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Plášilite
Plášilite is a very rare uranium mineral with the formula Na2(UO2)(SO4)2•3H2O. Chemically related minerals include natrozippeite, belakovskiite, meisserite, fermiite and oppenheimerite. Most of these uranyl sulfate minerals were originally found in the Blue Lizard mine, San Juan County, Utah, US. The mineral is named after Czech crystallographer Jakub Plášil. Association and origin Plášilite is associated with other sulfate minerals: natrozippeite, johannite, blödite, brochantite, chalcanthite, gypsum, hexahydrite, manganoblödite, and tamarugite. Non-sulfate coexisting minerals include atacamite, calcite, dickite and gerhardtite. Plášilite is secondary in origin, being the product of weathering of the primary uranium mineral, uraninite. Crystal structure The crystal structure of plášilite is of a new type. Its building blocks are: * (UO2)2(SO4)2(OH)2 sheets, with a charge 2-, parallel to (010), of a phosphuranylite topology * edge-sharing NaO2(H2O)4 polyhedra, parall ...
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Fermiite
Fermiite is a rare uranium mineral with the formula Na4(UO2)(SO4)3·3H2O.Kampf, A.R., Plášil, J., Kasatkin, A.V., Marty, J., and Čejka, J., 2015. Fermiite, Na4(UO2)(SO4)3·3H2O and oppenheimerite, Na2(UO2)(SO4)2·3H2O, two new uranyl sulfate minerals from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 79(5), 1123-1142 Chemically related minerals include oppenheimerite, meisserite (which is also structurally-related to fermiite), belakovskiite, natrozippeite and plášilite. Fermiite comes from the Blue Lizard mine, San Juan County, Utah, USA, which is known for many rare uranium minerals.Kampf, A.R., Plášil, J., Kasatkin, A.V., Marty, J., and Čejka, J., 2015. Fermiite, Na4(UO2)(SO4)3·3H2O and oppenheimerite, Na2(UO2)(SO4)2·3H2O, two new uranyl sulfate minerals from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 79(5), 1123-1142 The name honors Enrico Fermi (1901–1954). Association Fermiite is closely associated with nume ...
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Oppenheimerite
Oppenheimerite is a very rare uranium mineral with the formula Na2(UO2)(SO4)2•3H2O. Chemically related minerals include fermiite, natrozippeite, plášilite, belakovskiite and meisserite. Most of these uranyl sulfate minerals were originally found in the Blue Lizard mine, San Juan County, Utah, US. The mineral is named after American Theoretical physicist J. Robert Oppenheimer. Association and origin Oppenheimerite is associated with other sulfate minerals: fermiite, bluelizardite, wetherillite, blödite, chalcanthite, epsomite, gypsum, hexahydrite, kröhnkite, manganoblödite Manganoblödite is a rare manganese mineral with the formula Na2Mn(SO4)2·4H2O. Somewhat chemically similar mineral is D'Ansite-(Mn). Manganoblödite was found in the Blue Lizard mine, San Juan County, Utah, US, which is known for several relativ ..., sideronatrite, and tamarugite. Crystal structure The crystal structure of oppenheimerite is of a new type. It contains chains of the (UO2)(SO4)2(H2 ...
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Belakovskiite
Belakovskiite is a very rare uranium mineral with the formula Na7(UO2)(SO4)4(SO3OH)(H2O)3.Kampf, A.R., Plášil, J., Kasatkin, A.V., and Marty, J., 2014. Belakovskiite, Na7(UO2)(SO4)4(SO3OH)(H2O)3, a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 78(3), 639-649 It is interesting in being a natural uranyl salt with hydrosulfate anion, a feature shared with meisserite. Other chemically related minerals include fermiite, oppenheimerite, natrozippeite and plášilite. Most of these uranyl sulfate minerals was originally found in the Blue Lizard mine, San Juan County, Utah, US. The mineral is named after Russian mineralogist Dmitry Ilych Belakovskiy. Association Belakovskiite is associated with other sulfate minerals: meisserite, blödite, ferrinatrite, kröhnkite Kröhnkite ( Na2Cu(SO4)2•2H2O ) is a rare copper sulfate mineral named after B. Kröhnke who first researched it. Kröhnkite may be replaced by Saranchinaite, th ...
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Meisserite
Meisserite is a very rare uranium mineral with the formula Na5(UO2)(SO4)3(SO3OH)(H2O).Plášil, J., Kampf, A.R., Kasatkin, A.V., and Marty, J., Škoda, R., Silva, S., and Čejka, J., 2013. Meisserite, Na5(UO2)(SO4)3(SO3OH)(H2O), a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 77(7), 2975-2978 It is interesting in being a natural uranyl salt with hydrosulfate ( hydroxysulfate) anion, a feature shared with belakovskiite. Other chemically related minerals include fermiite, oppenheimerite, natrozippeite and plášilite. Most of these uranyl sulfate minerals was originally found in the Blue Lizard mine, San Juan County, Utah, USA. The mineral is named after Swiss mineralogist Nicolas Meisser. Association and origin Meisserite is associated with other sulfate minerals: belakovskiite, johannite, chalcanthite, copiapite, ferrinatrite, and gypsum. It is resulting from post-mining oxidation of the primary uranium mineral - uranini ...
