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Thermal Batteries
Molten-salt batteries are a class of battery that uses molten salts as an electrolyte and offers both a high energy density and a high power density. Traditional non-rechargeable thermal batteries can be stored in their solid state at room temperature for long periods of time before being activated by heating. Rechargeable liquid-metal batteries are used for industrial power backup, special electric vehiclesand for grid energy storage, to balance out intermittent renewable power sources such as solar panels and wind turbines. In 2023, the use of molten salts as electrolytes for high-energy rechargeable lithium metal batteries was demonstrated. History Thermal batteries originated during World War II when German scientist Georg Otto Erb developed the first practical cells using a salt mixture as an electrolyte. Erb developed batteries for military applications, including the V-1 flying bomb and the V-2 rocket, and artillery fuzing systems. None of these batteries entered field ...
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Molten Salt Battery (Zebra)
Melting, or Enthalpy of fusion, fusion, is a physical process that results in the phase transition of a chemical substance, substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or Divorce, pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid melts to become a liquid. Substances in the molten state generally have reduced viscosity as the temperature increases. An exception to this principle is Allotropes of sulfur, elemental sulfur, whose viscosity increases in the range of 130 °C to 190 °C due to polymerization. Some organic compounds melt through mesophases, states of partial order between solid and liquid. First order phase transition From a thermodynamics point of view, at the melting point the change in Gibbs free energy ''∆G'' of the s ...
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Nuclear Weapons
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either nuclear fission, fission (fission or atomic bomb) or a combination of fission and nuclear fusion, fusion reactions (thermonuclear weapon), producing a nuclear explosion. Both bomb types release large quantities of energy from relatively small amounts of matter. Nuclear bombs have had Nuclear weapon yield, yields between 10 tons (the W54) and 50 megatons for the Tsar Bomba (see TNT equivalent). Yields in the low kilotons can devastate cities. A thermonuclear weapon weighing as little as can release energy equal to more than 1.2 megatons of TNT (5.0 Petajoule, PJ). Apart from the blast, Effects of nuclear explosions, effects of nuclear weapons include Firestorm, firestorms, extreme Thermal radiation, heat and ionizing radiation, radioactive nuclear fallout, an Nuclear electromagnetic pulse, electromagnetic pulse, and a radar blackout. The first nuclear weapons were deve ...
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STS-87
STS-87 was a Space Shuttle mission launched from Launch Complex 39B of the Kennedy Space Center on 19 November 1997. It was the 88th flight of the Space Shuttle and the 24th flight of '' Columbia''. The mission goals were to conduct experiments using the United States Microgravity Payload (USMP-4), conduct two EVAs, and deploy the SPARTAN-201 experiment. This mission marked the first time an EVA was performed from ''Columbia''. EVAs from ''Columbia'' were originally planned for STS-5 in 1982 and STS-80 in 1996, but were canceled due to spacesuit and airlock problems, respectively. It also marked the first EVA conducted by a Japanese astronaut, Takao Doi. Crew Backup crew Space walks *'' Scott and Doi'' – EVA 1 *EVA 1 Start: 25 November 1997 – 00:02 UTC *EVA 1 End: 25 November 1997 – 07:45 UTC *Duration: 7 hours, 43 minutes *'' Scott and Doi'' – EVA 2 *EVA 2 Start: 3 December 1997 – 09:09 UTC *EVA 2 End: 3 December 1997 – 14:09 UTC *Duration: 4 hours, 59 minutes ...
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Space Shuttle
The Space Shuttle is a retired, partially reusable launch system, reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program name was the Space Transportation System (STS), taken from the 1969 plan led by U.S. vice president Spiro Agnew for a system of reusable spacecraft where it was the only item funded for development. The first (STS-1) of four orbital test flights occurred in 1981, leading to operational flights (STS-5) beginning in 1982. Five complete Space Shuttle orbiter vehicles were built and flown on a total of 135 missions from 1981 to 2011. They launched from the Kennedy Space Center (KSC) in Florida. Operational missions launched numerous satellites, interplanetary probes, and the Hubble Space Telescope (HST), conducted science experiments in orbit, participated in the Shuttle–Mir program, Shuttle-''Mir'' program with Russia, ...
