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Methylpyrrolidone
''N''-Methyl-2-pyrrolidone (NMP) is an organic compound consisting of a 5-membered lactam. It is a colorless liquid, although impure samples can appear yellow. It is miscible with water and with most common organic solvents. It also belongs to the class of dipolar aprotic solvents such as dimethylformamide and dimethyl sulfoxide. It is used in the petrochemical, polymer and battery industries as a solvent, exploiting its nonvolatility and ability to dissolve diverse materials (including polyvinylidene difluoride, PVDF). It has a strong dipole moment and hydrogen bonding due to its cis-amide conformation. Preparation NMP is produced industrially by a typical ester-to-amide conversion, by treating gamma-butyrolactone with methylamine. Alternative routes include the partial hydrogenation of ''N''-methylsuccinimide and the reaction of acrylonitrile with methylamine followed by hydrolysis. About 200,000 to 250,000 tons are produced annually. Applications NMP is used to recover ...
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Twaron
Twaron (a brand name of Teijin Aramid) is a para-aramid, high-performance yarn. It is a heat-resistant fibre, helps in ballistic protection and cut protection. Twaron was developed in the early 1970s by the Dutch company Akzo Nobel's division Enka BV, later Akzo Industrial Fibers. The research name of the para-aramid fibre was originally Fiber X, but it was soon called Arenka. Although the Dutch para-aramid fiber was developed only a short time after DuPont's Kevlar, the introduction of Twaron as a commercial product came much later than Kevlar due to financial problems at the Akzo company in the 1970s. As of 2000, Twaron had become a global material and had been integrated into the global markets. Twaron has been around for over 30 years. History This is a chronology of the development of Twaron: * In 1960s a research program starts for "Fiber X." * In 1972 the ENKA Research laboratory develops a para-aramid called Arenka. * In 1973 Akzo decides to use sulfuric acid (H2SO4) ...
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Paint Stripper
Paint stripper or paint remover is a chemical product designed to remove paint, finishes, and coatings, while also cleaning the underlying surface. Chemical paint removers are advantageous because they act on any kind of geometry and they are cheap. They can however be slow acting. Paint can also be removed using mechanical methods (scraping or sanding) or heat (hot air, radiant heat, or steam). Types The selection of chemical paint removers is based on the chemical bonds that form the paint's binder. Two basic categories of chemical paint removers are caustic and solvent. Caustics Caustic paint removers, typically aqueous sodium hydroxide (also known as lye or caustic soda), work by breaking down the chemical bonds of the paint, usually by hydrolysis of the esters that comprise the paint film. Caustic removers must be neutralized or the new finish will fail prematurely. In addition, as caustic paint strippers typically include corrosive active ingredients, several side effect ...
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Aprotic
A polar aprotic solvent is a solvent that lacks an acidic proton and is polar. Such solvents lack hydroxyl and amine groups. In contrast to protic solvents, these solvents do not serve as proton donors in hydrogen bonding In chemistry, a hydrogen bond (H-bond) is a specific type of molecular interaction that exhibits partial covalent character and cannot be described as a purely electrostatic force. It occurs when a hydrogen (H) atom, Covalent bond, covalently b ..., although they can be proton acceptors. Many solvents, including chlorocarbons and hydrocarbons, are classifiable as aprotic, but polar aprotic solvents are of particular interest for their ability to dissolve salts. Methods for purification of common solvents are available. References * {{Chemical solutions Solvents ...
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Methylamine
Methylamine, also known as methanamine, is an organic compound with a formula of . This colorless gas is a derivative of ammonia, but with one hydrogen atom being replaced by a methyl group. It is the simplest primary amine. Methylamine is sold as a solution in methanol, ethanol, tetrahydrofuran, or water, or as the anhydrous gas in pressurized metal containers. Industrially, methylamine is transported in its anhydrous form in pressurized railcars and tank trailers. It has a strong odor similar to rotten fish. Methylamine is used as a building block for the synthesis of numerous other commercially available compounds. Industrial production Methylamine has been produced industrially since the 1920s (originally by Commercial Solvents Corporation for dehairing of animal skins). This was made possible by and his wife Eugenia who discovered amination of alcohols, including methanol, on alumina or kaolin catalyst after WWI, filed two patent applications in 1919 and published an a ...
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Miscible
Miscibility () is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). Such substances are said to be miscible (etymologically equivalent to the common term " mixable"). The term is most often applied to liquids but also applies to solids and gases. An example in liquids is the miscibility of water and ethanol as they mix in all proportions. By contrast, substances are said to be immiscible if the mixture does not form a solution for certain proportions. For one example, oil is not soluble in water, so these two solvents are immiscible. As another example, butanone (methyl ethyl ketone) is immiscible in water: it is soluble in water up to about 275 grams per liter, but will separate into two phases beyond that. Organic compounds In organic compounds, the weight percent of hydrocarbon chain often determines the compound's miscibility with water. For examp ...
