|
Thujaplicin
Thujaplicin (isopropyl cycloheptatrienolone) is any of three isomeric tropolone-related natural products that have been isolated from the softwoods of the trees of ''Cupressaceae'' family. These compounds are known for their antibacterial, antifungal, and antioxidant properties. They were the first natural tropolones to be made synthetically. History Thujaplicins were discovered in the mid-1930s and purified from the heartwood of ''Thuja plicata'' Donn ex D. Don, commonly called as Western red cedar tree. These compounds were also identified in the constituents of ''Chamaecyparis obtusa'', another species from the ''Cupressaceae'' family. ''C. obtusa'' is native to East Asian countries including Japan and Taiwan, and is also known as ''Taiwan hinoki'', from which the β-thujaplicin was first isolated in 1936 and received its name, ''hinokitiol''. Thujaplicins were the first natural tropolones to be made synthetically, by Ralph Raphael and colleagues, and the β-thujaplicin w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Hinokitiol
Hinokitiol (β-thujaplicin) is a natural monoterpenoid found in the wood of trees in the family Cupressaceae. It is a tropolone derivative and one of the thujaplicins. Hinokitiol is used in oral and skin care products, and is a food additive used in Japan. History Hinokitiol was discovered by a Japanese chemist Tetsuo Nozoe in 1936. It was isolated from the essential oil component of the heartwood of '' Taiwanese hinoki'', from which the compound ultimately adopted its name. Hinokitiol is the first non- benzenoid aromatic compound identified. The compound has a heptagonal molecular structure and was first synthesized by Ralph Raphael in 1951. Due to its iron-chelating activity, hinokitiol has been called an "Iron Man molecule" in the scientific media, which is ironic because Tetsuo is translated into English as "Iron Man". Taiwanese hinoki is native to East Asian countries, particularly to Japan and Taiwan. Hinokitiol has also been found in other trees of the ''Cupressaceae' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Thuja Plicata
''Thuja plicata'' is a large evergreen coniferous tree in the family Cupressaceae, native to the Pacific Northwest of North America. Its common name is western redcedar in the U.S. or western red cedar in the UK, and it is also called pacific red cedar, giant arborvitae, western arborvitae, just cedar, giant cedar, or shinglewood. It is not a true cedar of the genus ''Cedrus''. ''T. plicata'' is the largest species in the genus ''Thuja'', growing up to tall and in diameter. It mostly grows in areas that experience a mild climate with plentiful rainfall, although it is sometimes present in drier areas on sites where water is available year-round, such as wet valley bottoms and mountain streamsides. The species is shade-tolerant and able to establish in forest understories and is thus considered a climax species. It is a very long-lived tree, with some specimens reaching ages of well over 1,000 years. Indigenous peoples of the Pacific Northwest use the wood of this species for ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Tetsuo Nozoe
Tetsuo Nozoe (野副 鉄男, 16 May 1902 – 4 April 1996) was a Japanese organic chemist. He is known for the discovery of hinokitiol, a seven-membered aromatic compound, and studying non-benzenoid aromatic compounds. Early life and career Tetsuo Nozoe was born on 16 May 1902 in Sendai to Juichi Nozoe, a lawyer and one-time member of the National Diet, and Toyo Nozoe. Tetsuo's family was Buddhist except of his mother who was a devout Christian. Tetsuo had three sisters and seven brothers, and he was the sixth child in the family. He started doing chemical experiments at home since his junior high school days. Although his parents wanted him to become a medical doctor, and even sent him for premedical classes, he proceeded his education with chemistry. After graduating from high school in Sendai, he entered the Department of Chemistry at Tohoku Imperial University in 1920. In university, he studied organic chemistry under Riko Majima, a leading scientist in organic chemistry ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Tropolone
