|
Nitrile Oxide
In organic chemistry, a nitrile is any organic compound that has a functional group. The name of the compound is composed of a base, which includes the carbon of the , suffixed with "nitrile", so for example is called " propionitrile" (or propanenitrile). The prefix '' cyano-'' is used interchangeably with the term ''nitrile'' in industrial literature. Nitriles are found in many useful compounds, including methyl cyanoacrylate, used in super glue, and nitrile rubber, a nitrile-containing polymer used in latex-free laboratory and medical gloves. Nitrile rubber is also widely used as automotive and other seals since it is resistant to fuels and oils. Organic compounds containing multiple nitrile groups are known as cyanocarbons. Inorganic compounds containing the group are not called nitriles, but cyanides instead. Though both nitriles and cyanides can be derived from cyanide salts, most nitriles are not nearly as toxic. Structure and basic properties The N−C−C geome ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triple Bond
A triple bond in chemistry is a chemical bond between two atoms involving six Electron pair bond, bonding electrons instead of the usual two in a covalent bond, covalent single bond. Triple bonds are stronger than the equivalent covalent bond, single bonds or double bond, double bonds, with a bond order of three. The most common triple bond is in a nitrogen N2 molecule; the second most common is that between two carbon atoms, which can be found in alkynes. Other functional groups containing a triple bond are cyanides and isocyanides. Some diatomic molecules, such as diphosphorus and carbon monoxide, are also triple bonded. In skeletal formula, skeletal formulae the triple bond is drawn as three parallel lines (≡) between the two connected atoms. Bonding Triple bonding can be explained in terms of orbital hybridization. In the case of acetylene, each carbon atom has two sp orbital, sp-orbitals and two p-orbitals. The two sp-orbitals are linear, with 180° bond angles, and occupy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Formate
Formate (IUPAC name: methanoate) is the conjugate base of formic acid. Formate is an anion () or its derivatives such as ester of formic acid. The salts and esters are generally colorless. Fundamentals When dissolved in water, formic acid converts to formate: : Formate is a planar anion. The two oxygen atoms are equivalent and bear a partial negative charge. The remaining C-H bond is not acidic. Biochemistry : Formate is a common C-1 source in living systems. It is formed from many precursors including choline, serine, and sarcosine. It provides a C-1 source in the biosynthesis of some nucleic acids. Formate (or formic acid) is invoked as a leaving group in the demethylation of some sterols. These conversions are catalyzed by aromatase enzymes using O2 as the oxidant. Specific conversions include testosterone to estradiol and androstenedione to estrone. Formate is reversibly oxidized by the enzyme formate dehydrogenase from ''Desulfovibrio gigas'': : Formate esters ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hermann Von Fehling
Hermann von Fehling (9 June 1812 – 1 July 1885) was a German chemist, famous as the developer of Fehling's solution used for estimation of sugar. Biography Hermann von Fehling was born in Lübeck. With the intention of taking up pharmacy he entered Heidelberg University about 1835. After graduating he went to Gießen as preparateur to Justus von Liebig, with whom he elucidated the composition of paraldehyde and metaldehyde. In 1839, on Liebig's recommendation, he was appointed to the chair of chemistry in the polytechnic in Stuttgart, a position he held for over 45 years. He died in Stuttgart in 1885. His earlier work included an investigation of succinic acid, and the preparation of phenyl cyanide (better known as benzonitrile), the simplest nitrile of the aromatic series. Later his time was mainly occupied with questions of technology and public health rather than with pure chemistry. Among the analytical methods he worked up the best known is that for the estimation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Théophile-Jules Pelouze
Théophile-Jules Pelouze (also known as Jules Pelouze), ; 26 February 180731 May 1867) was a French chemist. Life He was born at Valognes, and died in Paris. His father, Edmond Pelouze, was an industrial chemist and the author of several technical handbooks. The son, after spending some time in a pharmacy at La Fère acted as laboratory assistant to Gay-Lussac and Jean Louis Lassaigne at Paris from 1827 to 1829. In 1830 he was appointed associate professor of chemistry at Lille, but returning to Paris next year became ''repetiteur'', and subsequently professor at the École polytechnique. He also held the chair of chemistry at the Collège de France, and in 1833 became assayer to the mint and in 1848 president of the ''Commission des Monnaies''. After the coup d'état in 1851 he resigned his appointments, but continued to conduct an experimental laboratory-school he had started in 1846. There he worked with the explosive material guncotton and other nitrosulphates. His ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Justus Von Liebig
Justus ''Freiherr'' von Liebig (12 May 1803 – 18 April 1873) was a Germans, German scientist who made major contributions to the theory, practice, and pedagogy of chemistry, as well as to agricultural and biology, biological chemistry; he is considered one of the principal founders of organic chemistry. As a professor at the University of Giessen, he devised the modern laboratory-oriented teaching method, and for such innovations, he is regarded as one of the most outstanding chemistry teachers of all time. He has been described as the "father of the fertilizer industry" for his emphasis on nitrogen and minerals as essential plant nutrients, and his popularization of the law of the minimum, which states that plant growth is limited by the scarcest nutrient resource, rather than the total amount of resources available. He also developed a manufacturing process for Meat extract, beef extracts, and with his consent a company, called Liebig Extract of Meat Company, was founded to e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Friedrich Wöhler
