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Tetragonal Polycrystalline Zirconia
Yttria blends of approximately 3% are called either tetragonal polycrystalline zirconia or tetragonal zirconia polycrystal (forming the initialisms TZP or TPZ) and have the finest grain size. These grades exhibit the highest toughness at room temperature, because they are nearly 100% tetragonal, but this degrades severely between 200 and 500 °C as these irreversible crystal transformations also cause dimensional change. See also *Zirconium dioxide Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant s ... References {{DEFAULTSORT:Tetragonal Polycrystalline Zirconia Yttrium compounds Zirconium compounds Ceramic materials ...
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Yttria
Yttrium oxide, also known as yttria, is Y2 O3. It is an air-stable, white solid substance. The thermal conductivity of yttrium oxide is 27 W/(m·K). Uses Phosphors Yttria is widely used to make Eu:YVO4 and Eu:Y2O3 phosphors that give the red color in color TV picture tubes. Yttria lasers Y2O3 is a prospective solid-state laser material. In particular, lasers with ytterbium as dopant allow the efficient operation both in continuous operation and in pulsed regimes. At high concentration of excitations (of order of 1%) and poor cooling, the quenching of emission at laser frequency and avalanche broadband emission takes place. (Yttria-based lasers are not to be confused with YAG lasers using yttrium aluminum garnet, a widely used crystal host for rare earth laser dopants). Gas Lighting The original use of the mineral yttria and the purpose of its extraction from mineral sources was as part of the process of making gas mantles and other products for turning the flames of artific ...
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Zirconia
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mineral tazheranite ...
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Initialism
An acronym is a word or name formed from the initial components of a longer name or phrase. Acronyms are usually formed from the initial letters of words, as in ''NATO'' (''North Atlantic Treaty Organization''), but sometimes use syllables, as in ''Benelux'' (short for ''Belgium, the Netherlands, and Luxembourg''). They can also be a mixture, as in ''radar'' (''Radio Detection And Ranging''). Acronyms can be pronounced as words, like ''NASA'' and ''UNESCO''; as individual letters, like ''FBI'', '' TNT'', and ''ATM''; or as both letters and words, like '' JPEG'' (pronounced ') and ''IUPAC''. Some are not universally pronounced one way or the other and it depends on the speaker's preference or the context in which it is being used, such as '' SQL'' (either "sequel" or "ess-cue-el"). The broader sense of ''acronym''—the meaning of which includes terms pronounced as letters—is sometimes criticized, but it is the term's original meaning and is in common use. Dictionary and s ...
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Zirconium Dioxide
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mineral tazher ...
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Yttrium Compounds
An yttrium compound is a chemical compound containing yttrium (element symbol: Y). Among these compounds, yttrium generally has a +3 valence. The solubility properties of yttrium compounds are similar to those of the lanthanides. For example oxalates and carbonates are hardly soluble in water, but soluble in excess oxalate or carbonate solutions as complexes are formed. Sulfates and double sulfates are generally soluble. They resemble the "yttrium group" of heavy lanthanide elements. Chalcogenides The oxides and hydroxides of yttrium are yttrium oxide (Y2O3) and yttrium hydroxide (Y(OH)3), respectively, and they are both white solids which are hardly soluble in water. Among them, yttrium oxide can be prepared by heating yttrium carbonate or yttrium oxalate. Alternatively the oxychloride, Y3O4Cl can be heated in air to yield the oxide. Yttrium hydroxide can be precipitated by the reaction of soluble yttrium compounds with sodium hydroxide or ammonia, and can also be obtained by ...
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Zirconium Compounds
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'', "gold-like" or "as gold"). It is a lustrous, grey-white, strong transition metal that closely resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium forms a variety of inorganic and organometallic compounds such as zirconium dioxide and zirconocene dichloride, respectively. Five isotopes occur naturally, four of which are stable. Zirconium compounds have no known biological role. Characteristics Zirconium is a lustrous, greyish-white, soft, ductile, malleable metal that is solid at room temperature, though it is hard and brittle at lesser purities. In powder form, zirconium is high ...
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