Tropolone is an organic compound with the chemical formula . It is a pale yellow solid that is soluble in organic solvents. The compound has been of interest to research chemists because of its unusual electronic structure and its role as a ligand precursor. Although not usually prepared from tropone, it can be viewed as its derivative with a hydroxyl group in the 2-position. Synthesis and reactions Many methods have been described for the synthesis of tropolone. One involves bromination of 1,2-cycloheptanedione with ''N''-bromosuccinimide followed by dehydrohalogenation at elevated temperatures, while another uses acyloin condensation of the ethyl ester of pimelic acid the acyloin again followed by oxidation by bromine. : An alternate route is a +2 cycloaddition of cyclopentadiene with a ketene to give a bicyclo .2.0eptyl structure, followed by hydrolysis and breakage of the fusion bond to give the single ring: : Thy hydroxyl group of tropolone is acidic, having a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Thujopsis
''Thujopsis'' () is a genus of conifers in the cypress family (Cupressaceae), the sole member of which is ''Thujopsis dolabrata''. It is endemic to Japan, where it is known as ''asunaro'' (). It is similar to the closely related genus '' Thuja'' (arborvitae), differing in its broader, thicker leaves and cones. Etymology A popular allegory for the etymology of ''asunaro'' is ''asu wa hinoki ni narou'' (), literally "tomorrow it will become a hinoki cypress", i.e. the tree looks like a smaller version of the common hinoki cypress. In Japan, it is also known as ''hiba'' (), among many regional variations: asunaro is called ''ate'' () in Ishikawa, ''atebi'' on Sado Island, among other names. Outside of Japan, it is also known as false arborvitae or hiba arborvitae. Description ''Thujopsis'' is a medium to large evergreen tree, reaching up to 40 m tall and 1.5 m trunk diameter, with red-brown bark which peels in vertical strips. The leaves are arranged in decussate pairs, sc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Juniperus Californica
''Juniperus californica'', the California juniper, is a species of juniper native to southwestern North America. Description ''Juniperus californica'' is a shrub or small tree reaching , but rarely up to tall. The bark is ashy gray, typically thin, and appears to be "shredded". The shoots are fairly thick compared to most junipers, between in diameter. The foliage is bluish-gray and scale-like. The juvenile leaves (on the seedlings) are needle-like and long. Arranged in opposite decussate pairs or whorls of three, the adult leaves are scale-like, long on lead shoots and broad. The cones are berrylike, in diameter, blue-brown with a whitish waxy bloom, turning reddish-brown, and contain a single seed (rarely two or three). The seeds are mature in about 8 or 9 months. The male cones are long and shed their pollen in early spring. This juniper is largely dioecious, producing cones of only one sex, but around 2% of plants are monoecious, with both sexes on the same plant. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Juniperus Communis
''Juniperus communis'', the common juniper, is a species of small tree or shrub in the cypress family Cupressaceae. An evergreen conifer, it has the largest geographical range of any woody plant, with a circumpolar distribution throughout the cool temperate Northern Hemisphere. Description ''Juniperus communis'' is highly variable in form, ranging from —rarely —tall to a low, often prostrate spreading shrub in exposed locations. It has needle-like leaves in whorls of three; the leaves are green, with a single white stomatal band on the inner surface. It never attains the scale-like adult foliage of other members of the genus. It is dioecious, with male and female cones on separate plants so requiring wind pollination to transfer pollen from male to female cones. Male trees or shrubs naturally live longer than female trees or shrubs; a male tree or shrub can live more than 2000 years.Lena K. Ward, The Conservation of Juniper: Longevity and Old Age, Journal of Applied Ecology, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Juniperus Chinensis
''Juniperus chinensis'', the Chinese juniper, is a species of plant in the cypress family Cupressaceae, native to China, Myanmar, Japan, Korea and the Russian Far East. Growing tall, it is a very variable coniferous evergreen tree or shrub. A variety of ''Juniperus chinensis'' referred to as " Shimpaku" is one of the top species used in the Japanese art of bonsai. Among the multiple cultivars of Shimpaku found in Japan, the most desirable due to its tight, fine foliage and excellent growing habits, is the "Itoigawa" variety. Growth The leaves grow in two forms, juvenile needle-like leaves long, and adult scale-leaves 1.5–3 mm long. Mature trees usually continue to bear some juvenile foliage as well as adult, particularly on shaded shoots low in the crown. This species is often dioecious (either male or female plants), but some individual plants produce both sexes of flowers. The blue-black berry-like cones grow to 7–12 mm in diameter, have a whitish waxy b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Cupressus Macrocarpa
