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Quantum Pendulum
The quantum pendulum is fundamental in understanding hindered internal rotations in chemistry, quantum features of scattering atoms, as well as numerous other quantum phenomena. Though a pendulum not subject to the small-angle approximation has an inherent nonlinearity, the Schrödinger equation for the quantized system can be solved relatively easily. Schrödinger equation Using Lagrangian mechanics from classical mechanics, one can develop a Hamiltonian (quantum mechanics), Hamiltonian for the system. A simple pendulum has one generalized coordinate (the angular displacement \phi) and two constraints (the length of the string and the plane of motion). The kinetic and potential energies of the system can be found to be :T = \frac m l^2 \dot^2, :U = mgl (1 - \cos\phi). This results in the Hamiltonian :\hat = \frac + mgl (1 - \cos\phi). The time-dependent Schrödinger equation for the system is :i \hbar \frac = -\frac \frac + mgl (1 - \cos\phi) \Psi. One must solve the time ...
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Schrödinger Equation
The Schrödinger equation is a partial differential equation that governs the wave function of a non-relativistic quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. It is named after Erwin Schrödinger, an Austrian physicist, who postulated the equation in 1925 and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of the wave function, the quantum-mechanical characterization of an isolated physical system. The equation was postulated by Schrödinger based on a postulate of Louis de Broglie that all matter has an associated matter wave. The equati ...
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Lagrangian Mechanics
In physics, Lagrangian mechanics is a formulation of classical mechanics founded on the d'Alembert principle of virtual work. It was introduced by the Italian-French mathematician and astronomer Joseph-Louis Lagrange in his presentation to the Turin Academy of Science in 1760 culminating in his 1788 grand opus, ''Mécanique analytique''. Lagrangian mechanics describes a mechanical system as a pair consisting of a configuration space (physics), configuration space ''M'' and a smooth function L within that space called a ''Lagrangian''. For many systems, , where ''T'' and ''V'' are the Kinetic energy, kinetic and Potential energy, potential energy of the system, respectively. The stationary action principle requires that the Action (physics)#Action (functional), action functional of the system derived from ''L'' must remain at a stationary point (specifically, a Maximum and minimum, maximum, Maximum and minimum, minimum, or Saddle point, saddle point) throughout the time evoluti ...
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Hamiltonian (quantum Mechanics)
In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy. Its spectrum, the system's ''energy spectrum'' or its set of ''energy eigenvalues'', is the set of possible outcomes obtainable from a measurement of the system's total energy. Due to its close relation to the energy spectrum and time-evolution of a system, it is of fundamental importance in most formulations of quantum theory. The Hamiltonian is named after William Rowan Hamilton, who developed a revolutionary reformulation of Newtonian mechanics, known as Hamiltonian mechanics, which was historically important to the development of quantum physics. Similar to vector notation, it is typically denoted by \hat, where the hat indicates that it is an operator. It can also be written as H or \check. Introduction The Hamiltonian of a system represents the total energy of the system; that is, the sum of the kine ...
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Mathieu Functions
In mathematics, Mathieu functions, sometimes called angular Mathieu functions, are solutions of Mathieu's differential equation : \frac + (a - 2q\cos(2x))y = 0, where are real-valued parameters. Since we may add to to change the sign of , it is a usual convention to set . They were first introduced by Émile Léonard Mathieu, who encountered them while studying vibrating elliptical drumheads.Morse and Feshbach (1953).Brimacombe, Corless and Zamir (2021) They have applications in many fields of the physical sciences, such as optics, quantum mechanics, and general relativity. They tend to occur in problems involving periodic motion, or in the analysis of partial differential equation (PDE) boundary value problems possessing elliptic symmetry.Gutiérrez-Vega (2015). Definition Mathieu functions In some usages, ''Mathieu function'' refers to solutions of the Mathieu differential equation for arbitrary values of a and q. When no confusion can arise, other authors use the ...
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Natural Number
In mathematics, the natural numbers are the numbers 0, 1, 2, 3, and so on, possibly excluding 0. Some start counting with 0, defining the natural numbers as the non-negative integers , while others start with 1, defining them as the positive integers Some authors acknowledge both definitions whenever convenient. Sometimes, the whole numbers are the natural numbers as well as zero. In other cases, the ''whole numbers'' refer to all of the integers, including negative integers. The counting numbers are another term for the natural numbers, particularly in primary education, and are ambiguous as well although typically start at 1. The natural numbers are used for counting things, like "there are ''six'' coins on the table", in which case they are called ''cardinal numbers''. They are also used to put things in order, like "this is the ''third'' largest city in the country", which are called ''ordinal numbers''. Natural numbers are also used as labels, like Number (sports), jersey ...
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Bloch Waves
In condensed matter physics, Bloch's theorem states that solutions to the Schrödinger equation in a periodic potential can be expressed as plane waves modulated by periodic functions. The theorem is named after the Swiss physicist Felix Bloch, who discovered the theorem in 1929. Mathematically, they are written where \mathbf is position, \psi is the wave function, u is a periodic function with the same periodicity as the crystal, the wave vector \mathbf is the crystal momentum vector, e is Euler's number, and i is the imaginary unit. Functions of this form are known as Bloch functions or Bloch states, and serve as a suitable basis for the wave functions or states of electrons in crystalline solids. The description of electrons in terms of Bloch functions, termed Bloch electrons (or less often ''Bloch Waves''), underlies the concept of electronic band structures. These eigenstates are written with subscripts as \psi_, where n is a discrete index, called the band index, ...
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Quantum Tunneling
In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This means that the magnitude of the physical property can take on only discrete values consisting of integer multiples of one quantum. For example, a photon is a single quantum of light of a specific frequency (or of any other form of electromagnetic radiation). Similarly, the energy of an electron bound within an atom is quantized and can exist only in certain discrete values. Atoms and matter in general are stable because electrons can exist only at discrete energy levels within an atom. Quantization is one of the foundations of the much broader physics of quantum mechanics. Quantization of energy and its influence on how energy and matter interact (quantum electrodynamics) is part of the fundamental framework for understanding and describing ...
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Quantum Harmonic Oscillator
The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator. Because an arbitrary smooth potential can usually be approximated as a harmonic potential at the vicinity of a stable equilibrium point, it is one of the most important model systems in quantum mechanics. Furthermore, it is one of the few quantum-mechanical systems for which an exact, analytical solution is known. One-dimensional harmonic oscillator Hamiltonian and energy eigenstates The Hamiltonian of the particle is: \hat H = \frac + \frac k ^2 = \frac + \frac m \omega^2 ^2 \, , where is the particle's mass, is the force constant, \omega = \sqrt is the angular frequency of the oscillator, \hat is the position operator (given by in the coordinate basis), and \hat is the momentum operator (given by \hat p = -i \hbar \, \partial / \partial x in the coordinate basis). The first term in the Hamiltonian represents the kinetic energy of the particle, and the second ...
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Quantum Models
In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This means that the magnitude of the physical property can take on only discrete values consisting of integer multiples of one quantum. For example, a photon is a single quantum of light of a specific frequency (or of any other form of electromagnetic radiation). Similarly, the energy of an electron bound within an atom is quantized and can exist only in certain discrete values. Atoms and matter in general are stable because electrons can exist only at discrete energy levels within an atom. Quantization is one of the foundations of the much broader physics of quantum mechanics. Quantization of energy and its influence on how energy and matter interact (quantum electrodynamics) is part of the fundamental framework for understanding and describing ...
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