...
signed the Eastern Canada Acid Rain Program. The provinces agreed to limit their combined sulfur dioxide emissions to 2.3 million tonnes by 1994. The Canada-US Air Quality Agreement was signed in 1991. In 1998, all federal, provincial, and territorial Ministers of Energy and Environment signed The Canada-Wide Acid Rain Strategy for Post-2000, which was designed to protect lakes that are more sensitive than those protected by earlier policies.


In India

Acid rain was first reported in
Mumbai Mumbai ( ; ), also known as Bombay ( ; its official name until 1995), is the capital city of the Indian state of Maharashtra. Mumbai is the financial capital and the most populous city proper of India with an estimated population of 12 ...
(then Bombay) in 1974. Acid rain has been a reported cause of decrease in soil pH, especially in the areas of northeast, coastal regions of
Karnataka Karnataka ( ) is a States and union territories of India, state in the southwestern region of India. It was Unification of Karnataka, formed as Mysore State on 1 November 1956, with the passage of the States Reorganisation Act, 1956, States Re ...
,
Kerala Kerala ( , ) is a States and union territories of India, state on the Malabar Coast of India. It was formed on 1 November 1956, following the passage of the States Reorganisation Act, by combining Malayalam-speaking regions of the erstwhile ...
,
Odisha Odisha (), formerly Orissa (List of renamed places in India, the official name until 2011), is a States and union territories of India, state located in East India, Eastern India. It is the List of states and union territories of India by ar ...
,
Bihar Bihar ( ) is a states and union territories of India, state in Eastern India. It is the list of states and union territories of India by population, second largest state by population, the List of states and union territories of India by are ...
, and
West Bengal West Bengal (; Bengali language, Bengali: , , abbr. WB) is a States and union territories of India, state in the East India, eastern portion of India. It is situated along the Bay of Bengal, along with a population of over 91 million inhabi ...
. The spread of acid rain over India was first studied by a team of researchers in 1989. Increased risk might be posed by the expected rise in total sulphur emissions from 4,400 kilotonnes (kt) in 1990 to 6,500 kt in 2000, 10,900 kt in 2010 and 18,500 in 2020. Damage to
Taj Mahal The Taj Mahal ( ; ; ) is an ivory-white marble mausoleum on the right bank of the river Yamuna in Agra, Uttar Pradesh, India. It was commissioned in 1631 by the fifth Mughal Empire, Mughal emperor, Shah Jahan () to house the tomb of his belo ...
is a popular example of acid rain's corrosive effect in India.


Emissions of chemicals leading to acidification

The most important gas which leads to acidification is sulfur dioxide. Emissions of nitrogen oxides which are oxidized to form
nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
are of increasing importance due to stricter controls on emissions of sulfur compounds. 70 Tg(S) per year in the form of SO2 comes from fossil fuel combustion and industry, 2.8 Tg(S) from
wildfires A wildfire, forest fire, or a bushfire is an unplanned and uncontrolled fire in an area of Combustibility and flammability, combustible vegetation. Depending on the type of vegetation present, a wildfire may be more specifically identified as a ...
, and 7–8 Tg(S) per year from
volcanoes A volcano is commonly defined as a vent or fissure in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often fo ...
.Berresheim, H.; Wine, P.H. and Davies D.D. (1995). "Sulfur in the Atmosphere". In ''Composition, Chemistry and Climate of the Atmosphere'', ed. H.B. Singh. Van Nostrand Rheingold