''Hesperocyparis macrocarpa'' also known as ''Cupressus macrocarpa'', or the Monterey cypress is a coniferous tree, and is one of several species of Cupressaceae, cypress trees native to California. The Monterey cypress is found naturally only on the Central Coast (California), Central Coast of California. Due to being a glacial relict, the natural distributional range of the species during modern times is confined to two small relict populations near Carmel-by-the-Sea, California, Carmel, California, at Cypress Point in Pebble Beach, California, Pebble Beach and at Point Lobos. Historically during the peak of the last ice age, Monterey cypress would have likely comprised a much larger forest that extended much further north and south.Axelrod, D. I. (1982)Age and origin of the Monterey endemic area.''Madroño'', ''29''(3), 127–147. Description ''Hesperocyparis macrocarpa'' is a medium-sized coniferous evergreen tree, which often becomes irregular and flat-topped as a resul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Cupressus Macnabiana
''Hesperocyparis macnabiana'' (MacNab cypress or Shasta cypress) is a species of western cypress in from California that was previously named ''Cupressus macnabiana''. Distribution ''Hesperocyparis macnabiana'' is endemic to northern California. ''Hesperocyparis macnabiana'' is one of the most widely distributed of all the native California cypresses, found growing in chaparral, oak woodlands, and coniferous woodlands habitats along the inner northern California Coast Ranges and the foothills of the northern Sierra Nevada. MacNab cypress is often associated with ultramafic soils. Description ''Hesperocyparis macnabiana'' is an evergreen shrub or small tree, (rarely to ) tall, with a spreading crown that is often broader than it is tall. The foliage is produced in dense, short flat sprays (unlike most other California cypresses, which do not have flattened sprays), bright glaucous gray-green, with a strong spicy-resinous scent. The leaves are scale-like, 1–2 mm long wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Cupressus Arizonica
''Hesperocyparis arizonica'', the Arizona cypress, is a North American species of tree in the cypress family Cupressaceae, native species, native to the southwestern United States and Mexico. Populations may be scattered rather than in large, dense stands. Description ''Hesperocyparis arizonica'' is a coniferous evergreen tree with a cone, conic to ovoid-conic crown. It grows to heights of , and its trunk diameter reaches . The foliage grows in dense sprays, varying from dull gray-green to bright glaucous blue-green. The leaves are scale-like, 2–5 mm long, and produced on rounded (not flattened) shoots. The seed conifer cone, cones are globose to oblong, 15–33 mm long, with 6 or 8 (rarely 4 or 10) scales, green at first, maturing gray or gray-brown about 20–24 months after pollination. The cones remain closed for many years, only opening after the bearing branch is killed (in a wildfire or otherwise), allowing the seeds to colonize the bare ground exposed by the f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
Chamaecyparis Thyoides
''Chamaecyparis thyoides'' (Atlantic white cedar, Atlantic white cypress, southern white cedar, whitecedar, or false-cypress), a species of ''Cupressaceae'', is native to the Atlantic coast of North America and is found from southern Maine to Georgia (U.S. state), Georgia and along the Gulf of Mexico coast from Florida to Mississippi. It is one of two species of ''Chamaecyparis'' found in North America. ''C. thyoides'' resides on the East Coast of the United States, East Coast and chamaecyparis lawsoniana, ''C. lawsoniana'' can be found on the West Coast of the United States, West Coast. There are two geographically isolated subspecies, treated by some botanists as distinct species, by others at just variety (biology), varietal rank: ''Chamaecyparis thyoides thyoides'' and ''Chamaecyparis thyoides henryae'' (H.L.Li) E.Murray (syn. ''Chamaecyparis thyoides'' subsp. ''henryae'' (H.L.Li) Little; ''Chamaecyparis henryae'' H.L.Li) The species grows in forested wetlands where they tend ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] [Amazon] |
