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Isophthalate
Isophthalic acid is an organic compound with the formula C6H4(CO2H)2. This colorless solid is an isomer of phthalic acid and terephthalic acid. The main industrial uses of purified isophthalic acid (PIA) are for the production of polyethylene terephthalate (PET) resin and for the production of unsaturated polyester resin (UPR) and other types of coating resins. Isophthalic acid is one of three isomers of benzenedicarboxylic acid, the others being phthalic acid and terephthalic acid. Crystalline isophthalic acid is built up from molecules connected by hydrogen bonds, forming infinite chains. Preparation Isophthalic acid is produced on the billion kilogram per year scale by oxidizing meta-xylene using oxygen. The process employs a cobalt-manganese catalyst. The world's largest producer of isophthalic acid is Lotte Chemical Corporation. In the laboratory, chromic acid can be used as the oxidant. It also arises by fusing potassium meta-sulfobenzoate, or meta-bromobenzoate wi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polybenzimidazole
Polybenzimidazole (PBI, short for poly[2,2’-(''m''-phenylen)-5,5’-bisbenzimidazole]) fiber is a synthetic fiber with a very high decomposition temperature. It does not exhibit a melting point, it has exceptional thermal and chemical stability, and it does not readily ignite. It was first discovered in 1961, by American polymer chemist Carl Shipp Marvel in the pursuit of new materials with superior stability, retention of stiffness, and toughness at elevated temperature. Due to its high stability, polybenzimidazole is used to fabricate high-performance protective apparel such as Bunker gear, firefighter's gear, Space suit, astronaut space suits, high temperature protective gloves, welders’ apparel and aircraft wall fabrics. Polybenzimidazole has been applied as a Proton exchange membrane fuel cell, membrane in fuel cells. History Discovery Brinker and Robinson first reported aliphatic polybenzimidazoles in 1949. However the discovery of aromatic polybenzimidazole, which sho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carboxylic Acid
In organic chemistry, a carboxylic acid is an organic acid that contains a carboxyl group () attached to an Substituent, R-group. The general formula of a carboxylic acid is often written as or , sometimes as with R referring to an organyl group (e.g., alkyl, alkenyl, aryl), or hydrogen, or other groups. Carboxylic acids occur widely. Important examples include the amino acids and fatty acids. Deprotonation of a carboxylic acid gives a carboxylate anion. Examples and nomenclature Carboxylic acids are commonly identified by their trivial names. They often have the suffix ''-ic acid''. IUPAC-recommended names also exist; in this system, carboxylic acids have an ''-oic acid'' suffix. For example, butyric acid () is butanoic acid by IUPAC guidelines. For nomenclature of complex molecules containing a carboxylic acid, the carboxyl can be considered position one of the parent chain even if there are other substituents, such as 3-chloropropanoic acid. Alternately, it can be named ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lotte Chemical Corporation
Lotte Chemical Corporation () is a chemical company headquartered in Seoul, South Korea. Lotte Chemical is one of the largest chemical companies in the world by revenue. Lotte Chemical manufactures synthetic resins and other chemical products used for various industrial materials. History Lotte Chemical was established as Honam Petrochemical in 1976 and became part of Lotte Group after three years. After being integrated into Lotte, the company acquired various companies for business expansion. In 2010, Honam took over Malaysia's Titan Chemicals for US$1.27 billion to expand its business to the Southeast Asian market. In 2012, Honam merged with KP Chemical and was renamed Lotte Chemical. Lotte Chemical acquired Samsung's chemical businesses, including Samsung SDI's chemical unit, Samsung Fine Chemicals, and Samsung BP Chemicals for 3 trillion won in 2016. Products Lotte Chemical produces ethylene, polyethylene, and polypropylene by using naphtha extracted from crude oil. Subs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plastic Bottle
A plastic bottle is a bottle constructed from high-density or low density plastic. Plastic bottles are typically used to store liquids such as water, soft drinks, motor oil, cooking oil, medicine, shampoo or milk. They range in sizes, from very small bottles to large carboys. Consumer blow molded containers often have integral package handle, handles or are shaped to facilitate grasping. Plastic was invented in the nineteenth century and was originally used to replace common materials such as ivory, rubber, and shellac. Plastic bottles were first used commercially in 1947, but remained relatively expensive until the early 1950s when high-density polyethylene was introduced. They quickly became popular with both manufacturers and customers because compared to glass bottles, plastic bottles are lighter, cheaper and easier to transport. However, the biggest advantage plastic bottles have over their glass counterparts is their superior resistance to Structural integrity and failure, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nomex
Nomex is a trademarked term for an inherently flame-resistant fabric with meta-aramid chemistry widely used for industrial applications and fire protection equipment. It was developed in the early 1960s by DuPont and first marketed in 1967. The fabric is often combined with Kevlar to increase its resistance for breakage or tear. Properties Nomex and related aramid polymers are related to nylon, but have aromatic backbones, and hence are more rigid and more durable. Nomex is an example of a '' meta'' variant of the aramids (Kevlar is a '' para'' aramid). Unlike Kevlar, Nomex strands cannot align during filament polymerization and have less strength: its ultimate tensile strength is . However, it has excellent thermal, chemical, and radiation resistance for a polymer material. It can withstand temperatures of up to . Production Nomex is produced by condensation reaction from the monomers ''m''-phenylenediamine and isophthaloyl chloride. It is sold in both fiber and s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acyl Chloride
