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Principle Of Maximum Work
In the history of science, the principle of maximum work was a postulate concerning the relationship between chemical reactions, heat evolution, and the potential work produced there from. The principle was developed in approximate form in 1875 by French chemist Marcellin Berthelot, in the field of thermochemistry, and then in 1876 by American mathematical physicist Willard Gibbs, in the field of thermodynamics, in a more accurate form. Berthelot's version was essentially: "every pure chemical reaction is accompanied by evolution of heat." (and that this yields the maximum amount of work). The effects of irreversibility, however, showed this version to be incorrect. This was rectified, in thermodynamics, by incorporating the concept of entropy. Overview Berthelot independently enunciated a generalization (commonly known as Berthelot's Third Principle, or Principle of Maximum Work), which may be briefly stated as: every pure chemical reaction is accompanied by evolution of heat. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
History Of Science
The history of science covers the development of science from ancient history, ancient times to the present. It encompasses all three major branches of science: natural science, natural, social science, social, and formal science, formal. Protoscience, Science in the ancient world, early sciences, and natural philosophies such as alchemy and astrology that existed during the Bronze Age, Iron Age, classical antiquity and the Middle Ages, declined during the early modern period after the establishment of formal disciplines of science in the Age of Enlightenment. The earliest roots of scientific thinking and practice can be traced to Ancient Egypt and Mesopotamia during the 3rd and 2nd millennia BCE. These civilizations' contributions to mathematics, astronomy, and medicine influenced later Greek natural philosophy of Science in classical antiquity, classical antiquity, wherein formal attempts were made to provide explanations of events in the Universe, physical world based on n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Affinity
In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition. History Early theories The idea of ''affinity'' is extremely old. Many attempts have been made at identifying its origins. The majority of such attempts, however, except in a general manner, end in futility since "affinities" lie at the basis of all Magic (paranormal), magic, thereby pre-dating science. Physical chemistry, however, was one of the first branches of science to study and formulate a "theory of affinity". The name ''affinitas'' was first used in the sense of chemical relation by German philosopher Albertus Magnus near the year 1250. Later, those as Robert Boyle, John Mayow, Johann Glauber, Isaac Newton, and Georg Stahl put forward ideas on elective ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Thermodynamics
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the ''spontaneity'' of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics. Starting from the first and second laws of thermodynamics, four equations called the "fundamental equations of Gibbs" can be derived. From these four, a multitude of equations, relating the thermodynamic properties of the thermodynamic system can be derived using relatively simple mathematics. This outlines the mathematical framework of chemical thermodynamics. History In 1865, the German physicist Rudolf Clausius, in his ''Mechanical Theory of Heat'', suggested that the principles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Engine
A heat engine is a system that transfers thermal energy to do mechanical or electrical work. While originally conceived in the context of mechanical energy, the concept of the heat engine has been applied to various other kinds of energy, particularly electrical, since at least the late 19th century. The heat engine does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the higher temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a lower temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic System
A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes. According to internal processes, passive systems and active systems are distinguished: passive, in which there is a redistribution of available energy, active, in which one type of energy is converted into another. Depending on its interaction with the environment, a thermodynamic system may be an isolated system, a Closed system#In thermodynamics, closed system, or an Open system (systems theory), open system. An isolated system does not exchange matter or energy with its surroundings. A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laws Of Thermodynamics
The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion. In addition to their use in thermodynamics, they are important fundamental laws of physics in general and are applicable in other natural sciences. Traditionally, thermodynamics has recognized three fundamental laws, simply named by an ordinal identification, the first law, the second law, and the third law.Guggenheim, E.A. (1985). ''Thermodynamics. An Advanced Treatment for Chemists and Physicists'', seventh edition, North Holland, Amsterdam, .Kittel, C. Kroemer, H. (1980). ''Thermal Physics'', second ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Of Reaction
The standard enthalpy of reaction (denoted \Delta H_^\ominus) for a chemical reaction is the difference between total product and total reactant molar enthalpies, calculated for substances in their standard states. The value can be approximately interpreted in terms of the total of the chemical bond energies for bonds broken and bonds formed. For a generic chemical reaction :\nu_ \text + \nu_ \text ~+ ~... \rightarrow \nu_ \text + \nu_ \text ~+ ~... the standard enthalpy of reaction \Delta H_^\ominus is related to the standard enthalpy of formation \Delta_ H^\ominus values of the reactants and products by the following equation: : \Delta H_^\ominus = \sum_ \nu_p\Delta_ H_^ - \sum_ \nu_r\Delta_ H_^ In this equation, \nu_i are the stoichiometric coefficients of each product and reactant. The standard enthalpy of formation, which has been determined for a vast number of substances, is the change of enthalpy during the formation of 1 mole of the substance from its constituen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Affinity
In chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition. History Early theories The idea of ''affinity'' is extremely old. Many attempts have been made at identifying its origins. The majority of such attempts, however, except in a general manner, end in futility since "affinities" lie at the basis of all Magic (paranormal), magic, thereby pre-dating science. Physical chemistry, however, was one of the first branches of science to study and formulate a "theory of affinity". The name ''affinitas'' was first used in the sense of chemical relation by German philosopher Albertus Magnus near the year 1250. Later, those as Robert Boyle, John Mayow, Johann Glauber, Isaac Newton, and Georg Stahl put forward ideas on elective ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Julius Thomsen
Julius may refer to: People * Julius (name), a masculine given name and surname (includes a list of people with the name) * Julius (nomen), the name of a Roman family (includes a list of Ancient Romans with the name) ** Julius Caesar (100–44 BC), Roman military and political leader and one of the most influential men of classical antiquity * Julius (judge royal) (fl. before 1135), noble in the Kingdom of Hungary * Julius, Count of Lippe-Biesterfeld (1812–1884), German noble * Julius, Duke of Brunswick-Lüneburg (1528–1589), German noble Arts and entertainment * Julius (''Everybody Hates Chris''), a character from the American sitcom * "Julius" (song), by Phish, 1994 Other uses * Julius (chimpanzee), a chimpanzee at Kristiansand Zoo and Amusement Park in Norway * Julius (month), the month of the ancient Roman calendar originally called ''Quintilis'' and renamed for Julius Caesar * Julius (restaurant), a tavern in Greenwich Village, New York City * Julius (software) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isaac Newton
Sir Isaac Newton () was an English polymath active as a mathematician, physicist, astronomer, alchemist, theologian, and author. Newton was a key figure in the Scientific Revolution and the Age of Enlightenment, Enlightenment that followed. His book (''Mathematical Principles of Natural Philosophy''), first published in 1687, achieved the Unification of theories in physics#Unification of gravity and astronomy, first great unification in physics and established classical mechanics. Newton also made seminal contributions to optics, and Leibniz–Newton calculus controversy, shares credit with German mathematician Gottfried Wilhelm Leibniz for formulating calculus, infinitesimal calculus, though he developed calculus years before Leibniz. Newton contributed to and refined the scientific method, and his work is considered the most influential in bringing forth modern science. In the , Newton formulated the Newton's laws of motion, laws of motion and Newton's law of universal g ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
