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Photon Upconversion
Photon upconversion (UC) is a process in which the sequential Absorption (electromagnetic radiation), absorption of two or more photons leads to the Emission spectrum, emission of light at shorter wavelength than the excitation wavelength. It is an Stokes shift, anti-Stokes type emission. An example is the conversion of infrared light to visible light. Upconversion can take place in both organic and inorganic materials, through a number of different mechanisms. Organic molecules that can achieve photon upconversion through triplet-triplet annihilation are typically Polycyclic aromatic hydrocarbon, polycyclic aromatic hydrocarbons (PAHs). Inorganic materials capable of photon upconversion often contain ions of d-block or f-block elements. Examples of these ions are lanthanides, Ln3+, titanium, Ti2+, nickel, Ni2+, molybdenum, Mo3+, rhenium, Re4+, osmium, Os4+, and so on. Physical mechanisms There are three basic mechanisms for photon upconversion in inorganic materials and at leas ...
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Stokes And Anti-Stokes Emission
Stokes may refer to: People * Stokes (surname), a surname (including a list of people with the name) * Governor Stokes (other) * Senator Stokes (other) Science * Stokes (unit), a measure of viscosity * Stokes boundary layer * Stokes drift * Stokes equation (other) * Stokes flow * Stokes' law * Stokes' law of sound attenuation * Stokes line * Stokes number * Stokes parameters * Stokes radius * Stokes relations * Stokes shift * Stokes stream function * Stokes' theorem * Stokes wave * Campbell–Stokes recorder * Navier–Stokes equations Places * Stokes Bay (other) * Stokes Township (other) Australia * Stokes, Queensland, a locality in the Shire of Carpentaria, Queensland * Stokes County, Queensland * Stokes National Park, in the Goldfields-Esperance region of Western Australia Canada * Stokes Mountain, a mountain in Nunavut * Stokes Range, a mountain range in Nunavut New Zealand * Stokes Valley, a suburb of Lower Hutt ** Sto ...
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Molybdenum
Molybdenum is a chemical element; it has Symbol (chemistry), symbol Mo (from Neo-Latin ''molybdaenum'') and atomic number 42. The name derived from Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals have been known throughout history, but the element was discovered (in the sense of differentiating it as a new entity from the mineral salts of other metals) in 1778 by Carl Wilhelm Scheele. The metal was first isolated in 1781 by Peter Jacob Hjelm. Molybdenum does not occur naturally as a Native metal, free metal on Earth; in its minerals, it is found only in oxidation state, oxidized states. The free element, a silvery metal with a grey cast, has the List of elements by melting point, sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of the world production of the element (about 80%) is used in steel alloys, including high-strength alloys and superalloys. Most molybdenum ...
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Anthracene
Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C14H10, consisting of three fused benzene rings. It is a component of coal tar. Anthracene is used in the production of the red dye alizarin and other dyes, as a scintillator to detect high energy particles, as production of pharmaceutical drugs. Anthracene is colorless but exhibits a blue (400–500 nm peak) fluorescence under ultraviolet radiation. History and etymology Crude anthracene (with a melting point of only 180°) was discovered in 1832 by Jean-Baptiste Dumas and Auguste Laurent who crystalized it from a fraction of coal tar later known as "anthracene oil". Since their (inaccurate) measurements showed the proportions of carbon and hydrogen of it to be the same as in naphthalene, Laurent called it ''paranaphtaline'' in his 1835 publication of the discovery, which is translated to English as paranaphthalene. Two years later, however, he decided to rename the compound to its modern name d ...
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Triplet-Triplet Annihilation
Triplet-triplet annihilation (TTA) is an energy transfer mechanism where two molecules in their triplet excited states interact to form a ground state molecule and an excited molecule in its singlet state. This mechanism is example of Dexter energy transfer mechanism. In triplet-triplet annihilation, one molecule transfers its excited state energy to the second molecule, resulting in the first molecule returning to its ground state and the second molecule being promoted to a higher excited singlet state. Triplet-triplet annihilation was first discovered in the 1960s to explain the observation of delayed fluorescence in anthracene derivatives. Photon upconversion Triplet-triplet annihilation combines the energy of two triplet-excited molecules onto one molecule to produce a higher excited state. Since the higher excited state is an emissive singlet state, TTA can be used to achieve photon upconversion which is a process that converts the energy of two photons into one photon of ...
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Black Body
A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The radiation emitted by a black body in thermal equilibrium with its environment is called ''black-body radiation''. The name "black body" is given because it absorbs all colors of light. In contrast, a white body is one with a "rough surface that reflects all incident rays completely and uniformly in all directions." A black body in thermal equilibrium (that is, at a constant temperature) emits electromagnetic black-body radiation. The radiation is emitted according to Planck's law, meaning that it has a spectrum that is determined by the temperature alone (see figure at right), not by the body's shape or composition. An ideal black body in thermal equilibrium has two main properties: #It is an ideal emitter: at every frequency, it emits as much or more thermal radiative energy as any other body at the same temperature. ...
