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2,6-Naphthalenedicarboxylic acid is an
organic compound Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co ...
with the formula C10H6(CO2H)2. This colorless solid is one of several isomers of naphthalenedicarboxylic acid. It is a precursor to the high performance polyester
polyethylene naphthalate Polyethylene naphthalate (poly(ethylene 2,6-naphthalate) or PEN) is a polyester derived from naphthalene-2,6-dicarboxylic acid and ethylene glycol. As such it is related to poly(ethylene terephthalate), but with superior barrier properties. Prod ...
(PEN, poly(ethylene-2,6-naphthalene dicarboxylate)). It is also used in the synthesis of some metal-organic frameworks.


Preparation

It was first prepared by Robert Evert and in 1876 by hydrolysis of 2,6-dicyanonaphthalene. 1,8-Naphthalenedicarboxylic acid can be isomerized to 2,6-naphthalenedicarboxylic acid via the intermediacy of the dipotassium dicarboxylates. It is also produced by oxidation of 2,6-diisopropylnaphthalene..


References

Dicarboxylic acids Naphthalenes {{aromatic-stub