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Uranium Carbonate
Uranyl carbonate refers to the inorganic compound with the formula UO2CO3. Also known by its mineral name rutherfordine, this material consists of uranyl (UO22+) and carbonate (CO32-). Like most uranyl salts, the compound is a polymeric, each uranium(VI) center being bonded to eight O atoms. Hydrolysis products of rutherfordine are also found in both the mineral and organic fractions of coal and its fly ash and is the main component of uranium in mine tailing seepage water. __TOC__ Uranyl carbonates as a class of materials Many uranyl carbonates exist, rutherfordine being the simplest stoichiometry. Most uranyl carbonates additional components including water and diverse anions and cations. A common method for concentrating uranium from a solution uses solutions of uranyl carbonates, which are passed through a resin bed where the complex ions are transferred to the resin by ion exchange with a negative ion like chloride. After build-up of the uranium complex on the resin, the ur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranyl Compounds
The uranyl ion with the chemical formula has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen, with uranium in the oxidation state +6. Four or more ligands may be bound to the uranyl ion in an equatorial plane around the uranium atom. The uranyl ion forms many complexes, particularly with ligands that have oxygen donor atoms. Complexes of the uranyl ion are important in the extraction of uranium from its ores and in nuclear fuel reprocessing. Structure and bonding The uranyl ion is linear and symmetrical, specifically belonging to the D∞h point group, with both U–O bond lengths of about 180 pm. The bond lengths are indicative of the presence of multiple bonding between the uranium and oxygen atoms. Since uranium(VI) has the electronic configuration of the preceding noble gas, radon, the electrons used in forming the U–O bonds are supplied by the oxygen atoms. The electrons are donated into empty atomic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Znucalite
Znucalite or CaZn11(UO2)(CO3)3(OH)20·4(H2O) is a rare, radioactive, white to pale cream colored uranium-containing carbonate mineral, hydrated calcium zinc uranyl carbonate hydroxide. Znucalite crystallizes in the orthorhombic system, often forming aggregates or crusts, and is found as a rare secondary species in carbonate-hosted (meaning it is mined from carbonate containing formations such as limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...) polymetallic veins, and nearby oxidizing uranium veins; on dump material and coating mine walls, apparently of post-mine origin. It fluoresces yellow-green under UV light. It was first described in 1989, after being discovered in Lill Mine, Černojamské deposit (Black pits deposit) in the Czech Republic. It was named in 1990 by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zellerite
Zellerite is a uranium mineral, named after its discoverer, geologist Howard Davis Zeller. It has a type locality of the Lucky MC uranium mine in Wyoming, USA. It was approved by the IMA in 1965, but was first published a year after its approval. Properties Zellerite is a dimorph of meyrowitzite. It is a uranyl carbonate. It is an acicular mineral, and occurs in crystals that resemble the shape of needles. It can occur as fine hairlike fibers as well. The size of each crystal is up to 2 mm, and it grows in roughly radial aggregates, veinlets, and incrustations. Elongation is possible. It has pleochroic attributes, which is an optical phenomenon. Depending on which axis the specimen is being inspected, it can occur as it changes color. Upon being inspected on the x or y axis, the mineral can seem to be colorless, but on the z axis, it is seen in a pale yellow color. The mineral also shows luminescence. Under both a short wave and a long wave ultraviolet light, it fluoresces i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wyartite
Wyartite ·7H2O is a uranium bearing mineral named after Jean Wyart (1902–1992), mineralogist at the Sorbonne, Paris. It has greenish-black, black, or violet-black, translucent to opaque orthorhombic crystals. It has a hardness of 3 to 4 on the Mohs scale. Its other names are ianthinite (of Bignand), wyartit and wyartita. It belongs to the uranium carbonate group of minerals. It is found next to rutherfordine in Shinkolobwe, Shaba, Zaire. Determination of the structure of wyartite provided the first evidence for a pentavalent uranium mineral. Like all uranium minerals it is radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside .... References Uranium minerals Calcium minerals Carbonate minerals Orthorhombic minerals Minerals in space group 19 Uranium(V) compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Schröckingerite
Schröckingerite is a radioactive yellow uranium-containing carbonate mineral, hydrated sodium calcium uranyl sulfate carbonate fluoride.http://www.webmineral.com/data/Schrockingerite.shtml Webmineralhttp://www.mindat.org/min-3584.html Mindat Schröckingerite crystallizes in the orthorhombic system, occurring as globular clusters, and fluoresces yellow-green under ultraviolet light. Schröckingerite was first described in 1783 from an occurrence in Jáchymov, Bohemia, Czech Republic The Czech Republic, also known as Czechia, and historically known as Bohemia, is a landlocked country in Central Europe. The country is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the south ..., and named for its discoverer, Julius Freiherr Schröckinger von Neudenberg (1814–1882). References External links Uranium(VI) minerals Carbonate minerals Sulfate minerals Triclinic minerals Minerals in space group 2 {{Carbonate-m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