Natural phenomena

The principal natural
phenomena A phenomenon ( phenomena), sometimes spelled phaenomenon, is an observable Event (philosophy), event. The term came into its modern Philosophy, philosophical usage through Immanuel Kant, who contrasted it with the noumenon, which ''cannot'' be ...
that contribute acid-producing gases to the
atmosphere An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
are emissions from volcanoes. Thus, for example, fumaroles from the Laguna Caliente crater of Poás Volcano create extremely high amounts of acid rain and fog, with acidity as high as a pH of 2, clearing an area of any vegetation and frequently causing irritation to the eyes and lungs of inhabitants in nearby settlements. Acid-producing gasses are also created by biological processes that occur on the land, in
wetland A wetland is a distinct semi-aquatic ecosystem whose groundcovers are flooded or saturated in water, either permanently, for years or decades, or only seasonally. Flooding results in oxygen-poor ( anoxic) processes taking place, especially ...
s, and in the
ocean The ocean is the body of salt water that covers approximately 70.8% of Earth. The ocean is conventionally divided into large bodies of water, which are also referred to as ''oceans'' (the Pacific, Atlantic, Indian Ocean, Indian, Southern Ocean ...
s. The major biological source of sulfur compounds is dimethyl sulfide. Nitric acid in
rain Rain is a form of precipitation where water drop (liquid), droplets that have condensation, condensed from Water vapor#In Earth's atmosphere, atmospheric water vapor fall under gravity. Rain is a major component of the water cycle and is res ...
water is an important source of fixed
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
for plant life, and is also produced by electrical activity in the atmosphere such as
lightning Lightning is a natural phenomenon consisting of electrostatic discharges occurring through the atmosphere between two electrically charged regions. One or both regions are within the atmosphere, with the second region sometimes occurring on ...
. Acidic deposits have been detected in glacial ice thousands of years old in remote parts of the globe.


Human activity

The principal cause of acid rain is sulfur and nitrogen compounds from human sources, such as
electricity generation Electricity generation is the process of generating electric power from sources of primary energy. For electric utility, utilities in the electric power industry, it is the stage prior to its Electricity delivery, delivery (Electric power transm ...
, animal agriculture, factories, and
motor vehicle A motor vehicle, also known as a motorized vehicle, automotive vehicle, automobile, or road vehicle, is a self-propelled land vehicle, commonly wheeled, that does not operate on railway track, rails (such as trains or trams), does not fly (such ...
s. These also include power plants, which use electric power generators that account for a quarter of nitrogen oxides and two-thirds of sulfur dioxide within the atmosphere. Industrial acid rain is a substantial problem in China and Russia and areas downwind from them. These areas all burn sulfur-containing
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
to generate heat and electricity. The problem of acid rain has not only increased with population and industrial growth, but has become more widespread. The use of tall smokestacks to reduce local
pollution Pollution is the introduction of contaminants into the natural environment that cause harm. Pollution can take the form of any substance (solid, liquid, or gas) or energy (such as radioactivity, heat, sound, or light). Pollutants, the component ...
has contributed to the spread of acid rain by releasing gases into regional atmospheric circulation; dispersal from these taller stacks causes pollutants to be carried farther, causing widespread ecological damage. Often deposition occurs a considerable distance downwind of the emissions, with mountainous regions tending to receive the greatest deposition (because of their higher rainfall). An example of this effect is the low pH of rain which falls in
Scandinavia Scandinavia is a subregion#Europe, subregion of northern Europe, with strong historical, cultural, and linguistic ties between its constituent peoples. ''Scandinavia'' most commonly refers to Denmark, Norway, and Sweden. It can sometimes also ...
. Regarding low pH and pH imbalances in correlation to acid rain, low levels, or those under the pH value of 7, are considered acidic. Acid rain falls at a pH value of roughly 4, making it harmful to consume for humans. When these low pH levels fall in specific regions, they not only affect the environment but also human health. With acidic pH levels in humans comes hair loss, low urinary pH, severe mineral imbalances, constipation, and many cases of chronic disorders like Fibromyalgia and Basal Carcinoma.


Chemical process

Combustion of fuels and smelting of some ores produce sulfur dioxide and nitric oxides. They are converted into sulfuric acid and nitric acid. In the gas phase sulfur dioxide is oxidized to
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
: : Nitrogen dioxide reacts with hydroxyl radicals to form nitric acid: :NO2 + OH· → HNO3 The detailed mechanisms depend on the presence water and traces of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
and
manganese Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition m ...
. A number of oxidants are capable of these reactions aside from O2, these include
ozone Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
,
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscosity, viscous than Properties of water, water. It is used as an oxidizer, bleaching agent, and antiseptic, usua ...
, and
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
.


Acid deposition


Wet deposition

Wet deposition of acids occurs when any form of precipitation (rain, snow, and so on) removes acids from the atmosphere and delivers it to the Earth's surface. This can result from the deposition of acids produced in the raindrops (see aqueous phase chemistry above) or by the precipitation removing the acids either in clouds or below clouds. Wet removal of both gases and aerosols are both of importance for wet deposition.


