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Veining (metallurgy)
In metallurgy a veining (or ''finning'') is the occurrence of a sheet like casting defect, produced by molten metal penetration into a sand casting mould. Description Veining occurs as 'vein' like projections from a casting, usually at right angles to the casting's surface; the phenonoma can occur in any alloy, and is commonly seen in ferrous or copper based castings. Veining has been attributed to temperature differences at distance from the molten metal resulting in differential thermal expansion in the sand leading to strain in, and failure of the sand mould. Research has shown that a main cause of veining is thermal expansion of the silica sand in combination with reduction in sand volume above 573C (after the alpha to beta silica phase transformation) due to softening/sintering and/or melting of sand grains, which results in cracking/voids. Veining can be reduced or avoided by the use of more refractory non-silica sands (zircon, chromite etc); by flux additives which lower ...
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Sand Casting
Sand casting, also known as sand molded casting, is a metal casting process characterized by using sand—known as ''casting sand''—as the mold material. The term "sand casting" can also refer to an object produced via the sand casting process. Sand castings are produced in specialized factories called foundries. In 2003, over 60% of all metal castings were produced via sand casting. Molds made of sand are relatively cheap, and sufficiently refractory even for steel foundry use. In addition to the sand, a suitable bonding agent (usually clay) is mixed or occurs with the sand. The mixture is moistened, typically with water, but sometimes with other substances, to develop the strength and plasticity of the clay and to make the aggregate suitable for molding. The sand is typically contained in a system of frames or mold boxes known as a flask. The mold cavities and gate system are created by compacting the sand around models called patterns, by carving directly into the san ...
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Zircon
Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green. The name derives from the Persian ''zargun'', meaning "gold-hued". This word is changed into " jargoon", a term applied to light-colored zircons. The English word "zircon" is derived from ''Zirkon'', which is the German adaptation of this word. Yellow, orange, and red zircon is also known as " hyacint ...
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Chromite
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of Iron, FeChromium, Cr2Oxygen, O4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (Magnesium, MgChromium, Cr2Oxygen, O4). Substitution of the element aluminium can also occur, leading to hercynite (Iron, FeAluminum, Al2Oxygen, O4). Chromite today is mined particularly to make stainless steel through the production of ferrochrome (Iron, FeChromium, Cr), which is an iron-chromium alloy. Chromite grains are commonly found in large mafic igneous intrusions such as the Bushveld in South Africa and India. Chromite is iron-black in color with a metallic Lustre (mineralogy), luster, a dark brown Streak (mineralogy), streak and a hardness on the Mohs scale of mineral hardness, Mohs scale of 5.5. Properties Chromite ...
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Tridymite
Tridymite is a high-temperature polymorphism (materials science), polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is silicon, Sioxygen, O2. Tridymite was first described in 1868 and the Type locality (geology), type location is in Hidalgo, Mexico. The name is from the Greek (language), Greek ''tridymos'' for ''triplet'' as tridymite commonly occurs as Crystal twinning, twinned crystal ''wikt:trilling, trillings'' (compound crystals comprising three twinned crystal components). Structure Tridymite can occur in seven crystalline forms. Two of the most common at standard pressure are known as α and β. The α-tridymite phase is favored at elevated temperatures (above 870 °C) and it converts to β-cristobalite at 1,470 °C. However, tridymite does usually not form from pure β-quartz, one needs to add trace amounts of certain compounds to achieve t ...
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Cristobalite
Cristobalite ( ) is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, Si O2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico. It is used in dentistry as a component of alginate impression materials as well as for making models of teeth. Properties Metastability Cristobalite is stable only above 1470 °C, but can crystallize and persist metastably at lower temperatures. The persistence of cristobalite outside its thermodynamic stability range occurs because the transition from cristobalite to quartz or tridymite is "reconstructive", requiring the breaking up and reforming of the silica framework. These frameworks are composed of SiO4 tetrahedra in which every oxygen atom is shared with a neig ...
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Quartz Inversion
The room-temperature form of quartz, α-quartz, undergoes a reversible change in crystal structure at 573 °C to form β-quartz. This phenomenon is called an inversion, and for the α to β quartz inversion is accompanied by a linear expansion of 0.45%. This inversion can lead to cracking of ceramic ware if cooling occurs too quickly through the inversion temperature. This is called ''dunting'', and the resultant faults are known as ''dunts''. To avoid such thermal shock faults, cooling rates not exceeding 50 °C/hour have been recommended. At 870 °C quartz ceases to be stable but, in the absence of fluxes, does not alter until a much higher temperature is reached, when, depending on the temperature and nature of the fluxes present, it is converted into the polymorphs of cristobalite and / or tridymite. These polymorphs also experience temperature-induced inversions. The inversion of cristobalite at 220 °C can be advantageous to achieve the ''cristobalite squ ...
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