Friedrich Wöhler Royal Society of London, FRS(For) HonFRSE (; 31 July 180023 September 1882) was a German chemist known for his work in both organic chemistry, organic and inorganic chemistry, being the first to isolate the chemical elements beryllium and yttrium in pure metallic form. He was the first to prepare several inorganic compounds, including silane and silicon nitride. Wöhler is also known for seminal contributions in organic chemistry, in particular, the Wöhler synthesis of urea. His synthesis of the organic compound urea in the laboratory from inorganic substances contradicted the belief that organic compounds could only be produced by living organisms due to a "life force". However, the exact extent of Wöhler's role in diminishing the belief in vitalism is considered by some to be questionable. Biography Friedrich Wöhler was born in Eschersheim, Germany, and was the son of a veterinarian. As a boy, he showed interest in mineral collecting, drawing, and science. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzoic Acid
Benzoic acid () is a white (or colorless) solid organic compound with the formula , whose structure consists of a benzene ring () with a carboxyl () substituent. The benzoyl group is often abbreviated "Bz" (not to be confused with "Bn," which is used for benzyl), thus benzoic acid is also denoted as BzOH, since the benzoyl group has the formula –. It is the simplest aromatic carboxylic acid. The name is derived from gum benzoin, which was for a long time its only source. Benzoic acid occurs naturally in many plants and serves as an intermediate in the biosynthesis of many secondary metabolites. Salts of benzoic acid are used as food preservatives. Benzoic acid is an important precursor for the industrial synthesis of many other organic substances. The salts and esters of benzoic acid are known as benzoates (). History Benzoic acid was discovered in the sixteenth century. The dry distillation of gum benzoin was first described by Nostradamus (1556), and then by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzonitrile
Benzonitrile is the chemical compound with the formula , abbreviated PhCN. This aromatic organic compound is a colorless liquid with a cherry or almond like odour. It is mainly used industrially to produce the melamine resin precursor benzoguanamine. Production and reactions It is prepared by ammoxidation of toluene, that is its reaction with ammonia and oxygen (or air) at . : + 3/2 + → + In the laboratory it can be prepared by the dehydration of benzamide or benzaldehyde oxime or by the Rosenmund–von Braun reaction using cuprous cyanide or NaCN/ DMSO and bromobenzene. : Hydrogenation of benzonitrile in principle gives benzylamine, but owing to transamination, dibenzylamine and tribenzylamine are also produced. Applications Laboratory uses Benzonitrile is a useful solvent and a versatile precursor to many derivatives. It reacts with amines to afford N-substituted benzamides after hydrolysis. It is a precursor to diphenylmethanimine via reaction with phen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Joseph Louis Gay-Lussac
Joseph Louis Gay-Lussac ( , ; ; 6 December 1778 – 9 May 1850) was a French chemist and physicist. He is known mostly for his discovery that water is made of two parts hydrogen and one part oxygen by volume (with Alexander von Humboldt), for two laws related to gases, and for his work on alcohol–water mixtures, which led to the degrees Gay-Lussac used to measure alcoholic beverages in many countries. Biography Gay-Lussac was born at Saint-Léonard-de-Noblat in the present-day department of Haute-Vienne. His father, Anthony Gay, son of a doctor, was a lawyer and prosecutor and worked as a judge in Noblat Bridge. Father of two sons and three daughters, he owned much of the Lussac village and began to add the name of this hamlet to his name, following a custom of the Ancien Régime. Towards the year 1803, father and son formally adopted the name Gay-Lussac. During the Revolution, under the Law of Suspects, his father, former king's attorney, was imprisoned in Saint L ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Reviews
''Chemical Reviews'' is peer-reviewed scientific journal published twice per month by the American Chemical Society. It publishes review articles on all aspects of chemistry. It was established in 1924 by William Albert Noyes (University of Illinois). The editor-in-chief is Sharon Hammes-Schiffer. Abstracting and indexing The journal is abstracted and indexed in Chemical Abstracts Service, CAB International, EBSCOhost, ProQuest, PubMed, Scopus, and the Science Citation Index. According to the ''Journal Citation Reports'', the journal has a 2023 impact factor of 51.4. Journal ranking summary Based on the latest announced rankings, ''Chemical Reviews'' is positioned among the top journals in the field of chemistry across multiple citation databases. The following table summarizes its performance across Scopus and Web of Science. Journal ranking summary (2023)JRank: Chemical Reviewshttps://jrank.net/journals/chem-rev/metrics/ref> See also * Accounts of Chemical Research ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carl Wilhelm Scheele
Carl Wilhelm Scheele (, ; 9 December 1742 – 21 May 1786) was a Swedish Pomerania, German-Swedish pharmaceutical chemist. Scheele discovered oxygen (although Joseph Priestley published his findings first), and identified the elements molybdenum, tungsten, barium, nitrogen, and chlorine, among others. Scheele discovered organic acids Tartaric acid, tartaric, Oxalic acid, oxalic, Uric acid, uric, Lactic acid, lactic, and Citric acid, citric, as well as Hydrofluoric acid, hydrofluoric, Hydrocyanic acid, hydrocyanic, and Arsenic acid, arsenic acids. He preferred speaking German to Swedish his whole life, as German was commonly spoken among Swedish pharmacists.Fors, Hjalmar 2008. "Stepping through Science’s Door: C. W. Scheele, from Pharmacist's Apprentice to Man of Science". Ambix 55: 29–49 Biography Scheele was born in Stralsund, in western Pomerania, which at the time was a Dominions of Sweden, Swedish Dominion inside the Holy Roman Empire. Scheele's father, Joachim (or Jo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
