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Natural-gas
Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium. Methane is a colorless and odorless gas, and, after carbon dioxide, is the second-greatest greenhouse gas that contributes to global climate change. Because natural gas is odorless, a commercial odorizer, such as Methanethiol (mercaptan brand), that smells of hydrogen sulfide (rotten eggs) is added to the gas for the ready detection of gas leaks. Natural gas is a fossil fuel that is formed when layers of organic matter (primarily marine microorganisms) are thermally decomposed under oxygen-free conditions, subjected to intense heat and pressure underground over millions of years. The energy that the decayed organisms originally obtained from the sun via photosynthesis is stored as chemical energy within the molecules of methane and other ...
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Gas Flare
A gas flare, alternatively known as a flare stack, flare boom, ground flare, or flare pit, is a gas combustion device used in places such as petroleum refineries, chemical plants and natural gas processing plants, oil or gas extraction sites having oil wells, gas wells, offshore oil and gas rigs and landfills. In industrial plants, flare stacks are primarily used for burning off flammable gas released by safety valves during unplanned overpressuring of plant equipment. (See Chapter 11, ''Flare Stack Plume Rise''). During plant or partial plant startups and shutdowns, they are also often used for the planned combustion of gases over relatively short periods. At oil and gas extraction sites, gas flares are similarly used for a variety of startup, maintenance, testing, safety, and emergency purposes. In a practice known as production flaring, they may also be used to dispose of large amounts of unwanted associated petroleum gas, possibly throughout the life of an oil well. ...
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Gas Venting
Gas venting, more specifically known as natural-gas venting or methane venting, is the intentional and controlled release of gases containing alkane hydrocarbons - predominately methane - into Earth's atmosphere. It is a widely used method for disposal of unwanted gases which are produced during the extraction of coal and crude oil. Such gases may lack value when they are not recyclable into the production process, have no export route to consumer markets, or are surplus to near-term demand. In cases where the gases have value to the producer, substantial amounts may also be vented from the equipment used for gas collection, pipeline transport, transport, and distribution. Gas venting contributes strongly to climate change. Nevertheless, many individual cases are sufficiently small and dispersed to be deemed "safe" with regard to immediate health hazards. Large and concentrated releases are usually abated with gas flares to produce relatively less-harmful carbon dioxide gas. ...
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Odorizer
An odorizer is a device that adds an odorant to a gas. The most common type is one that adds a mercaptan liquid into natural gas distribution systems so that leaks can be readily detected. Other types have been used for carbon dioxide fire extinguishers. Natural gas odorizers Natural gas odorizers can vary from a simple wick in a container to computerized equipment, which controls the amount of odorant based on flow rate, tracks the amount of odorant in inventory, and alarms when odorant is not being injected into the gas stream. Odorants used for natural gas vary from country to country, depending on gas distribution regulations. Some odorants contain sulfur, which is oxidized to sulfur dioxide when the gas is burned. Sulfur-containing odorants include the following: * tert-Butylthiol (TBM) the main ingredient in many gas odorant blends * Tetrahydrothiophene (THT), used as an odorant for natural gas, usually in mixtures containing tert-butylthiol * 2-Propanethiol, commonl ...
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Gas-fired Power Plant
A gas-fired power plant, sometimes referred to as gas-fired power station, natural gas power plant, or methane gas power plant, is a thermal power station that burns natural gas to generate electricity. Gas-fired power plants generate almost a quarter of world electricity and are significant sources of greenhouse gas emissions. However, they can provide seasonal, dispatchable energy generation to compensate for variable renewable energy deficits, where hydropower or interconnectors are not available. In the early 2020s batteries became competitive with gas peaker plants. Basic concepts: heat into mechanical energy into electrical energy A gas-fired power plant is a type of fossil fuel power station in which chemical energy stored in natural gas, which is mainly methane, is converted successively into: thermal energy, mechanical energy and, finally, electrical energy. Although they cannot exceed the Carnot cycle limit for conversion of heat energy into useful work, the exc ...
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Helium
Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is the lowest among all the Chemical element, elements, and it does not have a melting point at standard pressures. It is the second-lightest and second-most Abundance of the chemical elements, abundant element in the observable universe, after hydrogen. It is present at about 24% of the total elemental mass, which is more than 12 times the mass of all the heavier elements combined. Its abundance is similar to this in both the Sun and Jupiter, because of the very high nuclear binding energy (per nucleon) of helium-4 with respect to the next three elements after helium. This helium-4 binding energy also accounts for why it is a product of both nuclear fusion and radioactive decay. The most common isotope of helium in the universe is helium-4, ...
