Silver Fluoride
Silver fluoride can refer to: * Silver subfluoride (disilver monofluoride), Ag2F * Silver(I) fluoride (silver monofluoride, argentous fluoride), AgF * Silver(I,II) fluorides (disilver trifluoride, trisilver tetrafluoride) Ag2F3, Ag3F4 * Silver(II) fluoride (silver difluoride, argentic fluoride), AgF2 * Silver(II,III) fluorides (disilver pentafluoride, trisilver octafluoride) Ag2F5, Ag3F8 * Silver(III) fluoride (silver trifluoride), AgF3 * Silver diammine fluoride, a material used to stop dental caries Tooth decay, also known as caries,The word 'caries' is a mass noun, and is not a plural of 'carie'.'' is the breakdown of teeth due to acids produced by bacteria. The resulting cavities may be a number of different colors, from yellow to black ... (cavities), AgFH6N2 Gallery References {{Reflist ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver Subfluoride
Silver subfluoride is the inorganic compound with the formula Ag2F. This is an unusual example of a compound where the oxidation state of silver is fractional. The compound is produced by the reaction of silver and silver(I) fluoride:Lee Poyer, Maurice Fielder, Hugh Harrison, Burl E. Bryant "Disilver Fluoride: (Silver “Subfluoride”)" Inorganic Syntheses, 1957, Volume 5, 92–94. :Ag + AgF → Ag2F It forms small crystals with a bronze reflex and is a good conductor of electricity. On contact with water almost instant hydrolysis occurs with the precipitation of silver (Ag) powder. Crystal structure Ag2F adopts the anti-CdI2 crystal structure In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ..., i.e. the same structure as cadmium iodide, CdI2, but with "Ag½+" centres in ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver(I) Fluoride
Silver(I) fluoride is the inorganic compound with the formula AgF. It is one of the three main fluorides of silver, the others being silver subfluoride and silver(II) fluoride. AgF has relatively few niche applications; it has been employed as a fluorination and desilylation reagent in organic synthesis and in aqueous solution as a topical caries treatment in dentistry. The hydrates of AgF present as colorless, while pure anhydrous samples are yellow. Preparation High-purity silver(I) fluoride can be produced by the heating of silver carbonate to under a hydrogen fluoride environment, in a platinum tube: : Laboratory routes to the compound typically avoid the use of gaseous hydrogen fluoride. One method is the thermal decomposition of silver tetrafluoroborate: : In an alternative route, silver(I) oxide is dissolved in concentrated aqueous hydrofluoric acid, and the silver fluoride is precipitated out of the resulting solution by acetone. : Properties Structure ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver(II) Fluoride
Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound - silver usually exists in its +1 oxidation state. It is used as a fluorinating agent. Preparation AgF2 can be synthesized by fluorinating Ag2O with elemental fluorine. Also, at 200 °C (473 K) elemental fluorine will react with AgF or AgCl to produce AgF2. As a strong fluorinating agent, AgF2 should be stored in Teflon or a passivated metal container. It is light sensitive. AgF2 can be purchased from various suppliers, the demand being less than 100 kg/year. While laboratory experiments find use for AgF2, it is too expensive for large scale industry use. In 1993, AgF2 cost between 1000-1400 US dollars per kg. Composition and structure AgF2 is a white crystalline powder, but it is usually black/brown due to impurities. The F/Ag ratio for most samples is < 2, typically approaching 1.75 due to contamination with [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver(III) Fluoride
Silver(III) fluoride, AgF3, is an unstable, bright-red, diamagnetic compound containing silver in the unusual +3 oxidation state. Its crystal structure is very similar to that of gold(III) fluoride: it is a polymer consisting of rectangular AgF4 units linked into chains by fluoro bridges. Preparation AgF3 can be prepared by treating a solution containing tetrafluoroargentate(III) ions in anhydrous hydrogen fluoride with boron trifluoride; the potassium tetrafluoroargentate(III) was prepared by heating a stoichiometric mix of potassium and silver nitrate in a sealed container filled with pressurised fluorine gas at 400C for 24 hours, twice. When dissolved in anhydrous HF, it decomposes spontaneously to Ag3F8 overnight at room temperature. The high-valence silver compounds described in the thesis are notable for their variety of colours: KAgF4 is bright orange, AgF3 bright red, AgFAsF6 is deep blue, Ag3F8 deep red-brown, and Pd(AgF4)2 is lime-green. Earlier preparations used ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver Diammine Fluoride
