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Triphenyl
Terphenyls are a group of closely related aromatic hydrocarbons. Also known as diphenylbenzenes or triphenyls, they consist of a central benzene ring substituted with two phenyl groups. There are three substitution patterns: ''ortho''-terphenyl, ''meta''-terphenyl, and ''para''-terphenyl. Commercial grade terphenyl is generally a mixture of the three isomers. This mixture is used in the production of polychlorinated terphenyls, which were formerly used as heat storage and transfer agents.''p''-Terphenyl at chemicalland21.com ''p''-Terphenyl derivatives are found in various fungi and bacteria. One example is , a pigment found in some mushrooms. These natural ''p''-terphenyls are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triphenylene
Triphenylene is an organic compound with the formula (C6H4)3. It's a flat polycyclic aromatic hydrocarbon (PAH) that has a highly symmetric and planar structure consists of four fused benzene rings. Triphenylene has delocalized 18-''π''-electron systems based on a planar structure, corresponding to the symmetry group ''D''3h. It is more Resonance (chemistry), resonance stable than its isomers chrysene, Benz(a)anthracene, benz[''a'']anthracene, Benzo(c)phenanthrene, benzo[''c'']phenanthrene, and tetracene, hence resists hydrogenation. It is a light yellow powder, insoluble in water. Triphenylene serves as a fundamental building block in Discotic liquid crystal, discotic liquid crystals, where its planar, disc-like structure facilitates the formation of columnar mesophases, enabling applications in organic electronics. It's also being used as the base of covalent and metal organic frameworks. Discovery and First Synthesis Triphenylene was first separated by German Chemists H. Sc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phenyl Compounds
In organic chemistry, the phenyl group, or phenyl ring, is a cyclic group of atoms with the formula , and is often represented by the symbol Ph (archaically φ) or Ø. The phenyl group is closely related to benzene and can be viewed as a benzene ring, minus a hydrogen atom, which may be replaced by some other element or compound to serve as a functional group. A phenyl group has six carbon atoms bonded together in a hexagonal planar ring, five of which are bonded to individual hydrogen atoms, with the remaining carbon bonded to a substituent. Phenyl groups are commonplace in organic chemistry. Although often depicted with alternating double and single bonds, the phenyl group is chemically aromatic and has equal bond lengths between carbon atoms in the ring. Nomenclature Usually, a "phenyl group" is synonymous with and is represented by the symbol Ph (archaically, Φ), or Ø. Benzene is sometimes denoted as PhH. Phenyl groups are generally attached to other atoms or groups. Fo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Meta-terphenyl
''m''-Terphenyls (also known as meta-terphenyls, meta-diphenylbenzenes, or meta-triphenyls) are organic molecules composed of two Phenyl group, phenyl groups bonded to a benzene ring in the one and three positions. The simplest formula is C18H14, but many different substituents can be added to create a diverse class of molecules. Due to the extensive Conjugated system, pi-conjugated system, the molecule it has a range of optical properties and because of its size, it is used to control the Steric effects, sterics in reactions with metals and Main-group element, main group elements. This is because of the disubstituted phenyl rings, which create a pocket for molecules and elements to bond without being connected to anything else. It is a popular choice in ligand, and the most chosen amongst the terphenyls because of its benefits in regards to sterics. Although many commercial methods exist to create m-terphenyl compounds, they can also be found naturally in plants such as mulberry t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polychlorinated Terphenyl
Polychlorinated terphenyls (PCTs) are a group of chlorine derivatives of terphenyls. They are chemically related to polychlorinated biphenyls and have similar chemical properties. They have very low electrical conductivity, high heat stability, and high resistance to alkalies and strong acids. They are non-flammable and insoluble in water. Typically produced and used as mixtures with varying degrees of chlorination, PCTs were once used as heat transfer agents in electric transformers, as plasticizers, as lubricating oils, and as flame retardants. Their production and use has been largely phased out due to environmental and safety concerns. International trade in PCTs is regulated by the Rotterdam Convention The Rotterdam Convention (formally, the Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade) is a multilateral treaty to promote shared responsibilities in relatio .... References {{ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terthiophene
Terthiophene is the organic compound with the formula 4H3Ssub>2C4H2S. It is an oligomer of the heterocycle thiophene, a shorter oligomer is dithienyl, and the parent polymer is polythiophene. In the most common isomer of terthiophene, two thienyl groups are connected via their 2 positions to a central thiophene, also at the carbon atoms flanking the sulfur. Preparation of terthiophene Terthiophene is prepared by the nickel- or palladium-catalysed coupling reaction of 2,5-dibromothiophene with the Grignard reagent derived from 2-bromothiophene. Properties and applications This substance is likely responsible for the insecticidal activity of ''Tagetes minuta'' as it can react with light and oxygen to make singlet oxygen. Together with derivatives of 2,2'-bithiophene, various chlorinated terthiophenes occur naturally in thistles. Terthiophene has been employed as building block for the organic semi-conductor polythiophene. See also * Biphenyl * Terphenyl * Terpyridine Terpyrid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aromatic Hydrocarbons
