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Thiosilicate
In chemistry and materials science, thiosilicate refers to materials containing anions of the formula . Derivatives where some sulfide is replaced by oxide are also called thiosilicates, examples being materials derived from the oxohexathiodisilicate . Silicon is tetrahedral in all thiosilicates and sulfur is bridging or terminal. Formally such materials are derived from silicon disulfide in analogy to the relationship between silicon dioxide and silicates. Thiosilicates are typically encountered as colorless solids. They are characteristically sensitive to hydrolysis. They are from the class of chalcogenidotetrelates. Materials science The LISICON (LIthium Super Ionic CONductor) include thiosilicates, which are fast ion conductors. Thiosilicates and related thiogermanates are also of interest for infrared Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silicon Disulfide
Silicon disulfide is the inorganic compound with the formula Si S2. Like silicon dioxide, this material is polymeric, but it adopts a 1-dimensional structure quite different from the usual forms of SiO2. Synthesis, structure, and properties The material is formed by heating silicon and sulfur or by the exchange reaction between SiO2 and Al2S3. The material consists of chains of edge-shared tetrahedra, -Si(μ-S)2Si(μ-S)2-. Like other silicon sulfur-compounds (e.g., bis(trimethylsilyl)sulfide) SiS2 hydrolyzes readily to release H2S. In liquid ammonia Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ... it is reported to form the imide Si(NH)2 and NH4SH, but a recent report has identified crystalline (NH4)2 iS3(NH3)�2NH3 as a product which contains the tetrahedral thiosilicate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiogermanates
Sulfidogermanates or thiogermanates are chemical compounds containing anions with sulfur atoms bound to germanium. They are in the class of chalcogenidotetrelates. Related compounds include thiosilicates, thiostannates, selenidogermanates, telluridogermanates and selenidostannate Selenidostannates are chemical compounds which contain anionic units of selenium connected to tin. They can be considered as stannates where selenium substitutes for oxygen. Similar compounds include the selenogermanates and thiostannates. They are ...s. Coordination of sulfur around germanium is tetrahedral meaning there are four sulfur atoms symmetrically arranged. This basic structure can form ortho salts with GeS44−, oligomers, or polymeric structures. Similar structures are also formed with heavy group 13 and group 14 elements due to their relatively stronger bonds with sulfur. Light elements from these groups have lower affinity for sulfur, so there are fewer compounds like this for boron, aluminiu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
LISICON
LISICON is an acronym for LIthium Super Ionic CONductor, which refers to a family of solids with the chemical formula Li2+2xZn1−xGeO4. The first example of this structure was discovered in 1977, providing a chemical formula of Li14Zn(GeO4)4. The crystal structure of LISICON consists of a network of i11Zn(GeO4)4sup>3- as well as 3 loosely bonded Li+. The weaker bonds allow for the lithium ions to easily move from site to site, not needing to break strong bonds to do so. Also, this structure forms large “bottlenecks” between the interstitial positions which these ions occupy, additionally lowering the energy required to move from site to site. These two factors allow for the lithium ions to diffuse quickly and easily through the structure. However, because of the shape of the channels through which these lithium ions can diffuse, they are limited to 2 dimensional diffusion. LISICON compounds have relatively high ionic conductivity, on the order of 10−6 S/cm at 25&nbs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry
Chemistry is the scientific study of the properties and behavior of matter. It is a physical science within the natural sciences that studies the chemical elements that make up matter and chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during chemical reaction, reactions with other chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the prop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
332-ICSD
33 may refer to: *33 (number) *33 BC *AD 33 *1933 *2033 Science * Arsenic, a metalloid in the periodic table * 33 Polyhymnia, an asteroid in the asteroid belt Music * La 33, a Colombian salsa music band Albums * ''33'' (Luis Miguel album) (2003) * ''33'' (Southpacific album) (1998) * ''33'' (Wanessa album) (2016) Songs *"33 'GOD'", a 2016 song by Bon Iver * "Thirty-Three" (song), a 1995 song by the Smashing Pumpkins *"Thirty Three", a song by Karma to Burn from the album ''Almost Heathen'', 2001 *"33", a 2002 song by Coheed and Cambria *"33", a song by Conrad Sewell from his 2023 album ''Precious'' *"33", a song by Sinéad O’Connor from her 2007 album ''Theology'' *"33" a 2020 song by Polo G Television *El 33, a Catalan television channel * "33" (''Battlestar Galactica''), an episode of ''Battlestar Galactica'' Other uses *Los 33, the miners involved in the 2010 Copiapó mining accident **''The 33'', a 2015 film based on the Copiapó mining accident * ''Thirty Three'' (film) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfides
Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (HS−) are the conjugate acids of sulfide. Chemical properties The sulfide ion does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8 MgI2 Metal derivati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Silicon Compounds
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bondsthat is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within living things. History Friedrich Wöhler's conversion of am ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Infrared
Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those of red light (the longest waves in the visible spectrum), so IR is invisible to the human eye. IR is generally (according to ISO, CIE) understood to include wavelengths from around to . IR is commonly divided between longer-wavelength thermal IR, emitted from terrestrial sources, and shorter-wavelength IR or near-IR, part of the solar spectrum. Longer IR wavelengths (30–100 μm) are sometimes included as part of the terahertz radiation band. Almost all black-body radiation from objects near room temperature is in the IR band. As a form of EMR, IR carries energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon. It was long known that fires e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fast Ion Conductor
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors. Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure. Mechanism Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors. Classification In solid electrolytes (glasses or crystals), the ionic cond ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chalcogenidotetrelate
Chalcogenidotetrelates are chemical compounds containing a group 14 element, known as a tetrel, and a group 16 element, known as a chalcogen. The group 14 elements are carbon, silicon, germanium, tin, lead and flerovium. Flerovium compounds like this are unknown due to its short half-life. The group 16 elements are oxygen, sulfur, selenium, tellurium, polonium and livermorium. Livermorium compounds like this are unknown due to its short half-life. Chalcogenidotetrelates are a class of chalcogenidometalates. In chalcogenidotetrelates, the chalcogen atom is normally divalent, and the tetrel atom is normally tetravalent. The chalcogen atom has one or two single bonds, or one double bond to tetrel atoms. The tetrel atom has one, two, three or four single bonds to chalcogen atoms, or one double bond plus one or two single bonds to chalcogen atoms. The tetrel atom would normally have four bonds in a +4 oxidation state. Carbon differs significantly from the other elements in seldom having ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Materials Science
Materials science is an interdisciplinary field of researching and discovering materials. Materials engineering is an engineering field of finding uses for materials in other fields and industries. The intellectual origins of materials science stem from the Age of Enlightenment, when researchers began to use analytical thinking from chemistry, physics, and engineering to understand ancient, phenomenological observations in metallurgy and mineralogy. Materials science still incorporates elements of physics, chemistry, and engineering. As such, the field was long considered by academic institutions as a sub-field of these related fields. Beginning in the 1940s, materials science began to be more widely recognized as a specific and distinct field of science and engineering, and major technical universities around the world created dedicated schools for its study. Materials scientists emphasize understanding how the history of a material (''processing'') influences its struc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis is the cleavage of Biomolecule, biomolecules where a water molecule is consumed to effect the separation of a larger molecule into component parts. When a carbohydrate is broken into its component sugar molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can be the reverse of a condensation reaction in which two molecules join into a larger one and eject a water molecule. Thus hydrolysis adds water to break down, whereas condensation builds up by removing water. Types Usually hydrolysis is a chemical process in which a molecule of water is added to a substance. Sometimes this addition causes both the su ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
