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Tetrafluoroberyllate
Tetrafluoroberyllate or orthofluoroberyllate is an anion containing beryllium and fluorine. The fluoroanion has a tetrahedral shape, with the four fluorine atoms surrounding a central beryllium atom. It has the same size and outer electron structure as sulfate. Therefore, many compounds that contain sulfate have equivalents with tetrafluoroberyllate. Examples of these are the langbeinites, and Tutton's salts. Properties The Be–F bond length is between 145 and 153 pm. The beryllium has sp3 atomic hybridization, leading to a longer bond than in BeF2, where the Be is sp hybridized. In trifluoroberyllates, there are actually BeF4 tetrahedra arranged in a triangle, so that three fluorine atoms are shared on two tetrahedra each, resulting in a formula of Be3F9. In the tetrafluoroberyllates, the tetrahedra can rotate to various degrees. At room temperature, they are hindered from moving. But as temperature increases, they can rotate around the threefold axis, (ie a line throu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Langbeinites
Langbeinites are a family of crystalline substances based on the structure of langbeinite with general formula , where M is a large univalent cation (such as potassium, rubidium, caesium, or ammonium), and M' is a small divalent cation (for example, magnesium, calcium, manganese, iron, cobalt, nickel, copper, zinc or cadmium). The sulfate group, , can be substituted by other tetrahedral anions with a double negative charge such as tetrafluoroberyllate (), selenate (), chromate (), molybdate (), or tungstates. Although monofluorophosphates are predicted, they have not been described. By redistributing charges other anions with the same shape such as phosphate also form langbeinite structures. In these the M' atom must have a greater charge to balance the extra three negative charges. At higher temperatures the crystal structure is cubic P213. However, the crystal structure may change to lower symmetries at lower temperatures, for example, P21, P1, or P212121. Usually this temp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tutton's Salts
Tutton's salts are a family of salts with the formula M2M'(SO4)2(H2O)6 (sulfates) or M2M'(SeO4)2(H2O)6 (selenates). These materials are double salts, which means that they contain two different cations, M+ and M'2+ crystallized in the same regular ionic lattice. The univalent cation can be potassium, rubidium, cesium, ammonium (NH4), deuterated ammonium (ND4) or thallium. Sodium or lithium ions are too small. The divalent cation can be magnesium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc or cadmium. In addition to sulfate and selenate, the divalent anion can be chromate (CrO42−), tetrafluoroberyllate (BeF42−), hydrogenphosphate (HPO42−) or monofluorophosphate (PO3F2−). Tutton's salts crystallize in the monoclinic space group ''P''21/''a''. The robustness is the result of the complementary hydrogen-bonding between the tetrahedral anions and cations as well their interactions with the metal aquo complex (H2O)6sup>2+. Examples and related compo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrafluoroborate
Tetrafluoroborate is the anion . This tetrahedral species is isoelectronic with tetrafluoroberyllate (), tetrafluoromethane (CF4), and tetrafluoroammonium () and is valence isoelectronic with many stable and important species including the perchlorate anion, , which is used in similar ways in the laboratory. It arises by the reaction of fluoride salts with the Lewis acid BF3, treatment of tetrafluoroboric acid with base, or by treatment of boric acid with hydrofluoric acid. As an anion in inorganic and organic chemistry The popularization of has led to decreased use of in the laboratory as a weakly coordinating anion. With organic compounds, especially amine derivatives, forms potentially explosive derivatives. Disadvantages to include its slight sensitivity to hydrolysis and decomposition via loss of a fluoride ligand, whereas does not suffer from these problems. Safety considerations, however, overshadow this inconvenience. With a formula weight of 86.8, BF is also conve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
BeF2
Beryllium fluoride is the inorganic compound with the formula Be F2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water. Properties Beryllium fluoride has distinctive optical properties. In the form of fluoroberyllate glass it has the lowest refractive index for a solid at room temperature of 1.275. Its dispersive power is the lowest for a solid at 0.0093, and the nonlinear coefficient is also the lowest at 2 × 10−14. Structure and bonding The structure of solid BeF2 resembles that of cristobalite. Be2+ centers are four coordinate and tetrahedral and the fluoride centers are two-coordinate. The Be-F bond lengths are about 1.54 Å. Analogous to SiO2, BeF2 can also adopt a number of related structures. An analogy also exists between BeF2 and AlF3: both adopt extended structures at mild temperature. Gas and liquid BeF2 Gaseous beryllium fluoride adopts a linear str ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beryllium
Beryllium is a chemical element with the symbol Be and atomic number 4. It is a steel-gray, strong, lightweight and brittle alkaline earth metal. It is a divalent element that occurs naturally only in combination with other elements to form minerals. Notable gemstones high in beryllium include beryl ( aquamarine, emerald) and chrysoberyl. It is a relatively rare element in the universe, usually occurring as a product of the spallation of larger atomic nuclei that have collided with cosmic rays. Within the cores of stars, beryllium is depleted as it is fused into heavier elements. Beryllium constitutes about 0.0004 percent by mass of Earth's crust. The world's annual beryllium production of 220 tons is usually manufactured by extraction from the mineral beryl, a difficult process because beryllium bonds strongly to oxygen. In structural applications, the combination of high flexural rigidity, thermal stability, thermal conductivity and low density (1.85 times that of wate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Beryllium Fluoride
