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Manganous Oxide
Manganese(II) oxide is an inorganic compound with chemical formula MnO.Arno H. Reidies "Manganese Compounds" Ullmann's Encyclopedia of Chemical Technology 2007; Wiley-VCH, Weinheim. It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives. Structure, stoichiometry, reactivity Like many metal monoxides, MnO adopts the rock salt structure, where cations and anions are both octahedrally coordinated. Also like many metal oxides, manganese(II) oxide is often nonstoichiometric: its composition can vary from MnO to MnO1.045. Below 118 K, MnO is antiferromagnetic. MnO has the distinction of being one of the first compounds to have its magnetic structure determined by neutron diffraction, the report appearing in 1951. This study showed that the Mn2+ ions form a face centered cubic magnetic sub-lattice where there are ferromagnetically coupled sheets that are anti-parallel with adjacent sheets. Manganese(II) oxide undergoes ...
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Manganosite
Manganosite is a rare mineral composed of manganese(II) oxide MnO. It was first described in 1817 for an occurrence in the Harz Mountains, Saxony-Anhalt, Germany. It has also been reported from Langban and Nordmark, Sweden and at Franklin Furnace, New Jersey. It also occurs in Japan, Kyrgyzstan and Burkina Faso. It occurs in manganese nodules. It also occurs as alteration of manganese minerals such as rhodocrosite during low oxygen metamorphism and metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com .... References Oxide minerals Manganese(II) minerals Cubic minerals Minerals in space group 225 Rocksalt group {{oxide-mineral-stub ...
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Food Additives
Food additives are substances added to food to preserve flavor or enhance taste, appearance, or other sensory qualities. Some additives, such as vinegar ( pickling), salt ( salting), smoke (smoking) and sugar (crystallization), have been used for centuries to preserve food. This allows for longer-lasting foods, such as bacon, sweets, and wines. With the advent of ultra-processed foods in the late 20th century, many additives having both natural and artificial origin were introduced. Food additives also include substances that may be introduced to food indirectly (called "indirect additives") in the manufacturing process through packaging, storage or transport. In Europe and internationally, many additives are designated with E numbers, while in the United States, additives in amounts deemed safe for human consumption are designated as GRAS. Identification To regulate these additives and inform consumers each additive is assigned a unique number called an "E number", which ...
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Ferrous Oxide
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists of hydrated iron(III) oxide (ferric oxide). Iron(II) oxide also refers to a family of related non-stoichiometric compounds, which are typically iron deficient with compositions ranging from Fe0.84O to Fe0.95O. Preparation FeO can be prepared by the thermal decomposition of iron(II) oxalate. : The procedure is conducted under an inert atmosphere to avoid the formation of iron(III) oxide (). A similar procedure can also be used for the synthesis of manganous oxide and stannous oxide. Stoichiometric FeO can be prepared by heating Fe0.95O with metallic iron at 770 °C and 36 kbar.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford University Press Reactions FeO is thermodynamically unstable below 575 °C, ...
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Calcining
Calcination is thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), generally for the purpose of removing impurities or volatile substances and/or to incur thermal decomposition. The root of the word calcination refers to its most prominent use, which is to remove carbon from limestone (calcium carbonate) through combustion to yield calcium oxide (quicklime). This calcination reaction is CaCO3(s) → CaO(s) + CO2(g). Calcium oxide is a crucial ingredient in modern cement, and is also used as a chemical flux in smelting. Industrial calcination generally emits carbon dioxide (). A calciner is a steel cylinder that rotates inside a heated furnace and performs indirect high-temperature processing (550–1150 °C, or 1000–2100 °F) within a controlled atmosphere. Etymology The process of calcination der ...
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Manganese(II) Nitrate
Manganese(II) nitrate refers to the inorganic compounds with formula Mn( NO3)2·(H2O)n. These compounds are nitrate salts containing varying amounts of water. A common derivative is the tetrahydrate, Mn(NO3)2·4H2O, but mono- and hexahydrates are also known as well as the anhydrous compound. Some of these compounds are useful precursors to the oxides of manganese. Typical of a manganese(II) compound, it is a paramagnetic pale pink solid. Structure Manganese(II) compounds, especially with oxygenated ligands, are typically octahedral. Following this trend, the tetrahydrate features four aquo ligands bound to Mn as well as two mutually cis, unidentate nitrate ligands. The hexaaquo salt features octahedral n(H2O)6sup>2+. Preparation, reactions, uses Manganese(II) nitrate is prepared from manganese dioxide and nitrogen dioxide: : In this redox reaction, two moles of the reductant (gas) donate each one electron to (black solid), the oxidant, which is reduced from its oxi ...