Dry deposition

Acid deposition also occurs via dry deposition in the absence of precipitation. This can be responsible for as much as 20 to 60% of total acid deposition. This occurs when particles and gases stick to the ground, plants or other surfaces.


Adverse effects

Acid rain has been shown to have adverse impacts on forests, freshwaters and soils, killing insect and aquatic life-forms as well as causing damage to buildings and having impacts on human health.


Surface waters and aquatic animals

Sulfuric acid and nitric acid have multiple impacts on aquatic ecosystems, including acidification, increased nitrogen and aluminum content, and alteration of biogeochemical processes. Both the lower pH and higher aluminium concentrations in surface water that occur as a result of acid rain can cause damage to fish and other aquatic animals. At pH lower than 5 most fish eggs will not hatch and lower pH can kill adult fish. As lakes and rivers become more acidic, biodiversity is reduced. Acid rain has eliminated insect life and some fish species, including the brook trout in some lakes, streams, and creeks in geographically sensitive areas, such as the
Adirondack Mountains The Adirondack Mountains ( ) are a massif of mountains in Northeastern New York which form a circular dome approximately wide and covering about . The region contains more than 100 peaks, including Mount Marcy, which is the highest point in Ne ...
of the United States. However, the extent to which acid rain contributes directly or indirectly via runoff from the catchment to lake and river acidity (i.e., depending on characteristics of the surrounding watershed) is variable. The United States Environmental Protection Agency's (EPA) website states: "Of the lakes and streams surveyed, acid rain caused acidity in 75% of the acidic lakes and about 50% of the acidic streams". Lakes hosted by silicate basement rocks are more acidic than lakes within limestone or other basement rocks with a carbonate composition (i.e. marble) due to buffering effects by carbonate minerals, even with the same amount of acid rain.


Soils

Soil biology Soil biology is the study of microbial and faunal activity and ecology in soil. Soil life, soil biota, soil fauna, or edaphon is a collective term that encompasses all organisms that spend a significant portion of their life cycle within a so ...
and chemistry can be seriously damaged by acid rain. Some microbes are unable to tolerate changes to low pH and are killed. The
enzyme An enzyme () is a protein that acts as a biological catalyst by accelerating chemical reactions. The molecules upon which enzymes may act are called substrate (chemistry), substrates, and the enzyme converts the substrates into different mol ...
s of these microbes are denatured (changed in shape so they no longer function) by the acid. The hydronium ions of acid rain also mobilize
toxin A toxin is a naturally occurring poison produced by metabolic activities of living cells or organisms. They occur especially as proteins, often conjugated. The term was first used by organic chemist Ludwig Brieger (1849–1919), derived ...
s, such as aluminium, and leach away essential nutrients and minerals such as
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
.US EPA
Effects of Acid Rain – Forests
:2 H+ (aq) + Mg2+ (clay) 2 H+ (clay) + Mg2+ (aq) Soil chemistry can be dramatically changed when base cations, such as calcium and magnesium, are leached by acid rain, thereby affecting sensitive species, such as sugar maple (
Acer saccharum ''Acer saccharum'', the sugar maple, is a species of flowering plant in the soapberry and lychee family Sapindaceae. It is native to the hardwood forests of eastern Canada and the eastern United States. Sugar maple is best known for being the p ...
). Soil acidification Impacts of acidic water and soil acidification on plants could be minor or in most cases major. Most minor cases which do not result in fatality of plant life can be attributed to the plants being less susceptible to acidic conditions and/or the acid rain being less potent. However, even in minor cases, the plant will eventually die due to the acidic water lowering the plant's natural pH. Acidic water enters the plant and causes important plant minerals to dissolve and get carried away; which ultimately causes the plant to die of lack of minerals for nutrition. In major cases, which are more extreme, the same process of damage occurs as in minor cases, which is removal of essential minerals, but at a much quicker rate. Likewise, acid rain that falls on soil and on plant leaves causes drying of the waxy leaf cuticle, which ultimately causes rapid water loss from the plant to the outside atmosphere and eventually results in death of the plant. Soil acidification can lead to a decline in soil microbes as a result of a change in pH, which would have an adverse effect on plants due to their dependence on soil microbes to access nutrients. To see if a plant is being affected by soil acidification, one can closely observe the plant leaves. If the leaves are green and look healthy, the soil pH is normal and acceptable for plant life. But if the plant leaves have yellowing between the veins on their leaves, that means the plant is suffering from acidification and is unhealthy. Moreover, a plant suffering from soil acidification cannot photosynthesize; the acid-water-induced process of drying out of the plant can destroy chloroplast organelles. Without being able to photosynthesize, a plant cannot create nutrients for its own survival or oxygen for the survival of aerobic organisms, which affects most species on Earth and ultimately ends the purpose of the plant's existence.  


