Nickel Selenide
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Nickel Selenide
Nickel selenide is the inorganic compound with the formula NiSe. As for many metal chalcogenides, the phase diagram for nickel(II) selenide is complicated. Two other selenides of nickel are known, NiSe2 with a pyrite structure, and Ni2Se3. Additionally, NiSe is usually nonstoichiometric and is often described with the formula Ni1−xSe, with 0 < x < 0.15. This material is a solid, and can be obtained as in the form of a black fine powder, or silver if obtained in the form of larger crystals. Nickel(II) selenide is insoluble in all solvents, but can be degraded by strongly oxidizing acids.


Synthesis and structure

Typically, NiSe is prepared by high temperature reaction of the elements. Such reactions typically afford mixed phase products. Milder methods have also been described using more specialised technique ...
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Nickel
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classifie ...
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Selenium
Selenium is a chemical element; it has symbol (chemistry), symbol Se and atomic number 34. It has various physical appearances, including a brick-red powder, a vitreous black solid, and a grey metallic-looking form. It seldom occurs in this elemental state or as pure ore compounds in Earth's crust. Selenium ( ) was discovered in 1817 by , who noted the similarity of the new element to the previously discovered tellurium (named for the Earth). Selenium is found in :Sulfide minerals, metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells. Applications in electronics, once important, have been mostly replaced with silicon semiconductor devices. Selenium is still used in a few types of Direct current, DC power surge ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Chalcogenide
: 220px, Cadmium sulfide, a prototypical metal chalcogenide, is used as a yellow pigment. A chalcogenide is a chemical compound consisting of at least one chalcogen anion and at least one more electropositive element. Although all group 16 elements of the periodic table are defined as chalcogens, the term chalcogenide is more commonly reserved for sulfides, selenides, tellurides, and polonides, rather than oxides. Many metal ores exist as chalcogenides. Photoconductive chalcogenide glasses are used in xerography. Some pigments and catalysts are also based on chalcogenides. The metal dichalcogenide MoS2 is a common solid lubricant. Alkali metal and alkaline earth chalcogenides Alkali metal and alkaline earth monochalcogenides are salt-like, being colourless and often water-soluble. The sulfides tend to undergo hydrolysis to form derivatives containing bisulfide (SH−) anions. The alkali metal chalcogenides often crystallize with the antifluorite structure and the alkal ...
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Nickel(IV) Selenide
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an e ...
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Pyrite
The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue give it a superficial resemblance to gold, hence the well-known nickname of ''fool's gold''. The color has also led to the nicknames ''brass'', ''brazzle'', and ''brazil'', primarily used to refer to pyrite found in coal. The name ''pyrite'' is derived from the Greek (), 'stone or mineral which strikes fire', in turn from (), 'fire'. In ancient Roman times, this name was applied to several types of stone that would create sparks when struck against steel; Pliny the Elder described one of them as being brassy, almost certainly a reference to what is now called pyrite. By Georgius Agricola's time, , the term had become a generic term for all of the sulfide minerals. Pyrite is usually found associated with other sulfides or oxides in ...
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Pyrite Group
The pyrite group of minerals is a set of cubic crystal system minerals with diploidal structure. Each metallic element is bonded to six "dumbbell" pairs of non-metallic elements and each "dumbbell" pair is bonded to six metal atoms. The group is named for its most common member, pyrite (fool's gold), which is sometimes explicitly distinguished from the group's other members as ''iron pyrite''. Pyrrhotite (magnetic pyrite) is magnetic, and is composed of iron and sulfur, but it has a different structure and is not in the pyrite group. Pyrite group minerals Pyrite-group minerals include: * Aurostibite * Cattierite * Dzharkenite * Erlichmanite * Fukuchilite * Gaotaiite * Geversite * Hauerite * Insizwaite * Kruťaite * Krutovite * Laurite * Penroseite * Pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Py ...
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Nickel(III) Selenide
Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an e ...
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Nonstoichiometric Compound
Non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula , whereas the more common material is nonstoichiometric, with ...
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Semi-conducting
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easily in one d ...
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Nickel Arsenide
Nickel arsenide is a compound of nickel and arsenic and component of the ore nickeline. It is highly toxic and a known carcinogen in humans. Uncontrolled decomposition of nickel arsenide can give rise to further toxic nickel compounds. Toxicity Nickel arsenide was one of the first compounds that revealed the toxicity of nickel. The damage to the miners' lungs was documented by Georgius Agricola in the 16th century: "kupfer-nickel" ores in the Schneeberg mines contained red-colored NiAs mineral originally mistaken for the copper ore, thus the (copper) in the name. The (demon) name was reflecting the damage it did to the health of the workers, in addition to them being unable to extract any copper from this ore. The acute oral LD50 In toxicology, the median lethal dose, LD50 (abbreviation for "lethal dose, 50%"), LC50 (lethal concentration, 50%) or LCt50 is a toxic unit that measures the lethal dose of a given substance. The value of LD50 for a substance is the dose req ...
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