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Trideuterium
Triatomic hydrogen or H3 is an unstable triatomic molecule containing only hydrogen. Since this molecule contains only three atoms of hydrogen it is the simplest triatomic molecule and it is relatively simple to numerically solve the quantum mechanics description of the particles. Being unstable the molecule breaks up in under a millionth of a second. Its fleeting lifetime makes it rare, but it is quite commonly formed and destroyed in the universe thanks to the commonness of the trihydrogen cation. The infrared spectrum of H3 due to vibration and rotation is very similar to that of the ion, . In the early universe this ability to emit infrared light allowed the primordial hydrogen and helium gas to cool down so as to form stars. Formation The neutral molecule can be formed in a low pressure gas discharge tube. A neutral beam of H3 can be formed from a beam of ions passing through gaseous potassium, which donates an electron to the ion, forming K+. Other gaseous alkali metals, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trihydrogen Cation
The trihydrogen cation or protonated molecular hydrogen ( IUPAC name: hydrogen onium ion) is a cation (positive ion) with formula , consisting of three hydrogen nuclei (protons) sharing two electrons. The trihydrogen cation is one of the most abundant ions in the universe. It is stable in the interstellar medium (ISM) due to the low temperature and low density of interstellar space. The role that plays in the gas-phase chemistry of the ISM is unparalleled by any other polyatomic ion. The trihydrogen cation is the simplest triatomic molecule, because its two electrons are the only valence electrons in the system. It is also the simplest example of a three-center two-electron bond system. History was first discovered by J. J. Thomson in 1911. While using an early form of mass spectrometry to study the resultant species of plasma discharges, he discovered a large abundance of a polyatomic ion with a mass-to-charge ratio of 3. He stated that the only two possibilities were ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triatomic Molecule
Triatomic molecules are molecules composed of three atoms, of either the same or different chemical elements. Examples include H2O, CO2 (pictured), HCN, O3 (ozone) and NO2. Molecular vibrations The vibrational modes of a triatomic molecule can be determined in specific cases. Symmetric linear molecules A symmetric linear molecule ABA can perform: * Antisymmetric longitudinal vibrations with frequency :\omega_a=\sqrt * Symmetric longitudinal vibrations with frequency :\omega_=\sqrt * Symmetric transversal vibrations with frequency :\omega_=\sqrt In the previous formulas, ''M'' is the total mass of the molecule, ''mA'' and ''mB'' are the masses of the elements A and B, ''k''1 and ''k''2 are the spring constants of the molecule along its axis and perpendicular to it. Types Homonuclear Homonuclear triatomic molecules contain three of the same kind of atom. That molecule will be an allotrope of that element. Ozone, O3 is an example of a triatomic molecule with all atoms ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Predissociation
Vibronic spectroscopy is a branch of molecular spectroscopy concerned with vibronic transitions: the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. In the gas phase, vibronic transitions are also accompanied by changes in rotational energy. Vibronic spectra of diatomic molecules have been analysed in detail; emission spectra are more complicated than absorption spectra. The intensity of allowed vibronic transitions is governed by the Franck–Condon principle. Vibronic spectroscopy may provide information, such as bond length, on electronic excited states of stable molecules. It has also been applied to the study of unstable molecules such as dicarbon (C2) in discharges, flames and astronomical objects.Hollas, p. 211. Principles Electronic transitions are typically observed in the visible and ultraviolet regions, in the wavelength range approximately 200–70 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ozone
Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lower atmosphere to (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the atmosphere, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation. Ozone's odor is reminiscent of chlorine, and detectable by many people at concentrations of as little as in air. Ozone's O3 chemical structure, structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetism, diamagnetic. At standard temperature and pressure, ozone is a pale blue gas that condenses at cryogenic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Joseph Lévine
Joseph is a common male name, derived from the Hebrew (). "Joseph" is used, along with "Josef (given name), Josef", mostly in English, French and partially German languages. This spelling is also found as a variant in the languages of the modern-day Nordic countries. In Portuguese language, Portuguese and Spanish language, Spanish, the name is "José". In Arabic, including in the Quran, the name is spelled , . In Kurdish language, Kurdish (''Kurdî''), the name is , Persian language, Persian, the name is , and in Turkish language, Turkish it is . In Pashto the name is spelled ''Esaf'' (ايسپ) and in Malayalam it is spelled ''Ousep'' (ഔസേപ്പ്). In Tamil language, Tamil, it is spelled as ''Yosepu'' (யோசேப்பு). The name has enjoyed significant popularity in its many forms in numerous countries, and ''Joseph'' was one of the two names, along with ''Robert'', to have remained in the top 10 boys' names list in the US from 1925 to 1972. It is especiall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Active Hydrogen
Nascent hydrogen is an outdated concept in organic chemistry that was once invoked to explain dissolving-metal reactions, such as the Clemmensen reduction and the Bouveault–Blanc reduction. Since organic compounds do not react with H2, a special state of hydrogen was postulated. It is now understood that dissolving-metal reactions occur at the metal surface, and the concept of nascent hydrogen has been discredited in organic chemistry. However, the formation of atomic hydrogen is largely invoked in inorganic chemistry and corrosion sciences to explain hydrogen embrittlement in metals exposed to electrolysis and anaerobic corrosion (e.g., dissolution of zinc in strong acids ( HCl) and aluminium in strong bases (NaOH)). The mechanism of hydrogen embrittlement was first proposed by Johnson (1875). The inability of hydrogen atoms to react with organic reagents in organic solvents does not exclude the transient formation of hydrogen atoms capable to immediately diffuse into the cryst ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alpha Particles