Forests and other vegetation

Adverse effects may be indirectly related to acid rain, like the acid's effects on soil (see above) or high concentration of gaseous precursors to acid rain. High altitude forests are especially vulnerable as they are often surrounded by clouds and fog which are more acidic than rain. Plants are capable of adapting to acid rain. On Jinyun Mountain,
Chongqing ChongqingPostal Romanization, Previously romanized as Chungking ();. is a direct-administered municipality in Southwestern China. Chongqing is one of the four direct-administered municipalities under the State Council of the People's Republi ...
, plant species were seen adapting to new environmental conditions. The affects on the species ranged from being beneficial to detrimental. With natural rainfall or mild acid rainfall, the biochemical and physiological characteristics of plant seedlings were enhanced. However, once the pH decreases below the threshold of 3.5, the acid rain can no longer be beneficial and begins to have negative affects. Acid rain can negatively impact photosynthesis in plant leaves, when leaves are exposed to a lower pH, photosynthesis is impacted due to the decline in chlorophyll. Acid rain also has the ability to cause deformation to leaves at a cellular level, examples include; tissue scaring and changes to the stomatal, epidermis and mesophyll cells. Additional impacts of acid rain includes a decline in cuticle thickness present on the leaf surface. Because acid rain damages leaves, this directly impacts a plants ability to have a strong canopy cover, a decline in canopy cover can lead plants to be more vulnerable to diseases. Dead or dying trees often appear in areas impacted by acid rain. Acid rain causes aluminum to leach from the soil, posing risks to both plant and animal life. Furthermore, it strips the soil of critical minerals and nutrients necessary for tree growth. At higher altitudes, acidic fog and clouds can deplete nutrients from tree foliage, leading to discolored or dead leaves and needles. This depletion compromises the trees' ability to absorb sunlight, weakening them and diminishing their capacity to endure cold conditions. Other plants can also be damaged by acid rain, but the effect on food crops is minimized by the application of lime and fertilizers to replace lost nutrients. In cultivated areas, limestone may also be added to increase the ability of the soil to keep the pH stable, but this tactic is largely unusable in the case of wilderness lands. When calcium is leached from the needles of red spruce, these trees become less cold tolerant and exhibit winter injury and even death. Acid rain may also affect crop productivity by necrosis or changes to soil nutrients, which ultimately prevent plants from reaching maturity.


Ocean acidification

Acid rain has a much less harmful effect on oceans on a global scale, but it creates an amplified impact in the shallower waters of coastal waters. Acid rain can cause the ocean's pH to fall, known as ocean acidification, making it more difficult for different coastal species to create their
exoskeleton An exoskeleton () . is a skeleton that is on the exterior of an animal in the form of hardened integument, which both supports the body's shape and protects the internal organs, in contrast to an internal endoskeleton (e.g. human skeleton, that ...
s that they need to survive. These coastal species link together as part of the ocean's food chain, and without them being a source for other marine life to feed off of, more marine life will die. Coral's limestone skeleton is particularly sensitive to pH decreases, because the
calcium carbonate Calcium carbonate is a chemical compound with the chemical formula . It is a common substance found in Rock (geology), rocks as the minerals calcite and aragonite, most notably in chalk and limestone, eggshells, gastropod shells, shellfish skel ...
, a core component of the limestone skeleton, dissolves in acidic (low pH) solutions. In addition to acidification, excess nitrogen inputs from the atmosphere promote increased growth of phytoplankton and other marine plants, which, in turn, may cause more frequent harmful algal blooms and
eutrophication Eutrophication is a general term describing a process in which nutrients accumulate in a body of water, resulting in an increased growth of organisms that may deplete the oxygen in the water; ie. the process of too many plants growing on the s ...
(the creation of oxygen-depleted "dead zones") in some parts of the ocean.


