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Safeners
Herbicide safeners are organic compounds used to enhance the effectiveness of herbicides, to make them "safer". They minimize the effect of the herbicide on crop plants, thereby improving selectivity between crop plants vs. weed species being targeted by the herbicide. One way that they function is by enhancing the expression of protective enzymes in the crop plant. These protective enzymes might include cytochrome P450. Herbicide safeners can be used to pretreat crop seeds prior to planting, or they can be sprayed on plants as a mixture with the herbicide. Inventory 190px, Flurazole is a safener applied to sorghum. After the discovery of the safener properties of naphthalic anhydride, additional safeners were reported. They are associated with particular crops, such as benoxacor for maize and flurazole for sorghum. Approximately 20 safeners were in use in 2023. The inventory: *benoxacor *BPCMS *cloquintocet *cyometrinil *cyprosulfamide *dichlormid *dicyclonon *dietholate *f ...
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Organic Compounds
Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-containing compounds such as alkanes (e.g. methane ) and its derivatives are universally considered organic, but many others are sometimes considered inorganic, such as certain compounds of carbon with nitrogen and oxygen (e.g. cyanide ion , hydrogen cyanide , chloroformic acid , carbon dioxide , and carbonate ion ). Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, and even hyd ...
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Herbicide
Herbicides (, ), also commonly known as weed killers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page for EPA reports on pesticide use ihere Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides (sometimes called "total weed killers") kill plants indiscriminately. The combined effects of herbicides, nitrogen fertilizer, and improved cultivars has increased yields (per acre) of major crops by three to six times from 1900 to 2000. In the United States in 2012, about 91% of all herbicide usage, was determined by weight applied, in agriculture. In 2012, world pesticide expenditures totaled nearly US$24.7 billion; herbicides were about 44% of those sales and constituted the biggest portion, followed by insecticides, fungicides, and fumigants. Herbicide is also used ...
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Crop
A crop is a plant that can be grown and harvested extensively for profit or subsistence. In other words, a crop is a plant or plant product that is grown for a specific purpose such as food, Fiber, fibre, or fuel. When plants of the same species are cultivated in rows or other systematic arrangements, it is called crop field or crop cultivation. Most crops are harvested as food for humans or fodder for livestock. Important non-food crops include horticulture, floriculture, and industrial crops. Horticulture crops include plants used for other crops (e.g. fruit trees). Floriculture crops include bedding plants, houseplants, flowering garden and pot plants, cut cultivated greens, and cut flowers. Industrial crops are produced for clothing (fiber crops e.g. cotton), biofuel (energy crops, algae fuel), or medicine (medicinal plants). Production There was an increase in global production of primary crops by 56% between 2000 and 2022 to 9.6 billion tonnes, which represents a 0 ...
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Weed
A weed is a plant considered undesirable in a particular situation, growing where it conflicts with human preferences, needs, or goals.Harlan, J. R., & deWet, J. M. (1965). Some thoughts about weeds. ''Economic botany'', ''19''(1), 16-24. Plants with characteristics that make them hazardous, aesthetically unappealing, difficult to control in managed environments, or otherwise unwanted in agriculture, farm land, Orchard, orchards, gardens, lawns, Park, parks, recreational spaces, residential and industrial areas, may all be considered weeds.Holzner, W., & Numata, M. (Eds.). (2013). ''Biology and ecology of weeds'' (Vol. 2). Springer Science & Business Media. The concept of weeds is particularly significant in agriculture, where the presence of weeds in fields used to grow crops may cause major losses in yields. Invasive species, plants introduced to an environment where their presence negatively impacts the overall functioning and biodiversity of the ecosystem, may also sometime ...
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Cytochrome P450
Cytochromes P450 (P450s or CYPs) are a Protein superfamily, superfamily of enzymes containing heme as a cofactor (biochemistry), cofactor that mostly, but not exclusively, function as monooxygenases. However, they are not omnipresent; for example, they have not been found in ''Escherichia coli''. In mammals, these enzymes oxidize steroids, fatty acids, xenobiotics, and participate in many biosyntheses. By hydroxylation, CYP450 enzymes convert xenobiotics into hydrophilic derivatives, which are more readily excreted. P450s are, in general, the terminal oxidase enzymes in electron transfer chains, broadly categorized as P450-containing systems. The term "P450" is derived from the spectrophotometry, spectrophotometric peak at the wavelength of the absorption spectroscopy, absorption maximum of the enzyme (450 nanometre, nm) when it is in the redox, reduced state and complexed with carbon monoxide. Most P450s require a protein partner to deliver one or more electrons to reduc ...
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Naphthalic Anhydride
1,8-Naphthalic anhydride is an organic compound with the formula C10H6(C2O3). It is one of three isomers of naphthalic anhydride, the other two being the 1,2- and the 2,3-derivatives. The 1,8-isomer is prepared by aerobic oxidation of acenaphthene. 2,6-naphthalenedicarboxylic acid can be prepared from this anhydride. 1,8-Naphthalic anhydride is a precursor to the 4-chloro and 4,5-dichloro derivatives. These chloride groups are susceptible to displacement by amines and alkoxides, giving rise, ultimately, to a large family of naphthalimides, which are used as optical brightener Optical brighteners, optical brightening agents (OBAs), fluorescent brightening agents (FBAs), or fluorescent whitening agents (FWAs), are chemical compounds that absorb light in the ultraviolet and violet region (usually 340-370 nm) of the ...s. Derivatives include: Alrestatin,... References {{DEFAULTSORT:Naphthalenedicarboxylic acid, 2, 6- Carboxylic anhydrides Naphthalenes ...
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Sorghum
''Sorghum bicolor'', commonly called sorghum () and also known as great millet, broomcorn, guinea corn, durra, imphee, jowar, or milo, is a species in the Poaceae, grass genus ''Sorghum (genus), Sorghum'' cultivated for its grain. The grain is used as food by humans, while the plant is used for animal feed and ethanol production. Sorghum originated in Africa, and is widely cultivated in tropical and subtropical regions. Sorghum is the world's fifth-most important cereal crop after rice, wheat, maize, and barley. Sorghum is typically an annual, but some cultivars are perennial. It grows in clumps that may reach over high. The grain is small, in diameter. Sweet sorghums are cultivars grown for forage, syrup production, and ethanol. They are taller than those grown for grain. Description Sorghum is a large stout grass that grows up to tall. It has large bushy flowerheads or panicles that provide an edible starchy grain with up to 3,000 seeds in each flowerhead. It grows ...
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Dichlormid
Dichlormid is an organic compound with the formula . The compound can be classified as the amide of diallylamine and dichloroacetic acid. It is an herbicide safener for use with maize. It can be synthesized by reacting diallylamine with dichloroacetyl chloride Dichloroacetyl chloride is the organic compound with the formula CHCl2COCl. It is the acyl chloride of dichloroacetic acid. It is a colourless liquid and is used in acylation reactions. Preparation Unlike typical acid chlorides, which are often ....{{cite book , last=Unger , first=T.A. , title=Pesticide Synthesis Handbook , publisher=William Andrew , year=1996 , isbn=978-0-8155-1853-2 , url=https://books.google.com/books?id=-9cHDi8OOO4C&pg=PA17 , access-date=2024-11-22 , page=17 References Diallylamino compounds Herbicides Acetamides Dichloromethyl compounds ...
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