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produced in different ways. Alpha particles are named after the first letter in the Greek alphabet, α. The symbol for the alpha particle is α or α2+. Because they are identical to helium nuclei, they are also sometimes written as He2+ or 2+ indicating a helium ion with a +2 charge (missing its two electrons). Once the ion gains electrons from its environment, the alpha particle becomes a normal (electrically neutral) helium atom . Alpha particles have a net spin of zero. When produced in standard alpha radioactive decay, alpha particles generally have a kinetic energy of about 5 MeV and a velocity in the vicinity of 4% of the speed of light. They are a highly ionizing form of particle radiation, with low penetration depth (stopped by a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
William Duane (physicist)
William Duane (February 17, 1872 – March 7, 1935) was an American physicist who conducted research on radioactivity and X-rays and their usage in the treatment of cancer. He developed the Duane-Hunt Law and Duane's hypothesis. He worked with Pierre and Marie Curie in their University of Paris laboratory for six years and developed a method for generating quantities of radon-222 "seeds" from radium for usage in early forms of brachytherapy. He was a professor at the University of Colorado Boulder, professor-emeritus and chair of biophysics at Harvard University and research fellow of physics at the Harvard Cancer Commission. He received the John Scott Medal and the Comstock Prize in Physics in 1922 and the Leonard Prize of the American Roentgen Ray Society in 1923. Early life and education Duane was born in Philadelphia, Pennsylvania, to Charles William and Emma Cushman (Lincoln) Duane. He was a direct descendant of Benjamin Franklin from his father's side. He receive ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gerald Wendt
Gerald L. Wendt (1891-1973) was a chemist who became a writer and lecturer on popular science. He was director of science and education at the New York World's Fair, an editor at ''Time'' magazine and ''Science Illustrated'', and worked for UNESCO. Gerald Louis Wendt was born on 3 Mar 1891 in Davenport, Iowa. He was married twice and had a son by his first marriage. He died on 22 December 1973. Wendt graduated from Harvard with a BA (1913) and a PhD (1916) in chemistry. He saw war service as a researcher for the Army in the Chemical Warfare Service, and taught at the Rice Institute and the University of Chicago The University of Chicago (UChicago, Chicago, or UChi) is a Private university, private research university in Chicago, Illinois, United States. Its main campus is in the Hyde Park, Chicago, Hyde Park neighborhood on Chicago's South Side, Chic .... Wendt spent many years as a public lecturer and writer and was by 1938 a serious public scientist. He became director ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arthur Jeffrey Dempster
Arthur Jeffrey Dempster (August 14, 1886 – March 11, 1950) was a Canadian-American physicist best known for his work in mass spectrometry and his discovery in 1935 of the uranium isotope 235U. Early life and education Dempster was born in Toronto, Ontario, Canada. He received his bachelor's and master's degrees at the University of Toronto in 1909 and 1910, respectively. After spending a semester each at Gottingen and Munich, Germany, and two years at the University of Wurzburg under Wilhelm Wien he left at the outset of World War I for the United States; there he completed his Ph.D. in physics, graduating summa cum laude, at the University of Chicago originally begun in Germany under Wien. Academic career Dempster joined the physics faculty at the University of Chicago in 1916 and remained there until his death in 1950. He co-developed a double-focusing mass spectrograph in 1936 with the help of the Americans Kenneth T. Bainbridge and J.H.E. Mattauch of Austria. This a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Niels Bohr
Niels Henrik David Bohr (, ; ; 7 October 1885 – 18 November 1962) was a Danish theoretical physicist who made foundational contributions to understanding atomic structure and old quantum theory, quantum theory, for which he received the Nobel Prize in Physics in 1922. Bohr was also a philosopher and a promoter of scientific research. Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been supplanted by other models, its underlying principles remain valid. He conceived the principle of Complementarity (physics), complementarity: that items could be separately analysed in terms of contradictory properties, like behaving as a Wave–particle duality, wave or a stream of particles. The notion of complementarity dominated Bohr's thinking in both science and philoso ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Johannes Stark
Johannes Stark (; 15 April 1874 – 21 June 1957) was a German physicist who received the Nobel Prize in Physics in 1919 "for his discovery of the Doppler effect in canal rays and the splitting of spectral lines in electric fields". This phenomenon is known as the Stark effect. Stark received his Ph.D. in physics from the University of Munich in 1897 under the supervision of Eugen von Lommel, and served as Lommel's assistant until his appointment as a lecturer at the University of Göttingen in 1900. He was an extraordinary professor at Leibniz University Hannover from 1906 until he became a professor at RWTH Aachen University in 1909. In 1917, he became professor at the University of Greifswald, and he also worked at the University of Würzburg from 1920 to 1922. A supporter of Adolf Hitler from 1924, Stark was one of the main figures, along with fellow Nobel laureate Philipp Lenard, in the antisemitic '' Deutsche Physik'' movement, which sought to remove Jewish scientists ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