Human health effects

Acid rain can negatively impact human health, especially when people breathe in particles released from acid rain. The effects of acid rain on human health are complex and may be seen in several ways, such as respiratory issues for long-term exposure and indirect exposure through contaminated food and water sources.


Nitrogen Dioxide Effects

Exposure to air pollutants associated with acid rain, such as nitrogen dioxide (NO2), may have a negative impact on respiratory health. Water-soluble nitrogen dioxide accumulates in the tiny airways, where it is transformed into nitric and nitrous acids.
Pneumonia Pneumonia is an Inflammation, inflammatory condition of the lung primarily affecting the small air sacs known as Pulmonary alveolus, alveoli. Symptoms typically include some combination of Cough#Classification, productive or dry cough, ches ...
caused by
nitric acid Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most com ...
s directly damages the epithelial cells lining the airways, resulting in
pulmonary edema Pulmonary edema (British English: oedema), also known as pulmonary congestion, is excessive fluid accumulation in the tissue or air spaces (usually alveoli) of the lungs. This leads to impaired gas exchange, most often leading to shortness ...
. Exposure to nitrogen dioxide also reduces the immune response by inhibiting the generation of inflammatory
cytokine Cytokines () are a broad and loose category of small proteins (~5–25 kDa) important in cell signaling. Cytokines are produced by a broad range of cells, including immune cells like macrophages, B cell, B lymphocytes, T cell, T lymphocytes ...
s by
alveolar macrophage An alveolar macrophage, pulmonary macrophage, (or dust cell, or dust eater) is a type of macrophage, a phagocytosis#Professional phagocytic cells, professional phagocyte, found in the airways and at the level of the pulmonary alveolus, alveoli in ...
s in response to bacterial infection. In animal studies, the pollutant further reduces respiratory immunity by decreasing mucociliary clearance in the lower respiratory tract, which results in a reduced ability to remove respiratory infections.


Sulfur Trioxide Effects

The effects of sulfur trioxide and
sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, ...
are similar because they both produce sulfuric acid when they come into touch with the wet surfaces of your skin or
respiratory system The respiratory system (also respiratory apparatus, ventilatory system) is a biological system consisting of specific organs and structures used for gas exchange in animals and plants. The anatomy and physiology that make this happen varies grea ...
. The amount of SO3 breath through the mouth is larger than the amount of SO3 breath through the nose. When humans breathe in sulfur trioxide, small droplets of sulfuric acid will form inside the body and enter the
respiratory tract The respiratory tract is the subdivision of the respiratory system involved with the process of conducting air to the alveoli for the purposes of gas exchange in mammals. The respiratory tract is lined with respiratory epithelium as respirato ...
to the lungs depending on the particle size. The effects of SO3 on the respiratory system lead to breathing difficulty in people who have
asthma Asthma is a common long-term inflammatory disease of the airways of the lungs. It is characterized by variable and recurring symptoms, reversible airflow obstruction, and easily triggered bronchospasms. Symptoms include episodes of wh ...
symptoms. Sulfur trioxide also causes very corrosive and irritation on the skin, eye, and
gastrointestinal tract The gastrointestinal tract (GI tract, digestive tract, alimentary canal) is the tract or passageway of the Digestion, digestive system that leads from the mouth to the anus. The tract is the largest of the body's systems, after the cardiovascula ...
s when there is direct exposure to a specific concentration or long-term exposure. Consuming concentrated sulfuric acid has been known to burn the mouth and throat, erode a hole in the stomach, burns when it comes into contact with skin, make your eyes weep if it gets into them, and mortality.


Federal Government's recommendation


Nitrogen Dioxides

A 25 parts per million (ppm) maximum for nitric oxide in working air has been set by the Occupational Safety and Health Administration (OSHA) for an 8-hour workday and a 40-hour workweek. Additionally, OSHA has established a 5-ppm nitrogen dioxide exposure limit for 15 minutes in the workplace.


Sulfur Trioxide

The not-to-exceed limits in the air, water, soil, or food that are recommended by regulations are often based on levels that affect animals before being modified to assist in safeguarding people. Depending on whether they employ different animal studies, have different exposure lengths (e.g., an 8-hour workday versus a 24-hour day), or for other reasons, these not-to-exceed values can vary between federal bodies. The amount of sulfur dioxide that can be emitted into the atmosphere is capped by the EPA. This reduces the quantity of sulfur dioxide in the air that turns into sulfur trioxide and sulfuric acid. Sulfuric acid concentrations in workroom air are restricted by OSHA to 1 mg/m3. Moreover, NIOSH advises a time-weighted average limit of 1 mg/m3.


