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Technetium 99
Technetium-99 (99Tc) is an isotope of technetium which decays with a half-life of 211,000 years to stable ruthenium-99, emitting beta particles, but no gamma rays. It is the most significant long-lived fission product of uranium fission, producing the largest fraction of the total long-lived radiation emissions of nuclear waste. Technetium-99 has a fission product yield of 6.0507% for thermal neutron fission of uranium-235. The metastable technetium-99m (99mTc) is a short-lived (half-life about 6 hours) nuclear isomer used in nuclear medicine, produced from molybdenum-99. It decays by isomeric transition to technetium-99, a desirable characteristic, since the very long half-life and type of decay of technetium-99 imposes little further radiation burden on the body. Radiation The weak beta emission is stopped by the walls of laboratory glassware. Soft X-rays are emitted when the beta particles are stopped, but as long as the body is kept more than 30 cm away these sh ...
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Trace Radioisotope
A trace radioisotope is a radioisotope that occurs naturally in trace amounts (i.e. extremely small). Generally speaking, trace radioisotopes have half-lives that are short in comparison with the age of the Earth, since primordial nuclides tend to occur in larger than trace amounts. Trace radioisotopes are therefore present only because they are continually produced on Earth by natural processes. Natural processes which produce trace radioisotopes include cosmic ray bombardment of stable nuclides, ordinary alpha and beta decay of the long-lived heavy nuclides, thorium-232, uranium-238, and uranium-235, spontaneous fission of uranium-238, and nuclear transmutation reactions induced by natural radioactivity, such as the production of plutonium-239 and uranium-236 from neutron capture by natural uranium. Elements The elements that occur on Earth only in traces are listed below. Isotopes of other elements (not exhaustive): *Tritium *Beryllium-7 *Beryllium-10 * Carbon-14 *Flu ...
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Samarium-151
Naturally occurring samarium (62Sm) is composed of five stable isotopes, 144Sm, 149Sm, 150Sm, 152Sm and 154Sm, and two extremely long-lived radioisotopes, 147Sm (half life: 1.06 y) and 148Sm (7 y), with 152Sm being the most abundant (26.75% natural abundance). 146Sm is also fairly long-lived (), but is not long-lived enough to have survived in significant quantities from the formation of the Solar System on Earth, although it remains useful in radiometric dating in the Solar System as an extinct radionuclide. Other than the naturally occurring isotopes, the longest-lived radioisotopes are 151Sm, which has a half-life of 88.8 years, and 145Sm, which has a half-life of 340 days. All of the remaining radioisotopes, which range from 129Sm to 168Sm, have half-lives that are less than two days, and the majority of these have half-lives that are less than 48 seconds. This element also has twelve known isomers with the most stable being 141mSm (t1/2 22.6 minutes), 143m1Sm (t1/ ...
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Cs-134
Caesium (55Cs) has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. The atomic masses of these isotopes range from 112 to 151. Only one isotope, 133Cs, is stable. The longest-lived radioisotopes are 135Cs with a half-life of 2.3 million years, with a half-life of 30.1671 years and 134Cs with a half-life of 2.0652 years. All other isotopes have half-lives less than 2 weeks, most under an hour. Beginning in 1945 with the commencement of nuclear testing, caesium radioisotopes were released into the atmosphere where caesium is absorbed readily into solution and is returned to the surface of the earth as a component of radioactive fallout. Once caesium enters the ground water, it is deposited on soil surfaces and removed from the landscape primarily by particle transport. As a result, the input function of these isotopes can be estimated as a function of time. List of isotopes , - , rowspan=2, 112Cs , rowspan=2 style="text- ...
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Cs-137
Caesium-137 (), cesium-137 (US), or radiocaesium, is a radioactive isotope of caesium that is formed as one of the more common fission products by the nuclear fission of uranium-235 and other fissionable isotopes in nuclear reactors and nuclear weapons. Trace quantities also originate from spontaneous fission of uranium-238. It is among the most problematic of the short-to-medium-lifetime fission products. Caesium-137 has a relatively low boiling point of and is volatilized easily when released suddenly at high temperature, as in the case of the Chernobyl nuclear accident and with atomic explosions, and can travel very long distances in the air. After being deposited onto the soil as radioactive fallout, it moves and spreads easily in the environment because of the high water solubility of caesium's most common chemical compounds, which are salts. Caesium-137 was discovered by Glenn T. Seaborg and Margaret Melhase. Decay Caesium-137 has a half-life of about 30.05 years.B ...