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Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an Organic chemistry, organic Organic compound, compound, and among the simplest of organic compounds. Methane is also a hydrocarbon. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the Atmosphere of Earth, atmosphere, it is known as atmospheric methane. ...
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Carbon Monoxide
Carbon monoxide (chemical formula CO) is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest oxocarbon, carbon oxide. In coordination complexes, the carbon monoxide ligand is called ''metal carbonyl, carbonyl''. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds. Numerous environmental and biological sources generate carbon monoxide. In industry, carbon monoxide is important in the production of many compounds, including drugs, fragrances, and fuels. Indoors CO is one of the most acutely toxic contaminants affecting indoor air quality. CO may be emitted from tobacco smoke and generated from malfunctioning fuel-burning stoves (wood, kerosene, natural gas, propane) and fuel-burning heating systems (wood, oil, n ...
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Hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the chemical formula, formula , called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas (dihydrogen) and in molecular forms, such as in water and organic compounds. The most common isotope of hydrogen (H) consists of one proton, one electron, and no neutrons. Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovere ...
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Manganosite
Manganosite is a rare mineral composed of manganese(II) oxide MnO. It was first described in 1817 for an occurrence in the Harz Mountains, Saxony-Anhalt, Germany. It has also been reported from Langban and Nordmark, Sweden and at Franklin Furnace, New Jersey. It also occurs in Japan, Kyrgyzstan and Burkina Faso. It occurs in manganese nodules. It also occurs as alteration of manganese minerals such as rhodocrosite during low oxygen metamorphism and metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com .... References Oxide minerals Manganese(II) minerals Cubic minerals Minerals in space group 225 Rocksalt group {{oxide-mineral-stub ...
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Manganese(III) Oxide
Manganese(III) oxide is a chemical compound with the formula Mn2O3. It occurs in nature as the mineral bixbyite (recently changed to bixbyite-(Mn)IMA 21-H: Redefinition of bixbyite and definition of bixbyite-(Fe) and bixbyite-(Mn). CNMNC Newsletter, 64, 2021; Mineralogical Magazine, 85, 2021).) and is used in the production of ferrites and thermistors. Preparation and chemistry Heating MnO2 in air at below 800 °C produces α-Mn2O3 (higher temperatures produce Mn3O4). γ-Mn2O3 can be produced by oxidation followed by dehydration of manganese(II) hydroxide. Many preparations of nano-crystalline Mn2O3 have been reported, for example syntheses involving oxidation of MnII salts or reduction of MnO2. Manganese(III) oxide is formed by the redox reaction in an alkaline cell: : 2 MnO2 + Zn → Mn2O3 + ZnO Manganese(III) oxide Mn2O3 must not be confused with MnOOH manganese(III) oxyhydroxide. Contrary to Mn2O3, MnOOH is a compound that decomposes at about 300 °C to form MnO ...
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Chemical Reaction
A chemical reaction is a process that leads to the chemistry, chemical transformation of one set of chemical substances to another. When chemical reactions occur, the atoms are rearranged and the reaction is accompanied by an Gibbs free energy, energy change as new products are generated. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the Atomic nucleus, nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive Chemical element, elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reagent, reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more Product (c ...
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Neutron Diffraction
Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of Neutron temperature, thermal or cold neutron radiation, neutrons to obtain a diffraction pattern that provides information of the structure of the material. The technique is similar to X-ray diffraction but due to their different scattering properties, neutrons and X-rays provide complementary information: X-Rays are suited for superficial analysis, strong x-rays from synchrotron radiation are suited for shallow depths or thin specimens, while neutrons having high penetration depth are suited for bulk samples.Measurement of residual stress in materials using neutrons
IAEA, ...
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