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Beta-alumina Solid Electrolyte
Beta-alumina solid electrolyte (BASE) is a fast-ion conductor material used as a membrane in several types of molten salt electrochemical cell. Currently there is no known substitute available. β-Alumina exhibits an unusual layered crystal structure which enables very fast-ion transport. β-Alumina is not an isomorphic form of aluminium oxide (Al2O3), but a sodium polyaluminate. It is a hard polycrystalline ceramic, which, when prepared as an electrolyte, is complexed with a mobile ion, such as Na+, K+, Li+, Ag+, H+, Pb2+, Sr2+ or Ba2+ depending on the application. β-Alumina is a good conductor of its mobile ion yet allows no non-ionic (i.e., electronic) conductivity. The crystal structure of the β-alumina provides an essential rigid framework with channels along which the ionic species of the solid can migrate. Ion transport involves hopping from site to site along these channels. Since the 1970s this technology has been thoroughly developed, resulting in interesting ap ...
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Ceramic
A ceramic is any of the various hard, brittle, heat-resistant, and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, and brick. The earliest ceramics made by humans were fired clay bricks used for building house walls and other structures. Other pottery objects such as pots, vessels, vases and figurines were made from clay, either by itself or mixed with other materials like silica, hardened by sintering in fire. Later, ceramics were glazed and fired to create smooth, colored surfaces, decreasing porosity through the use of glassy, amorphous ceramic coatings on top of the crystalline ceramic substrates. Ceramics now include domestic, industrial, and building products, as well as a wide range of materials developed for use in advanced ceramic engineering, such as semiconductors. The word '' ceramic'' comes from the Ancient Greek word (), meaning ...
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Sulfur
Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere Th ...
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Alkali Metal
The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names for the elements in some languages, such as German and Russian. rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute Group (periodic table)#Group names, group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of periodic trends, group trends in properties in the periodic table, with elements exhibiting well-characterised Homologous series, homologous behaviour. This family of elements is also known as the lithium family after its leading element. The alkali metals are all shiny, hardness, sof ...
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Lithium–sulfur Battery
The lithium–sulfur battery (Li–S battery) is a type of rechargeable battery. It is notable for its high specific energy. The low atomic weight of lithium and moderate atomic weight of sulfur means that Li–S batteries are relatively light (about the density of water). They were used on the longest and highest-altitude unmanned solar-powered aeroplane flight (at the time) by Airbus Zephyr, Zephyr 6 in August 2008. Lithium–sulfur batteries may displace lithium-ion cells because of their higher energy density and reduced cost. This is due to two factors. First the use of sulfur instead of a less energy dense and more expensive substances such as cobalt and/or iron compounds found in Lithium-ion battery, lithium-ion batteries. Secondly, the use of metallic lithium instead of intercalating lithium ions allows for much higher energy density, as less substances are needed to hold "lithium" and lithium is directly oxidized. Li–S batteries offer specific energies on the order of 5 ...
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Sodium–sulfur Battery
A sodium–sulfur (NaS) battery is a type of molten-salt battery, molten-salt battery (electricity), battery that uses liquid sodium and liquid sulfur electrodes. This type of battery has a similar energy density to lithium-ion battery, lithium-ion batteries, and is fabricated from inexpensive and low-toxicity materials. Due to the high operating temperature required (usually between 300 and 350 °C), as well as the highly reactive nature of sodium and sodium polysulfides, these batteries are primarily suited for grid energy storage, stationary energy storage applications, rather than for use in vehicles. Molten Na-S batteries are scalable in size: there is a 1 MW microgrid support system on Santa Catalina Island (California), Catalina Island CA (USA) and a 50 MW/300 MWh system in Fukuoka, Kyushu, (Japan). In 2024, only one company (NGK Insulators) produced molten NaS batteries on a commercial scale. BASF Stationary Energy Storage GmbH, a wholly owned subsidiary of BASF SE, a ...
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Melting Point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state of matter, state from solid to liquid. At the melting point the solid and liquid phase (matter), phase exist in Thermodynamic equilibrium, equilibrium. The melting point of a substance depends on pressure and is usually specified at a Standard temperature and pressure, standard pressure such as 1 Atmosphere (unit), atmosphere or 100 Pascal (unit), kPa. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point. Because of the ability of substances to Supercooling, supercool, the freezing point can easily appear to be below its actual value. When the "characteristic freezing point" of a substance is determined, in fact, the actual methodology is almost always "the principle of observing the disappearance rather than the formation of ice, that is, the #Melting point measurements, melting ...
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Reduction Potential
Redox potential (also known as oxidation / reduction potential, ''ORP'', ''pe'', ''E_'', or E_) is a measure of the tendency of a chemical species to acquire electrons from or lose electrons to an electrode and thereby be reduced or oxidised respectively. Redox potential is expressed in volts (V). Each species has its own intrinsic redox potential; for example, the more positive the reduction potential (reduction potential is more often used due to general formalism in electrochemistry), the greater the species' affinity for electrons and tendency to be reduced. Measurement and interpretation In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential w ...
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