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Solid-state NMR
Solid-state nuclear magnetic resonance (ssNMR) is a spectroscopy technique used to characterize atomic-level structure and dynamics in solid materials. ssNMR spectra are broader due to nuclear spin interactions which can be categorized as dipolar coupling, chemical shielding, Quadrupole, quadrupolar interactions, and j-coupling. These interactions directly affect the lines shapes of experimental ssNMR spectra which can be seen in powder and dipolar patterns. There are many essential solid-state techniques alongside advanced ssNMR techniques that may be applied to elucidate the fundamental aspects of solid materials. ssNMR is often combined with magic angle spinning (MAS) to remove Anisotropy, anisotropic interactions and improve the sensitivity of the technique. The applications of ssNMR further extend to biology and medicine. Nuclear spin interactions The resonance frequency of a nuclear spin depends on the strength of the magnetic field at the Atomic nucleus, nucleus, which c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
900 Magnet New
9 (nine) is the natural number following and preceding . Evolution of the Hindu–Arabic digit Circa 300 BC, as part of the Brahmi numerals, various Indians wrote a digit 9 similar in shape to the modern closing question mark without the bottom dot. The Kshatrapa, Andhra and Gupta started curving the bottom vertical line coming up with a -look-alike. How the numbers got to their Gupta form is open to considerable debate. The Nagari continued the bottom stroke to make a circle and enclose the 3-look-alike, in much the same way that the sign @ encircles a lowercase ''a''. As time went on, the enclosing circle became bigger and its line continued beyond the circle downwards, as the 3-look-alike became smaller. Soon, all that was left of the 3-look-alike was a squiggle. The Arabs simply connected that squiggle to the downward stroke at the middle and subsequent European change was purely cosmetic. While the shape of the glyph for the digit 9 has an ascender in most modern typefa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Shift Anisotropy
In nuclear magnetic resonance (NMR) spectroscopy, the chemical shift is the resonant frequency of an atomic nucleus relative to a standard in a magnetic field. Often the position and number of chemical shifts are diagnostic of the structure of a molecule. Chemical shifts are also used to describe signals in other forms of spectroscopy such as photoemission spectroscopy. Some atomic nuclei possess a magnetic moment (nuclear spin), which gives rise to different energy levels and resonance frequencies in a magnetic field. The total magnetic field experienced by a nucleus includes local magnetic fields induced by currents of electrons in the molecular orbitals (electrons have a magnetic moment themselves). The electron distribution of the same type of nucleus (e.g. ) usually varies according to the local geometry (binding partners, bond lengths, angles between bonds, and so on), and with it the local magnetic field at each nucleus. This is reflected in the spin energy levels (and re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Paramagnetism
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some compounds; they have a relative magnetic permeability slightly greater than 1 (i.e., a small positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer. Paramagnetism is due to the presence of unpaired electrons in the material, so most atom ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Bonds
A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds or through the sharing of electrons as in covalent bonds, or some combination of these effects. Chemical bonds are described as having different strengths: there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force, and hydrogen bonding. Since opposite electric charges attract, the negatively charged electrons surrounding the nucleus and the positively charged protons within a nucleus attract each other. Electrons shared between two nuclei will be attracted to both of them. "Constructive quantum mechanical wavefunction interference" stabilizes the paired nuclei (see Theories of chemical bonding). Bonded nuclei maintain an optimal di ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Legendre Polynomials
In mathematics, Legendre polynomials, named after Adrien-Marie Legendre (1782), are a system of complete and orthogonal polynomials with a wide number of mathematical properties and numerous applications. They can be defined in many ways, and the various definitions highlight different aspects as well as suggest generalizations and connections to different mathematical structures and physical and numerical applications. Closely related to the Legendre polynomials are associated Legendre polynomials, Legendre functions, Legendre functions of the second kind, big q-Legendre polynomials, and associated Legendre functions. Definition and representation Definition by construction as an orthogonal system In this approach, the polynomials are defined as an orthogonal system with respect to the weight function w(x) = 1 over the interval [-1,1]. That is, P_n(x) is a polynomial of degree n, such that \int_^1 P_m(x) P_n(x) \,dx = 0 \quad \text n \ne m. With the additional standardi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zeeman Effect
The Zeeman effect () is the splitting of a spectral line into several components in the presence of a static magnetic field. It is caused by the interaction of the magnetic field with the magnetic moment of the atomic electron associated with its Angular momentum, orbital motion and Spin (physics), spin; this interaction shifts some orbital energies more than others, resulting in the split spectrum. The effect is named after the Netherlands, Dutch physicist Pieter Zeeman, who discovered it in 1896 and received a Nobel Prize in Physics for this discovery. It is analogous to the Stark effect, the splitting of a spectral line into several components in the presence of an electric field. Also, similar to the Stark effect, transitions between different components have, in general, different intensities, with some being entirely forbidden (in the dipole approximation), as governed by the selection rules. Since the distance between the Zeeman sub-levels is a function of magnetic field ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Field Gradient