Other adverse effects

Acid rain can damage buildings, historic monuments, and statues, especially those made of rocks, such as
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
and
marble Marble is a metamorphic rock consisting of carbonate minerals (most commonly calcite (CaCO3) or Dolomite (mineral), dolomite (CaMg(CO3)2) that have recrystallized under the influence of heat and pressure. It has a crystalline texture, and is ty ...
, that contain large amounts of calcium carbonate. Acids in the rain react with the calcium compounds in the stones to create gypsum, which then flakes off. :CaCO3 (s) + H2SO4 (aq) CaSO4 (s) + CO2 (g) + H2O (l) The effects of this are commonly seen on old gravestones, where acid rain can cause the inscriptions to become completely illegible. Acid rain also increases the
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
rate of metals, in particular
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
,
steel Steel is an alloy of iron and carbon that demonstrates improved mechanical properties compared to the pure form of iron. Due to steel's high Young's modulus, elastic modulus, Yield (engineering), yield strength, Fracture, fracture strength a ...
,
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
and
bronze Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals (such as phosphorus) or metalloid ...
.


Affected areas

Places significantly impacted by acid rain around the globe include most of eastern Europe from Poland northward into Scandinavia, the eastern third of the United States, and southeastern
Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...
. Other affected areas include the southeastern coast of China and
Taiwan Taiwan, officially the Republic of China (ROC), is a country in East Asia. The main geography of Taiwan, island of Taiwan, also known as ''Formosa'', lies between the East China Sea, East and South China Seas in the northwestern Pacific Ocea ...
.


Prevention methods


Technical solutions

Many coal-firing
power station A power station, also referred to as a power plant and sometimes generating station or generating plant, is an industrial facility for the electricity generation, generation of electric power. Power stations are generally connected to an electr ...
s use flue-gas desulfurization (FGD) to remove sulfur-containing gases from their stack gases. For a typical coal-fired power station, FGD will remove 95% or more of the SO2 in the flue gases. An example of FGD is the wet scrubber which is commonly used. A wet scrubber is basically a reaction tower equipped with a fan that extracts hot smoke stack gases from a power plant into the tower. Lime or limestone in slurry form is also injected into the tower to mix with the stack gases and combine with the sulfur dioxide present. The calcium carbonate of the limestone produces pH-neutral calcium sulfate that is physically removed from the scrubber. That is, the scrubber turns sulfur pollution into industrial sulfates. In some areas the sulfates are sold to chemical companies as gypsum when the purity of calcium sulfate is high. In others, they are placed in
landfill A landfill is a site for the disposal of waste materials. It is the oldest and most common form of waste disposal, although the systematic burial of waste with daily, intermediate and final covers only began in the 1940s. In the past, waste was ...
. The effects of acid rain can last for generations, as the effects of pH level change can stimulate the continued leaching of undesirable chemicals into otherwise pristine water sources, killing off vulnerable insect and fish species and blocking efforts to restore native life. Fluidized bed combustion also reduces the amount of sulfur emitted by power production. Vehicle emissions control reduces emissions of nitrogen oxides from motor vehicles.


International treaties

International treaties on the long-range transport of atmospheric pollutants have been agreed upon by western countries for some time now. Beginning in 1979, European countries convened in order to ratify general principles discussed during the UNECE Convention. The purpose was to combat Long-Range Transboundary Air Pollution. The 1985 Helsinki Protocol on the Reduction of Sulfur Emissions under the Convention on Long-Range Transboundary Air Pollution furthered the results of the convention. Results of the treaty have already come to fruition, as evidenced by an approximate 40 percent drop in particulate matter in North America. The effectiveness of the Convention in combatting acid rain has inspired further acts of international commitment to prevent the proliferation of particulate matter. Canada and the US signed the Air Quality Agreement in 1991. Most European countries and Canada signed the treaties. Activity of the Long-Range Transboundary Air Pollution Convention remained dormant after 1999, when 27 countries convened to further reduce the effects of acid rain. In 2000, foreign cooperation to prevent acid rain was sparked in Asia for the first time. Ten diplomats from countries ranging throughout the continent convened to discuss ways to prevent acid rain. Following these discussions, the Acid Deposition Monitoring Network in East Asia (EANET) was established in 2001 as an intergovernmental initiative to provide science-based inputs for decision makers and promote international cooperation on acid deposition in East Asia. In 2023, the EANET member countries include Cambodia, China, Indonesia, Japan, Lao PDR, Malaysia, Mongolia, Myanmar, the Philippines, Republic of Korea, Russia, Thailand and Vietnam.