Aromatic compounds or arenes are organic compounds "with a chemistry typified by benzene" and "cyclically conjugated." The word "aromatic" originates from the past grouping of molecules based on odor, before their general chemical properties were understood. The current definition of aromatic compounds does not have any relation to their odor. Aromatic compounds are now defined as cyclic compounds satisfying Hückel's rule. Aromatic compounds have the following general properties: * Typically unreactive * Often non polar and hydrophobic * High carbon-hydrogen ratio * Burn with a strong sooty yellow flame, due to high C:H ratio * Undergo electrophilic substitution reactions and nucleophilic aromatic substitutions Arenes are typically split into two categories - benzoids, that contain a benzene derivative and follow the benzene ring model, and non-benzoids that contain other aromatic cyclic derivatives. Aromatic compounds are commonly used in organic synthesis and are involved in m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Reactor
A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons production and Research reactor, research. Fissile material, Fissile nuclei (primarily uranium-235 or plutonium-239) absorb single neutron, neutrons and split, releasing energy and multiple neutrons, which can induce further fission. Reactors stabilize this, regulating Neutron absorber, neutron absorbers and neutron moderator, moderators in the core. Fuel efficiency is exceptionally high; Enriched uranium#Low-enriched uranium (LEU), low-enriched uranium is 120,000 times more energy dense than coal. Heat from nuclear fission is passed to a working fluid Nuclear reactor#By coolant, coolant. In commercial reactors, this drives Turbine, turbines and electrical generator shafts. Some reactors are used for district heating, and isotopes, isoto ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Nuclear Reactor
An organic nuclear reactor, or organic cooled reactor (OCR), is a type of nuclear reactor that uses some form of organic fluid, typically a hydrocarbon substance like polychlorinated biphenyl (PCB), for cooling and sometimes as a neutron moderator as well. Using an organic fluid had a major advantage over conventional designs using water as the coolant. Water tends to corrode and dissolve metals, both the nuclear fuel and the reactor as a whole. To avoid corrosion of the fuel, it is formed into cylindrical pellets and then inserted in zirconium tubes or other "cladding" materials. The rest of the reactor has to be built out of materials that are both corrosion resistant and resistant to the effects of neutron embrittlement. In contrast, many common organic fluids are less corrosive to metals, allowing the fuel assemblies to be much simpler and the coolant pipes to be built of normal carbon steels instead of more expensive corrosion-resistant metals. Some organics also have the ad ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Moderated Reactor Experiment
The Organic Moderated Reactor Experiment (OMRE) was a 16 Megawatt thermal, MWt experimental Organic nuclear reactor, organic nuclear reactor that operated at the National Reactor Testing Station from 1957 to 1963 to explore the use of hydrocarbons as Nuclear reactor coolant, coolant, Neutron moderator, moderator, and Neutron reflector, reflector materials in power reactor conditions. Such organic compounds, organic fluids are non-corrosive, do not become highly neutron activation, activated under irradiation, and can operate at low pressure and moderate temperature. These characteristics were considered promising towards the goal of achieving economical commercial nuclear power. The information provided by OMRE established the credibility of the Organic nuclear reactor concept and led to the commercial demonstration at the Piqua Nuclear Generating Station. More recently, OMRE has been cited as providing key input and motivation for modern designs of such systems, aiming to help im ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Royal Society Of Chemistry
The Royal Society of Chemistry (RSC) is a learned society and professional association in the United Kingdom with the goal of "advancing the chemistry, chemical sciences". It was formed in 1980 from the amalgamation of the Chemical Society, the Royal Institute of Chemistry, the Faraday Society, and the Society for Analytical Chemistry with a new Royal Charter and the dual role of learned society and professional body. At its inception, the Society had a combined membership of 49,000 in the world. The headquarters of the Society are at Burlington House, Piccadilly, London. It also has offices in Thomas Graham House in Cambridge (named after Thomas Graham (chemist), Thomas Graham, the first president of the Chemical Society) where ''RSC Publishing'' is based. The Society has offices in the United States, on the campuses of The University of Pennsylvania and Drexel University, at the University City Science Center in Philadelphia, Pennsylvania, in both Beijing and Shanghai, People' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terpyridine
Terpyridine (2,2';6',2"-terpyridine, often abbreviated to Terpy or Tpy) is a heterocyclic compound derived from pyridine. It is a white solid that is soluble in most organic solvents. The compound is mainly used as a ligand in coordination chemistry. Synthesis Terpyridine was first synthesized by G. Morgan and F. H. Burstall in 1932 by the oxidative coupling of pyridines. This method, however, proceeded in low yields. More efficient syntheses have since been described, mainly starting from 2-acetylpyridine. One method produces an enaminone by the reaction of 2-acetylpyridine with N,N-dimethylformamide dimethyl acetal. The base-catalyzed reaction of 2-acetylpyridine with carbon disulfide followed by alkylation with methyl iodide gives C5H4NCOCH=C(SMe)2. Condensation of this species with 2-acetylpyridine forms the related 1,5-diketone, which condenses with ammonium acetate to form a terpyridine. Treatment of this derivative with Raney nickel removes the thioether group. Othe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