In atomic, molecular, and solid-state physics, the electric field gradient (EFG) measures the rate of change of the electric field at an atomic nucleus generated by the electronic charge distribution and the other nuclei. The EFG couples with the nuclear electric quadrupole moment of quadrupolar nuclei (those with spin quantum number greater than one-half) to generate an effect which can be measured using several spectroscopic methods, such as nuclear magnetic resonance (NMR), microwave spectroscopy, electron paramagnetic resonance (EPR, ESR), nuclear quadrupole resonance (NQR), Mössbauer spectroscopy or perturbed angular correlation (PAC). The EFG is non-zero only if the charges surrounding the nucleus violate cubic symmetry and therefore generate an inhomogeneous electric field at the position of the nucleus. EFGs are highly sensitive to the electronic density in the immediate vicinity of a nucleus. This is because the EFG operator scales as ''r''−3, where ''r'' is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tensor Product
In mathematics, the tensor product V \otimes W of two vector spaces V and W (over the same field) is a vector space to which is associated a bilinear map V\times W \rightarrow V\otimes W that maps a pair (v,w),\ v\in V, w\in W to an element of V \otimes W denoted . An element of the form v \otimes w is called the tensor product of v and w. An element of V \otimes W is a tensor, and the tensor product of two vectors is sometimes called an ''elementary tensor'' or a ''decomposable tensor''. The elementary tensors span V \otimes W in the sense that every element of V \otimes W is a sum of elementary tensors. If bases are given for V and W, a basis of V \otimes W is formed by all tensor products of a basis element of V and a basis element of W. The tensor product of two vector spaces captures the properties of all bilinear maps in the sense that a bilinear map from V\times W into another vector space Z factors uniquely through a linear map V\otimes W\to Z (see the section below ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magic Angle
The magic angle is a precisely defined angle, the value of which is approximately 54.7356°. The magic angle is a root of a second-order Legendre polynomial, , and so any interaction which depends on this second-order Legendre polynomial vanishes at the magic angle. This property makes the magic angle of particular importance in magic angle spinning solid-state NMR spectroscopy. In magnetic resonance imaging, structures with ordered collagen, such as tendons and ligaments, oriented at the magic angle may appear hyperintense in some sequences; this is called the magic angle artifact or effect. Mathematical definition The magic angle ''θ''m is \theta_\mathrm = \arccos \frac = \arctan \sqrt \approx 0.955\,32\ \text \approx 54.7^\circ \! , where arccos and arctan are the inverse cosine and tangent functions respectively. is the angle between the space diagonal of a cube and any of its three connecting edges, see image. Another representation of the magic angle is half of the o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum Permeability
The vacuum magnetic permeability (variously ''vacuum permeability'', ''permeability of free space'', ''permeability of vacuum'', ''magnetic constant'') is the magnetic permeability in a classical vacuum. It is a physical constant, conventionally written as ''μ''0 (pronounced "mu nought" or "mu zero"), approximately equal to 4π × 10−7 H/m (by the former definition of the ampere). It quantifies the strength of the magnetic field induced by an electric current. Expressed in terms of SI base units, it has the unit Kilogram, kg⋅Metre, m⋅Second, s−2⋅A−2. It can be also expressed in terms of SI derived units, Newton (unit), N⋅A−2, Henry (unit), H·m−1, or Tesla (unit), T·m·A−1, which are all equivalent. Since the 2019 revision of the SI, revision of the SI in 2019 (when the values of ''Elementary charge, e'' and ''Planck constant, h'' were fixed as defined quantities), ''μ''0 is an experimentally determined constant, its value being proportional ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reduced Planck Constant
The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a matter wave equals the Planck constant divided by the associated particle momentum. The constant was postulated by Max Planck in 1900 as a proportionality constant needed to explain experimental black-body radiation. Planck later referred to the constant as the "quantum of action". In 1905, Albert Einstein associated the "quantum" or minimal element of the energy to the electromagnetic wave itself. Max Planck received the 1918 Nobel Prize in Physics "in recognition of the services he rendered to the advancement of Physics by his discovery of energy quanta". In metrology, the Planck constant is used, together with other constants, to define the kilogram, the SI unit of mass. The SI units are defined in such a way that, when the Pla ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gyromagnetic Ratio
In physics, the gyromagnetic ratio (also sometimes known as the magnetogyric ratio in other disciplines) of a particle or system is the ratio of its magnetic moment to its angular momentum, and it is often denoted by the symbol , gamma. Its SI unit is the reciprocal second per tesla (s−1⋅T−1) or, equivalently, the coulomb per kilogram (C⋅kg−1). The -factor of a particle is a related dimensionless value of the system, derived as the ratio of its gyromagnetic ratio to that which would be classically expected from a rigid body of which the mass and charge are distributed identically, and for which total mass and charge are the same as that of the system. For a classical rotating body Consider a nonconductive charged body rotating about an axis of symmetry. According to the laws of classical physics, it has both a magnetic dipole moment due to the movement of charge and an angular momentum due to the movement of mass arising from its rotation. It can be shown that as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