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Air Mass (solar Energy)
The air mass coefficient defines the direct optical path length through the Earth's atmosphere, expressed as a ratio relative to the path length vertically upwards, i.e. at the zenith. The air mass coefficient can be used to help characterize the solar spectrum after solar radiation has traveled through the atmosphere. The air mass coefficient is commonly used to characterize the performance of solar cells under standardized conditions, and is often referred to using the syntax "AM" followed by a number. "AM1.5" is almost universal when characterizing terrestrial power-generating panels. Description The overall intensity of solar radiation is like that of a black body radiator of the same size at about 5,800 K.or more precisely 5,777 K as reported iNASA Solar System Exploration - Sun: Facts & Figures retrieved 27 April 2011 "Effective Temperature ... 5777 K" As it passes through the atmosphere, sunlight is attenuated by scattering and absorption; the more atmo ...
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Energy Conversion Efficiency
Energy conversion efficiency (''η'') is the ratio between the useful output of an energy conversion machine and the input, in energy terms. The input, as well as the useful output may be chemical, electric power, mechanical work, light (radiation), or heat. The resulting value, ''η'' (eta), ranges between 0 and 1. Overview Energy conversion efficiency depends on the usefulness of the output. All or part of the heat produced from burning a fuel may become rejected waste heat if, for example, work is the desired output from a thermodynamic cycle. Energy converter is an example of an energy transformation. For example, a light bulb falls into the categories energy converter. \eta = \frac Even though the definition includes the notion of usefulness, efficiency is considered a technical or physical term. Goal or mission oriented terms include effectiveness and efficacy. Generally, energy conversion efficiency is a dimensionless number between 0 and 1.0, or 0% to 100%. ...
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Passive Radiative Cooling
Passive daytime radiative cooling (PDRC) (also passive radiative cooling, daytime passive radiative cooling, radiative sky cooling, photonic radiative cooling, and terrestrial radiative cooling) is the use of unpowered, reflective/ thermally-emissive surfaces to lower the temperature of a building or other object. It has been proposed as a method of reducing temperature increases caused by greenhouse gases by reducing the energy needed for air conditioning, lowering the urban heat island effect, and lowering human body temperatures. PDRCs can aid systems that are more efficient at lower temperatures, such as photovoltaic systems, dew collection devices, and thermoelectric generators. Some estimates propose that dedicating 1–2% of the Earth's surface area to PDRC would stabilize surface temperatures. Regional variations provide different cooling potentials with desert and temperate climates benefiting more than tropical climates, attributed to the effects of humidity and cloud c ...
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Nicolaas Bloembergen
Nicolaas Bloembergen (March 11, 1920 – September 5, 2017) was a Dutch- American physicist and Nobel laureate, recognized for his work in developing driving principles behind nonlinear optics for laser spectroscopy. During his career, he was a professor at Harvard University and later at the University of Arizona and at Leiden University in 1973 (as Lorentz Professor). Bloembergen shared the 1981 Nobel Prize in Physics along with Arthur Schawlow and Kai Siegbahn because their work "has had a profound effect on our present knowledge of the constitution of matter" through the use of laser spectroscopy. In particular, Bloembergen was singled out because he "founded a new field of science we now call non-linear optics" by mixing "two or more beams of laser light... in order to produce laser light of a different wave length" and thus significantly broaden the laser spectroscopy frequency band. Early life Bloembergen was born in Dordrecht on March 11, 1920, where his father was ...
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Second-harmonic Generation
Second-harmonic generation (SHG), also known as frequency doubling, is the lowest-order wave-wave nonlinear interaction that occurs in various systems, including optical, radio, atmospheric, and magnetohydrodynamic systems. As a prototype behavior of waves, SHG is widely used, for example, in doubling laser frequencies. SHG was initially discovered as a nonlinear optical process in which two photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with twice the energy of the initial photons (equivalently, twice the frequency and half the wavelength), that conserves the coherence of the excitation. It is a special case of sum-frequency generation (2 photons), and more generally of harmonic generation. The second-order nonlinear susceptibility of a medium characterizes its tendency to cause SHG. Second-harmonic generation, like other even-order nonlinear optical phenomena, is not allowed in media with inversion symmet ...
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Two-photon Absorption
In atomic physics, two-photon absorption (TPA or 2PA), also called two-photon excitation or non-linear absorption, is the (almost) simultaneous Absorption (electromagnetic radiation), absorption of two photons of identical or different frequencies in order to Electron excitation, excite an atom or a molecule from one state (usually the ground state), via a virtual energy level, to a higher energy, most commonly an excited electronic state. Absorption of two photons with the same frequency is called degenerate two-photon absorption, while absorption of two photons with different frequencies is called non-degenerate two-photon absorption. The energy difference between the involved lower and upper states is equal or smaller than the sum of the photon energy, photon energies of the two photons absorbed. Since TPA depends on the simultaneous absorption of two photons, the probability of two-photon absorption is proportional to the photon dose (), which is proportional to the square of ...
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Nanoparticle
A nanoparticle or ultrafine particle is a particle of matter 1 to 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At the lowest range, metal particles smaller than 1 nm are usually called atom clusters instead. Nanoparticles are distinguished from microparticles (1-1000 μm), "fine particles" (sized between 100 and 2500 nm), and "coarse particles" (ranging from 2500 to 10,000 nm), because their smaller size drives very different physical or chemical properties, like colloidal properties and ultrafast optical effects or electric properties. Being more subject to the Brownian motion, they usually do not sediment, like colloid, colloidal particles that conversely are usually understood to range from 1 to 1000 nm. Being much smaller than the wavelengths of visible light (400-700 nm), nanoparticles cannot be seen with ordinary ...
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