Silver diammine fluoride (SDF), also known as silver diamine fluoride in most of the dental literature (although this is a chemical misnomer), is a topical medication used to treat and prevent dental caries (tooth decay) and relieve dentinal hypersensitivity. It is a colorless (most products) or blue-tinted (Advantage Arrest, SilverSense SDF), odourless liquid composed of silver, ammonium and fluoride ions at a pH of 10.4 (most products) or 13 (Riva Star). Ammonia compounds reduce the oxidative potential of SDF, increase its stability and helps to maintain a constant concentration over a period of time, rendering it safe for use in the mouth. Silver and fluoride ions possess antimicrobial properties and are used in the remineralization of enamel and dentin on teeth for preventing and arresting dental caries. SDF is also known as diammine silver fluoride, silver fluoride, and silver ammonium fluoride. It is frequently spelled "silver diamine fluoride" (with one ''m''); however, ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Dental Caries
Tooth decay, also known as caries,The word 'caries' is a mass noun, and is not a plural of 'carie'.'' is the breakdown of teeth due to acids produced by bacteria. The resulting cavities may be a number of different colors, from yellow to black. Symptoms may include pain and difficulty eating. Complications may include periodontal disease, inflammation of the tissue around the tooth, tooth loss and infection or dental abscess, abscess formation. Tooth regeneration is an ongoing Stem-cell therapy, stem cell–based field of study that aims to find methods to reverse the effects of decay; current methods are based on easing symptoms. The cause of cavities is acid from bacteria dissolving the hard tissues of the teeth (Tooth enamel, enamel, dentin and cementum). The acid is produced by the bacteria when they break down food debris or sugar on the tooth surface. Simple sugars in food are these bacteria's primary energy source and thus a diet high in simple sugar is a risk factor. I ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver Subfluoride
Silver subfluoride is the inorganic compound with the formula Ag2F. This is an unusual example of a compound where the oxidation state of silver is fractional. The compound is produced by the reaction of silver and silver(I) fluoride:Lee Poyer, Maurice Fielder, Hugh Harrison, Burl E. Bryant "Disilver Fluoride: (Silver “Subfluoride”)" Inorganic Syntheses, 1957, Volume 5, 92–94. :Ag + AgF → Ag2F It forms small crystals with a bronze reflex and is a good conductor of electricity. On contact with water almost instant hydrolysis occurs with the precipitation of silver (Ag) powder. Crystal structure Ag2F adopts the anti-CdI2 crystal structure In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat ..., i.e. the same structure as cadmium iodide, CdI2, but with "Ag½+" centres in ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver(I) Fluoride
Silver(I) fluoride is the inorganic compound with the formula AgF. It is one of the three main fluorides of silver, the others being silver subfluoride and silver(II) fluoride. AgF has relatively few niche applications; it has been employed as a fluorination and desilylation reagent in organic synthesis and in aqueous solution as a topical caries treatment in dentistry. The hydrates of AgF present as colorless, while pure anhydrous samples are yellow. Preparation High-purity silver(I) fluoride can be produced by the heating of silver carbonate to under a hydrogen fluoride environment, in a platinum tube: : Laboratory routes to the compound typically avoid the use of gaseous hydrogen fluoride. One method is the thermal decomposition of silver tetrafluoroborate: : In an alternative route, silver(I) oxide is dissolved in concentrated aqueous hydrofluoric acid, and the silver fluoride is precipitated out of the resulting solution by acetone. : Properties Structure ... [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |
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Silver(II) Fluoride
Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound - silver usually exists in its +1 oxidation state. It is used as a fluorinating agent. Preparation AgF2 can be synthesized by fluorinating Ag2O with elemental fluorine. Also, at 200 °C (473 K) elemental fluorine will react with AgF or AgCl to produce AgF2. As a strong fluorinating agent, AgF2 should be stored in Teflon or a passivated metal container. It is light sensitive. AgF2 can be purchased from various suppliers, the demand being less than 100 kg/year. While laboratory experiments find use for AgF2, it is too expensive for large scale industry use. In 1993, AgF2 cost between 1000-1400 US dollars per kg. Composition and structure AgF2 is a white crystalline powder, but it is usually black/brown due to impurities. The F/Ag ratio for most samples is < 2, typically approaching 1.75 due to contamination with [...More Info...]       [...Related Items...]     OR:     [Wikipedia]   [Google]   [Baidu]   |