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Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an Organic chemistry, organic Organic compound, compound, and among the simplest of organic compounds. Methane is also a hydrocarbon. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the Atmosphere of Earth, atmosphere, it is known as atmospheric methane. ...
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Alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like hexacontane () or 4-methyl-5-(1-methylethyl) octane, an isomer of dodecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula , and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote ''any'' saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes) or polycycl ...
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Petroleum
Petroleum, also known as crude oil or simply oil, is a naturally occurring, yellowish-black liquid chemical mixture found in geological formations, consisting mainly of hydrocarbons. The term ''petroleum'' refers both to naturally occurring unprocessed crude oil, as well as to petroleum products that consist of refining, refined crude oil. Petroleum is a fossil fuel formed over millions of years from anaerobic decay of organic materials from buried prehistoric life, prehistoric organisms, particularly planktons and algae, and 70% of the world's oil deposits were formed during the Mesozoic. Conventional reserves of petroleum are primarily recovered by oil drilling, drilling, which is done after a study of the relevant structural geology, sedimentary basin analysis, analysis of the sedimentary basin, and reservoir characterization, characterization of the petroleum reservoir. There are also unconventional (oil & gas) reservoir, unconventional reserves such as oil sands and oil sh ...
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Methanethiol
Methanethiol (also known as methyl mercaptan) is an organosulfur compound with the chemical formula . It is a colorless gas with a distinctive putrid smell. In small amounts, it is pervasive in nature and found in certain foods, such as some nuts and cheese. It contributes to many odors including the emissions from pulp mills, bad breath, and flatus. Methanethiol is the simplest thiol and is sometimes abbreviated as MeSH. It is flammable. Structure and reactions The molecule is tetrahedral at the carbon atom, like methanol. It is a weak acid, with a p''K''a of ~10.4, but is about a hundred thousand times more acidic than methanol. The colorless salt can be obtained by treatment with sodium methoxide: :CH3SH + CH3ONa → CH3SNa + CH3OH The thiolate anion in sodium methanethiolate is a strong nucleophile. It can be oxidized to dimethyl disulfide: :2CH3SH + → CH3SSCH3 + H2O Further oxidation takes the disulfide to two molecules of methanesulfonic acid, which is odorl ...
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Propane
Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum refining, it is often a constituent of liquefied petroleum gas (LPG), which is commonly used as a fuel in domestic and industrial applications and in low-emissions public transportation; other constituents of LPG may include propene, propylene, butane, butene, butylene, butadiene, and isobutylene. Discovered in 1857 by the French chemist Marcellin Berthelot, it became commercially available in the US by 1911. Propane has lower volumetric energy density than gasoline or coal, but has higher gravimetric energy density than them and burns more cleanly. Propane gas has become a popular choice for barbecues and portable stoves because its low −42 °C boiling point makes it vaporise inside pressurised liquid containers (it exists in two pha ...
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Ethane
Ethane ( , ) is a naturally occurring Organic compound, organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is List of purification methods in chemistry, isolated on an industrial scale from natural gas and as a petrochemical by-product of oil refinery, petroleum refining. Its chief use is as feedstock for ethylene production. The ethyl group is formally, although rarely practically, derived from ethane. History Ethane was first synthesised in 1834 by Michael Faraday, applying electrolysis of a potassium acetate solution. He mistook the hydrocarbon product of this reaction for methane and did not investigate it further. The process is now called Kolbe electrolysis: : acetate, CH3COO− → CH3• + carbon dioxide, CO2 + electron, e− : CH3• + •CH3 → C2H6 During the period 1847–1849, in an effort to vindicate the radical theory of organic chemistry, Hermann Kolbe ...
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Natural Gas Processing
Nature is an inherent character or constitution, particularly of the ecosphere or the universe as a whole. In this general sense nature refers to the laws, elements and phenomena of the physical world, including life. Although humans are part of nature, human activity or humans as a whole are often described as at times at odds, or outright separate and even superior to nature. During the advent of modern scientific method in the last several centuries, nature became the passive reality, organized and moved by divine laws. With the Industrial Revolution, nature increasingly became seen as the part of reality deprived from intentional intervention: it was hence considered as sacred by some traditions ( Rousseau, American transcendentalism) or a mere decorum for divine providence or human history ( Hegel, Marx). However, a vitalist vision of nature, closer to the pre-Socratic one, got reborn at the same time, especially after Charles Darwin. Within the various uses of the wo ...
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