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Atacamite
Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1802 by Dmitri de Gallitzin. The Atacama Desert is also the namesake of the mineral. Occurrence Atacamite is polymorphous with botallackite, clinoatacamite, and paratacamite. Atacamite is a comparatively rare mineral, formed from primary copper minerals in the oxidation or weathering zone of arid climates. It has also been reported as a volcanic sublimate from fumarole deposits, as sulfide alteration products in black smokers. The mineral has also been found naturally on oxidized copper deposits in Chile, China, Russia, Czech Republic, Arizona, and Australia. It occurs in association with cuprite, brochantite, linarite, caledonite, malachite, chrysocolla and its polymorphs. Synthetic Occurrence Atacamite has been discovered in the patina of the Statue of Liberty, and as alteration of ancient bronze and copp ...
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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German , a term from the 19th century that came from the Latin word for Lime (material), lime, (genitive ) with the suffix ''-ite'' used to name minerals. It is thus a Doublet (linguistics), doublet of the word ''wikt:chalk, chalk''. When applied by archaeology, archaeologists and ...
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Dickite
Dickite () is a phyllosilicate clay mineral named after the metallurgical chemist Allan Brugh Dick, who first described it. It is chemically composed of 20.90% aluminium, 21.76% silicon, 1.56% hydrogen and 55.78% oxygen. It has the same composition as kaolinite, nacrite, and halloysite, but with a different crystal structure ( polymorph). Dickite sometimes contains impurities such as titanium, iron, magnesium, calcium, sodium and potassium. Dickite occurs with other clays and requires x-ray diffraction for its positive identification. Dickite is an important alteration indicator in hydrothermal systems as well as occurring in soils and shales. Dickite's type location is in Pant-y-Gaseg, Amlwch, Isle of Anglesey, Wales, United Kingdom, where it was first described in 1888. Dickite appears in locations with similar qualities and is found in China, Jamaica, France, Germany, United Kingdom, United States, Italy, Belgium and Canada. History In 1888, Allan Brugh Dick (1833–1926) ...
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Gerhardtite
Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Copper, Cu(Nitrate, NO3)2(H2O)x. The hydrates are hygroscopic blue solids. Anhydrous copper nitrate forms blue-green crystals and Sublimation (phase transition), sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate. Synthesis and reactions Hydrated copper(II) nitrate Hydrated copper nitrate is prepared by treating copper metal or its oxide with nitric acid: : The same salts can be prepared treating copper metal with an aqueous solution of silver nitrate. That reaction illustrates the ability of copper metal to reduce silver ions. In aqueous solution, the hydrates exist as the aqua complex . Such complexes are highly labile and subject to rapid ligand exchange due to the d9 electronic configuration of copper(II). Attempted dehydration of any of the hydrated copper(II) nitrates by heating affords the oxides, not . At 80 °C the hydrates con ...
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Uraninite
Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes the mineral to contain oxides of lead and trace amounts of helium. It may also contain thorium and rare-earth elements. Overview Uraninite used to be known as pitchblende (from '' pitch'', because of its black color, and ''blende'', from ''blenden'' meaning "to deceive", a term used by German miners to denote minerals whose density suggested metal content, but whose exploitation, at the time they were named, was either unknown or not economically feasible). The mineral has been known since at least the 15th century, from silver mines in the Ore Mountains, on the German/Czech border. The type locality is the historic mining and spa town known as Joachimsthal, the modern-day Jáchymov, on the Czech side of the mountains, where F. E. ...
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Sulfate Mineral
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal Vein (geology), veins and as secondary minerals in the Redox, oxidizing zone of sulfide mineral deposits. The Chromate ion, chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 **Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O **Kieserite MgSO4·H2O **Starkeyite MgSO4·4H2O **Hexahydrite MgSO4·6H2O **Epsomite MgSO4·7H2O **Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O **Antlerite ...
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Phosphuranylite
Phosphuranylite is a uranyl phosphate mineral with formula KCa(H3O)3(UO2)7(PO4)4O4·8(H2O). It was first described in 1879 by Frederick Augustus Genth, from an occurrence in the Flat Rock pegmatite in Mitchell County, North Carolina Mitchell County is a county located in the U.S. state of North Carolina. As of the 2020 census, the population was 14,903. Its county seat is Bakersville. The county is home to Spruce Pine, nicknamed the "Mineral City of the World", and Bak ..., US. References Potassium minerals Calcium minerals Phosphate minerals Uranium(VI) minerals Octahydrate minerals Orthorhombic minerals Minerals in space group 63 Minerals described in 1879 {{phosphate-mineral-stub ...
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Manganoblödite
Manganoblödite is a rare manganese mineral with the formula Na2Mn(SO4)2·4H2O. Somewhat chemically similar mineral is D'Ansite-(Mn). Manganoblödite was found in the Blue Lizard mine, San Juan County, Utah, US, which is known for several relatively new secondary uranium minerals In the mine, manganoblödite occurs intimately intergrown with manganese-, cobalt- and nickel-enriched blödite and a yet another new mineral - cobaltoblödite. Manganoblödite, as suggested by its name is a manganese-analogue of blödite. It is also analogous to changoite, cobaltoblödite and nickelblödite - all three are members of the blödite group. Notes on chemistry Manganoblödite is impure, containing admixtures of magnesium, cobalt and nickel. Association and origin Besides blödite and cobaltoblödite, other minerals associated with manganoblödite include chalcanthite, gypsum, johannite, sideronatrite, a feldspar group mineral and quartz Quartz is a hard, crystalline mineral composed ...
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