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Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis is the cleavage of Biomolecule, biomolecules where a water molecule is consumed to effect the separation of a larger molecule into component parts. When a carbohydrate is broken into its component sugar molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can be the reverse of a condensation reaction in which two molecules join into a larger one and eject a water molecule. Thus hydrolysis adds water to break down, whereas condensation builds up by removing water. Types Usually hydrolysis is a chemical process in which a molecule of water is added to a substance. Sometimes this addition causes both the su ...
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Ashland Inc
Ashland, Inc., is an American chemical company headquartered in Wilmington, Delaware. The company was founded in the city of Ashland, Kentucky, in 1924, where it was headquartered before moving to Wilmington in 1994. The company has five wholly owned divisions, which include Chemical Intermediates and Solvents, Composites, Industrial Specialties, Personal and Home Care, & Pharmaceuticals, Food and Beverage, and Agriculture. Until 2017, the company was the primary manufacturer of Valvoline. History Founding and early years Ashland was founded in 1924 as the Ashland Refining Company in Catlettsburg, Kentucky, by Paul G. Blazer. In October 1923, J. Fred Miles of the Swiss Oil Company of Lexington, Kentucky Lexington is a Consolidated city-county, consolidated city coterminous with and the county seat of Fayette County, Kentucky, United States. As of the 2020 United States census, 2020 census the city's population was 322,570, making it the List of ..., employed Paul G. Blaze ...
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Kevlar
Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s as a replacement for steel in racing tires. It is typically spun into ropes or fabric sheets that can be used as such, or as an ingredient in composite material components. Kevlar has many applications, ranging from bicycle tires and sailcloth#Kevlar, racing sails to bulletproof vests, due to its high Specific strength, tensile strength-to-weight ratio; by this measure it is five times stronger than steel. It is also used to make modern marching drumheads that withstand high impact, and for Mooring, mooring lines and other underwater applications. A similar fiber, Twaron, with the same chemical structure was developed by Akzo in the 1970s. Commercial production started in 1986, and Twaron is manufactured by Teijin Aramid. History Poly- ...
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Aramid
Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic-rated bulletproof vest, body armor cloth, fabric and ballistic composites, in marine cordage, marine hull reinforcement, as an asbestos substitute, and in various lightweight consumer items ranging from phone cases to tennis rackets. The chain molecules in the fibers are highly oriented along the fiber axis. As a result, a higher proportion of the chemical bond contributes more to fiber strength than in many other synthetic fibres in the world. Aramids have a very high melting point (>). Common aramid brand names include Kevlar, Nomex, and Twaron. Terminology and chemical structure The term ''aramid'' is shortened from ''aromatic polyamide''. It was introduced in 1972, accepted in 1974 by the Federal Trade Commission of the USA as the name of a generic category of fiber distinct from nylon, and adopted by t ...
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Poly(p-phenylene Sulfide)
Polyphenylene sulfide (PPS) is an organic polymer consisting of aromatic rings linked by thioether, sulfides. Synthetic fiber and textiles derived from this polymer resist chemical and thermal attack. PPS is used in air filter, filter fabric for coal boilers, papermaking felts, electrical insulation, film capacitor#Polyphenylene sulfide (PPS) film capacitors, film capacitors, specialty synthetic membrane, membranes, gaskets, and seal (mechanical), packings. PPS is the precursor to a conductive polymer of the semi-flexible rod polymer family. The PPS, which is otherwise insulating, can be converted to the semiconductor, semiconducting form by oxidation or use of dopants.David Parker, Jan Bussink, Hendrik T. van de Grampel, Gary W. Wheatley, Ernst-Ulrich Dorf, Edgar Ostlinning, Klaus Reinking, "Polymers, High-Temperature" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH: Weinheim. Polyphenylene sulfide is an engineering plastic, commonly used today as a high-perf ...
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Textile
Textile is an Hyponymy and hypernymy, umbrella term that includes various Fiber, fiber-based materials, including fibers, yarns, Staple (textiles)#Filament fiber, filaments, Thread (yarn), threads, and different types of #Fabric, fabric. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the only manufacturing method, and many other methods were later developed to form textile structures based on their intended use. Knitting and Nonwoven, non-woven are other popular types of fabric manufacturing. In the contemporary world, textiles satisfy the material needs for versatile applications, from simple daily clothing to Bulletproof vest, bulletproof jackets, spacesuits, and Medical gown, doctor's gowns. Textiles are divided into two groups: consumer textiles for domestic purposes and technical textiles. In consumer textiles, Aesthetics (textile), aesthetics and Textile performance#Comfort, comfort are the most important factors, while in techn ...
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Polymer
A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compound (chemistry), compounds, produces unique physical property, physical properties including toughness, high rubber elasticity, elasticity, viscoelasticity, and a tendency to form Amorphous solid, amorphous and crystallization of polymers, semicrystalline structures rath ...
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