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Caesium
Caesium ( IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at . It is the least electronegative element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. The element has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the newly developed method of flame spectroscopy. The first small-scale applications fo ...
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Cationic
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron ...
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High-level Radioactive Waste
High-level waste (HLW) is a type of nuclear waste created by the reprocessing of spent nuclear fuel. It exists in two main forms: * First and second cycle raffinate and other waste streams created by nuclear reprocessing. * Waste formed by vitrification of liquid high-level waste. Liquid high-level waste is typically held temporarily in underground tanks pending vitrification. Most of the high-level waste created by the Manhattan Project and the weapons programs of the cold war exists in this form because funding for further processing was typically not part of the original weapons programs. Both spent nuclear fuel and vitrified waste are considered as suitable forms for long term disposal, after a period of temporary storage in the case of spent nuclear fuel. HLW contains many of the fission products and transuranic elements generated in the reactor core and is the type of nuclear waste with the highest activity. HLW accounts for over 95% of the total radioactivity pr ...
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Iodine-129
Iodine-129 (129I) is a long-lived radioisotope of iodine which occurs naturally, but also is of special interest in the monitoring and effects of man-made nuclear fission products, where it serves as both tracer and potential radiological contaminant. Formation and decay 129I is one of seven long-lived fission products. It is primarily formed from the fission of uranium and plutonium in nuclear reactors. Significant amounts were released into the atmosphere as a result of nuclear weapons testing in the 1950s and 1960s. It is also naturally produced in small quantities, due to the spontaneous fission of natural uranium, by cosmic ray spallation of trace levels of xenon in the atmosphere, and by cosmic ray muons striking tellurium-130. 129I decays with a half-life of 15.7 million years, with low-energy beta and gamma emissions, to stable xenon-129 (129Xe). Fission product 129I is one of the seven long-lived fission products that are produced in significant amounts. Its yield is ...
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Anion
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron ...
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Irish Sea
The Irish Sea or , gv, Y Keayn Yernagh, sco, Erse Sie, gd, Muir Èireann , Ulster-Scots: ''Airish Sea'', cy, Môr Iwerddon . is an extensive body of water that separates the islands of Ireland and Great Britain. It is linked to the Celtic Sea in the south by St George's Channel and to the Inner Seas off the West Coast of Scotland in the north by the North Channel. Anglesey, North Wales, is the largest island in the Irish Sea, followed by the Isle of Man. The term ''Manx Sea'' may occasionally be encountered ( cy, Môr Manaw, ga, Muir Meann gv, Mooir Vannin, gd, Muir Mhanainn). On its shoreline are Scotland to the north, England to the east, Wales to the southeast, Northern Ireland and the Republic of Ireland to the west. The Irish Sea is of significant economic importance to regional trade, shipping and transport, as well as fishing and power generation in the form of wind power and nuclear power plants. Annual traffic between Great Britain and Ireland a ...
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Sellafield
Sellafield is a large multi-function nuclear site close to Seascale on the coast of Cumbria, England. As of August 2022, primary activities are nuclear waste processing and storage and nuclear decommissioning. Former activities included nuclear power generation from 1956 to 2003, and nuclear fuel reprocessing from 1952 to 2022. Reprocessing ceased on 17 July 2022, when the Magnox Reprocessing Plant completed its last batch of fuel after 58 years of operation. The licensed site covers an area of , and comprises more than 200 nuclear facilities and more than 1,000 buildings. It is Europe's largest nuclear site and has the most diverse range of nuclear facilities in the world situated on a single site. The site's workforce size varies, and before the COVID-19 pandemic was approximately 10,000 people. The UK's National Nuclear Laboratory has its Central Laboratory and headquarters on the site. Originally built as a Royal Ordnance Factory in 1942, the site briefly passed in ...
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Nuclear Fuel Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. A breeder reactor is not restricted to using recycled plutonium and uranium. It can employ all the actinides, closing the nuclear fuel cycle and potentially multiplying the energy extracted from natural uranium by about 60 times. Reprocessing must be highly controlled and carefully executed in advanced facilities by highly specialized personnel. Fuel bundles which arrive at the sites from nuclear power plants (after having cooled down for several years) are completely dissolved ...
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