Emissions trading

In this regulatory scheme, every current polluting facility is given or may purchase on an open market an emissions allowance for each unit of a designated pollutant it emits. Operators can then install pollution control equipment, and sell portions of their emissions allowances they no longer need for their own operations, thereby recovering some of the capital cost of their investment in such equipment. The intention is to give operators economic incentives to install pollution controls. The first emissions trading market was established in the United States by enactment of the Clean Air Act Amendments of 1990. The overall goal of the Acid Rain Program established by the ActClean Air Act Amendments of 1990, 42 ''U.S. Code'
7651
is to achieve significant environmental and public health benefits through reductions in emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx), the primary causes of acid rain. To achieve this goal at the lowest cost to society, the program employs both regulatory and market based approaches for controlling air pollution.


See also

* Alkaline precipitation * Citizen science – one of two 'first uses' of the term was in an acid rain campaign in 1989. * List of environmental issues * Lists of environmental topics * Ocean acidification * Rain dust (an ''alkaline rain'') * Soil retrogression and degradation


References


Further reading

* Ritchie, Hannah, "What We Learned from Acid Rain: By working together, the nations of the world can solve
climate change Present-day climate change includes both global warming—the ongoing increase in Global surface temperature, global average temperature—and its wider effects on Earth's climate system. Climate variability and change, Climate change in ...
", ''
Scientific American ''Scientific American'', informally abbreviated ''SciAm'' or sometimes ''SA'', is an American popular science magazine. Many scientists, including Albert Einstein and Nikola Tesla, have contributed articles to it, with more than 150 Nobel Pri ...
'', vol. 330, no. 1 (January 2024), pp. 75–76. " untries will act only if they know others are willing to do the same. With acid rain, they did act collectively.... We did something similar to restore Earth's protective
ozone layer The ozone layer or ozone shield is a region of Earth's stratosphere that absorption (electromagnetic radiation), absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the a ...
.... e cost of technology really matters.... In the past decade the price of
solar energy Solar energy is the radiant energy from the Sun's sunlight, light and heat, which can be harnessed using a range of technologies such as solar electricity, solar thermal energy (including solar water heating) and solar architecture. It is a ...
has fallen by more than 90 percent and that of wind energy by more than 70 percent. Battery costs have tumbled by 98 percent since 1990, bringing the price of
electric car An electric car or electric vehicle (EV) is a passenger car, passenger automobile that is propelled by an electric motor, electric traction motor, using electrical energy as the primary source of propulsion. The term normally refers to a p ...
s down with them.... e stance of elected officials matters more than their
party A party is a gathering of people who have been invited by a Hospitality, host for the purposes of socializing, conversation, recreation, or as part of a festival or other commemoration or celebration of a special occasion. A party will oft ...
affiliation.... Change can happen – but not on its own. We need to drive it." (p. 76.)


External links


National Acid Precipitation Assessment Program Report
– a 98-page report to Congress (2005)


Acid rain for schools – Hubbard Brook
* United States Environmental Protection Agency â€

(superficial)

(more depth than ref. above) * U.S. Geological Survey â€


Acid Rain: A Continuing National Tragedy
– a report from The Adirondack Council on acid rain in the Adirondack region (1998)
What Happens to Acid Rain?


* [https://www.eanet.asia/resource/fourth-report-for-policy-makers-towards-clean-air-for-sustainable-future-in-east-asia-through-collaborative-activities/ Fourth Report for Policy Makers (RPM4): Towards Clean Air for Sustainable Future in East Asia through Collaborative Activities]- a report for policy-makers, Acid Deposition Monitoring Network in East Asia, EANET, (2019). {{Authority control Rain Pollution Air pollution Water pollution Forest pathology Environmental chemistry Sulfuric acid