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Potassium Hexacyanidoferrate(III)
Potassium ferricyanide is the chemical compound with the formula K3 e(CN)6 This bright red salt contains the octahedrally coordinated 3−">e(CN)6sup>3− ion. It is soluble in water and its solution shows some green-yellow fluorescence. It was discovered in 1822 by Leopold Gmelin. Preparation Potassium ferricyanide is manufactured by passing chlorine through a solution of potassium ferrocyanide. Potassium ferricyanide separates from the solution: :2 K4 e(CN)6+ Cl2 → 2 K3 e(CN)6+ 2 KCl Structure Like other metal cyanides, solid potassium ferricyanide has a complicated polymeric structure. The polymer consists of octahedral e(CN)6sup>3− centers crosslinked with K+ ions that are bound to the CN ligands. The K+---NCFe linkages break when the solid is dissolved in water. Applications The compound is also used to harden iron and steel, in electroplating, dyeing wool, as a laboratory reagent, and as a mild oxidizing agent in organic chemistry. Photography Blueprint, cya ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferric Oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula . It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when used in pigments. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (), which also occurs naturally as the mineral magnetite. Iron(III) oxide is often called rust, since rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as hydrous ferric oxide. Ferric oxide is readily attacked by even weak acids. It is a weak oxidising agent, most famously when reduced by aluminium in the thermite reaction. Structure can be obtained in various polymorphs. In the primary polymorph, α, iron adopts octahedral coordination geometry. That is, each Fe center is bound to six oxygen ligands. In ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ligand
In coordination chemistry, a ligand is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs, often through Lewis acids and bases, Lewis bases. The nature of metal–ligand bonding can range from covalent bond, covalent to ionic bond, ionic. Furthermore, the metal–ligand bond order can range from one to three. Ligands are viewed as Lewis bases, although rare cases are known to involve Lewis acids and bases, Lewis acidic "ligands". Metals and metalloids are bound to ligands in almost all circumstances, although gaseous "naked" metal ions can be generated in a high vacuum. Ligands in a complex dictate the reactivity (chemistry), reactivity of the central atom, including ligand substitution rates, the reactivity of the ligands themselves, and redox. Ligand selection requires critical consideration in many practical are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photographic Print Toning
In photography, toning is a method of altering the color of black-and-white photographs. In analog photography, it is a chemical process carried out on metal salt-based prints, such as silver prints, iron-based prints ( cyanotype or Van Dyke brown), or platinum or palladium prints. This darkroom process cannot be performed with a color photograph. The effects of this process can be emulated with software in digital photography. Sepia is considered a form of black-and-white or monochrome photography. Chemical toning Most toners work by replacing the metallic silver in the emulsion with a silver compound, such as silver sulfide (Ag2S) in the case of sepia toning. The compound may be more stable than metallic silver and may also have a different color or tone. Different toning processes give different colors to the final print. In some cases, the printer may choose to tone some parts of a print more than others. Toner also can increase the range of shades visible in a print ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyanotype
The cyanotype (from , and , ) is a slow-reacting, photographic printing formulation sensitive to a limited near-ultraviolet and blue light spectrum, the range 300 nm to 400 nm known as UVA radiation. It produces a monochrome, blue-coloured print on a range of supports, and is often used for art and reprography in the form of blueprints. For any purpose, the process usually uses two chemicals - ferric ammonium citrate or ferric ammonium oxalate, and potassium ferricyanide, and only water to develop and fix. Announced in 1842, it is still in use. History The cyanotype was discovered, and named thus, by Sir John Herschel, who in 1842 published his investigation of light on iron compounds, expecting that photochemical reactions would reveal, in a form visible to the human eye, the infrared extreme of the electromagnetic spectrum detected by his father William Herschel and the ultraviolet or " actinic" rays that had been discovered in 1801 by Johann Ritter. Tho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photography
Photography is the visual arts, art, application, and practice of creating images by recording light, either electronically by means of an image sensor, or chemically by means of a light-sensitive material such as photographic film. It is employed in many fields of science, manufacturing (e.g., photolithography), and business, as well as its more direct uses for art, film and video production, recreational purposes, hobby, and mass communication. A person who operates a camera to capture or take Photograph, photographs is called a photographer, while the captured image, also known as a photograph, is the result produced by the camera. Typically, a lens is used to focus (optics), focus the light reflected or emitted from objects into a real image on the light-sensitive surface inside a camera during a timed Exposure (photography), exposure. With an electronic image sensor, this produces an Charge-coupled device, electrical charge at each pixel, which is Image processing, electro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Blueprint