Beryllium fluoride is the inorganic compound with the formula Be F2. This white solid is the principal precursor for the manufacture of beryllium metal. Its structure resembles that of quartz, but BeF2 is highly soluble in water. Properties Beryllium fluoride has distinctive optical properties. In the form of fluoroberyllate glass it has the lowest refractive index for a solid at room temperature of 1.275. Its dispersive power is the lowest for a solid at 0.0093, and the nonlinear coefficient is also the lowest at 2 × 10−14. Structure and bonding The structure of solid BeF2 resembles that of cristobalite. Be2+ centers are four coordinate and tetrahedral and the fluoride centers are two-coordinate. The Be-F bond lengths are about 1.54 Å. Analogous to SiO2, BeF2 can also adopt a number of related structures. An analogy also exists between BeF2 and AlF3: both adopt extended structures at mild temperature. Gas and liquid BeF2 Gaseous beryllium fluoride adopts a linear s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluoroanion
In chemistry, a fluoroanion or fluorometallate anion is a polyatomic anion that contains one or more fluorine atoms. The ions and salts form from them are also known as complex fluorides. They can occur in salts, or in solution, but seldom as pure acids. Fluoroanions often contain elements in higher oxidation states. They mostly can be considered as fluorometallates, which are a subclass of halometallates. The following is a list of fluoroanions in atomic number order. * trifluoroberyllate * tetrafluoroberyllate *tetrafluoroborate *magnesium tetrafluoride * tetrafluoroaluminate * hexafluoroaluminate *hexafluorosilicate *hexafluorophosphate * Sulfur trifluoride anion * pentafluorosulfate aka pentafluorosulfite or Sulfur pentafluoride ion * sulfur pentafluoride anion * tetrafluorochlorate * hexafluorotitanate * hexafluorovanadate(III) * hexafluorovanadate(IV) * hexafluorovanadate(V) * trifluoromanganate *hexafluoromanganate(III) *hexafluoromanganate(IV) * heptafluoromanganate IV ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrahedral
In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the ordinary convex polyhedra and the only one that has fewer than 5 faces. The tetrahedron is the three-dimensional case of the more general concept of a Euclidean simplex, and may thus also be called a 3-simplex. The tetrahedron is one kind of pyramid, which is a polyhedron with a flat polygon base and triangular faces connecting the base to a common point. In the case of a tetrahedron the base is a triangle (any of the four faces can be considered the base), so a tetrahedron is also known as a "triangular pyramid". Like all convex polyhedra, a tetrahedron can be folded from a single sheet of paper. It has two such nets. For any tetrahedron there exists a sphere (called the circumsphere) on which all four vertices lie, and another ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Tetrafluoroberyllate
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable isotope is 23Na. The free metal does not occur in nature, and must be prepared from compounds. Sodium is the sixth most abundant element in the Earth's crust and exists in numerous minerals such as feldspars, sodalite, and halite (NaCl). Many salts of sodium are highly water-soluble: sodium ions have been leached by the action of water from the Earth's minerals over eons, and thus sodium and chlorine are the most common dissolved elements by weight in the oceans. Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide (lye) is used in soap manufacture, and sodium chloride (edible salt) is a de-icing agent and a nutrient for animals including hum ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Tetrafluoroberyllate
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic groups (indicated by R). Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): :H+ + NH3 -> H4 The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : H4 + B- -> HB + NH3 Thus, treatment of concentrated solutions of ammonium salts with strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: :H2O + NH3 OH- + H4 The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are conve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Fluoride
Sodium fluoride (NaF) is an inorganic compound with the formula . It is used in trace amounts in the fluoridation of drinking water, in toothpaste, in metallurgy, and as a flux. It is a colorless or white solid that is readily soluble in water. It is a common source of fluoride in the production of pharmaceuticals and is used to prevent dental cavities. In 2020, it was the 265th most commonly prescribed medication in the United States, with more than 1million prescriptions. Uses Dental caries Fluoride salts are often added to municipal drinking water (as well as to certain food products in some countries) for the purpose of maintaining dental health. The fluoride enhances the strength of teeth by the formation of fluorapatite, a naturally occurring component of tooth enamel. Although sodium fluoride is used to fluoridate water and is the standard by which other water-fluoridation compounds are gauged, hexafluorosilicic acid (H2SiF6) and its salt sodium hexafluorosil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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