In organic chemistry, an acyl chloride (or acid chloride) is an organic compound with the functional group . Their formula is usually written , where R is a side chain. They are reactive derivatives of carboxylic acids (). A specific example of an acyl chloride is acetyl chloride, . Acyl chlorides are the most important subset of acyl halides. Nomenclature Where the acyl chloride moiety takes priority, acyl chlorides are named by taking the name of the parent carboxylic acid, and substituting ''-yl chloride'' for ''-ic acid''. Thus: : : : butyr''ic acid'' (C3H7COOH) → butyr''yl chloride'' (C3H7COCl) (Idiosyncratically, for some trivial names, ''-oyl chloride'' substitutes ''-ic acid''. For example, pival''ic acid'' becomes pival''oyl chloride'' and acryl''ic acid'' becomes acryl''oyl chloride.'' The names pivalyl chloride and acrylyl chloride are less commonly used, although they are arguably more logical.) When other functional groups take priority, acyl chlorides a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dicarboxylic Acid
In organic chemistry, a dicarboxylic acid is an organic compound containing two carboxyl groups (). The general molecular formula for dicarboxylic acids can be written as , where R can be aliphatic or aromatic.Boy Cornils, Peter Lappe "Dicarboxylic Acids, Aliphatic" in Ullmann's Encyclopedia of Industrial Chemistry 2014, Wiley-VCH, Weinheim. In general, dicarboxylic acids show similar chemical behavior and reactivity to monocarboxylic acids. Dicarboxylic acids are usually colorless solids. A wide variety of dicarboxylic acids are used in industry. Adipic acid, for example, is a precursor to certain kinds of nylon. A wide variety of dicarboxylic acids are found in nature. Aspartic acid and glutamic acid are two amino acids found in all life. Succinic and fumaric acids are essential for metabolism. A large inventory of derivatives are known including many mono- and diesters, amides, etc. Partial list of saturated dicarboxylic acids Some common or illustrative examples : ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aromaticity
In organic chemistry, aromaticity is a chemical property describing the way in which a conjugated ring of unsaturated bonds, lone pairs, or empty orbitals exhibits a stabilization stronger than would be expected from conjugation alone. The earliest use of the term was in an article by August Wilhelm Hofmann in 1855. There is no general relationship between aromaticity as a chemical property and the olfactory properties of such compounds. Aromaticity can also be considered a manifestation of cyclic delocalization and of resonance. This is usually considered to be because electrons are free to cycle around circular arrangements of atoms that are alternately single- and double- bonded to one another. This commonly seen model of aromatic rings, namely the idea that benzene was formed from a six-membered carbon ring with alternating single and double bonds (cyclohexatriene), was developed by Kekulé (see History section below). Each bond may be seen as a hybrid of a single bo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyroracemic Acid
Pyruvic acid (CH3COCOOH) is the simplest of the alpha-keto acids, with a carboxylic acid and a ketone functional group. Pyruvate, the conjugate base, CH3COCOO−, is an intermediate in several metabolic pathways throughout the cell. Pyruvic acid can be made from glucose through glycolysis, converted back to carbohydrates (such as glucose) via gluconeogenesis, or converted to fatty acids through a reaction with acetyl-CoA. It can also be used to construct the amino acid alanine and can be converted into ethanol or lactic acid via fermentation. Pyruvic acid supplies energy to cell (biology), cells through the citric acid cycle (also known as the Krebs cycle) when oxygen is present (aerobic respiration), and alternatively lactic acid fermentation, ferments to produce lactic acid, lactate when oxygen is lacking. Chemistry In 1834, Théophile-Jules Pelouze distilled tartaric acid and isolated glutaric acid and another unknown organic acid. Jöns Jacob Berzelius characterized this o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mesitylene
Mesitylene or 1,3,5-trimethylbenzene is a derivative of benzene with three methyl substituents positioned symmetrically around the ring. The other two isomeric trimethylbenzenes are 1,2,4-trimethylbenzene (pseudocumene) and 1,2,3-trimethylbenzene (hemimellitene). All three compounds have the formula C6H3(CH3)3, which is commonly abbreviated C6H3Me3. Mesitylene is a colorless liquid with sweet aromatic odor. It is a component of coal tar, which is its traditional source. It is a precursor to diverse fine chemicals. The mesityl group (Mes) is a substituent with the formula C6H2Me3 and is found in various other compounds. Preparation Mesitylene is prepared by transalkylation of xylene over solid acid catalyst:Karl Griesbaum, Arno Behr, Dieter Biedenkapp, Heinz-Werner Voges, Dorothea Garbe, Christian Paetz, Gerd Collin, Dieter Mayer, Hartmut Höke “Hydrocarbons” in Ullmann's Encyclopedia of Industrial Chemistry 2002 Wiley-VCH, Weinheim. . :2 C6H4(CH3)2 ⇌ C6H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Water Of Crystallization
In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a chemical substance, substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the Crystal structure, crystalline framework of a metal complex or a salt (chemistry), salt, which is not directly chemical bond, bonded to the metal cation. Upon crystallization from water, or water-containing solvents, many chemical compound, compounds incorporate water molecules in their crystalline frameworks. Water of crystallization can generally be removed by heating a sample but the crystalline properties are often lost. Compared to Inorganic compound, inorganic salts, proteins crystallize with large amounts of water i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