A blueprint is a reproduction of a technical drawing or engineering drawing using a contact print process on light-sensitive sheets introduced by Sir John Herschel in 1842. The process allowed rapid and accurate production of an unlimited number of copies. It was widely used for over a century for the reproduction of specification drawings used in Architectural drawing#Working drawings, construction and industry. Blueprints were characterized by white lines on a blue background, a Negative (photography), negative of the original. Color or shades of grey could not be reproduced. The process is obsolete, initially superseded by the whiteprint#The_diazo_printing_process, diazo-based ''whiteprint'' process, and later by large-format xerography, xerographic photocopiers. It has since almost entirely been superseded by digital computer-aided construction drawings. The term ''wikt:blueprint, blueprint'' continues to be used informally to refer to any floor plan (and by analogy, wikt:blu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Chemistry
Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic matter, organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; Greeves, N. and Warren, S. (2012) ''Organic Chemistry''. Oxford University Press. pp. 1–15. . Study of structure determines their structural formula. Study of properties includes Physical property, physical and Chemical property, chemical properties, and evaluation of Reactivity (chemistry), chemical reactivity to understand their behavior. The study of organic reactions includes the organic synthesis, chemical synthesis of natural products, drugs, and polymers, and study of individual organic molecules in the laboratory and via theoretical (in silico) study. The range of chemicals studied chemistry includes hydrocarbons (compounds containing only carbon and hydrogen) as well as compounds based on carbon, but a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidizing Agent
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ''electron donor''). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reagent
In chemistry, a reagent ( ) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. The terms ''reactant'' and ''reagent'' are often used interchangeably, but reactant specifies a substance ''consumed'' in the course of a chemical reaction. ''Solvents'', though involved in the reaction mechanism, are usually not called reactants. Similarly, ''catalysts'' are not consumed by the reaction, so they are not reactants. In biochemistry, especially in connection with enzyme-catalyzed reactions, the reactants are commonly called substrates. Definitions Organic chemistry In organic chemistry, the term "reagent" denotes a chemical ingredient (a compound or mixture, typically of inorganic or small organic molecules) introduced to cause the desired transformation of an organic substance. Examples include the Collins reagent, Fenton's reagent, and Grignard reagents. Analytical chemistry In analytical chemistry, a reag ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Laboratory
A laboratory (; ; colloquially lab) is a facility that provides controlled conditions in which scientific or technological research, experiments, and measurement may be performed. Laboratories are found in a variety of settings such as schools, universities, privately owned research institutions, corporate research and testing facilities, government regulatory and forensic investigation centers, physicians' offices, clinics, hospitals, regional and national referral centers, and even occasionally personal residences. Overview The organisation and contents of laboratories are determined by the differing requirements of the specialists working within. A physics laboratory might contain a particle accelerator or vacuum chamber, while a metallurgy laboratory could have apparatus for casting or refining metals or for testing their strength. A chemist or biologist might use a wet laboratory, while a psychologist's laboratory might be a room with one-way mirrors and hidden ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wool
Wool is the textile fiber obtained from sheep and other mammals, especially goats, rabbits, and camelids. The term may also refer to inorganic materials, such as mineral wool and glass wool, that have some properties similar to animal wool. As an animal fiber, wool consists of protein together with a small percentage of lipids. This makes it chemically quite distinct from cotton and other plant fibers, which are mainly cellulose. Characteristics Wool is produced by follicles which are small cells located in the skin. These follicles are located in the upper layer of the skin called the epidermis and push down into the second skin layer called the dermis as the wool fibers grow. Follicles can be classed as either primary or secondary follicles. Primary follicles produce three types of fiber: kemp, medullated fibers, and true wool fibers. Secondary follicles only produce true wool fibers. Medullated fibers share nearly identical characteristics to hair and are long but ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electroplating
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the redox, reduction of cations of that metal by means of a direct current, direct electric current. The part to be coated acts as the cathode (negative electrode) of an electrolytic cell; the electrolyte is a solution (chemistry), solution of a salt (chemistry), salt whose cation is the metal to be coated, and the anode (positive electrode) is usually either a block of that metal, or of some inert electrical conductor, conductive material. The current is provided by an external power supply. Electroplating is widely used in industry and decorative arts to improve the surface qualities of objects—such as resistance to abrasion (mechanical), abrasion and corrosion, lubrication, lubricity, reflectivity, electrical conductivity, or appearance. It is used to build up thickness on undersized or worn-out parts and to manufacture metal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
