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Hydrolysable Tannin
A hydrolysable tannin or pyrogallol-type tannin is a type of tannin that, on heating with hydrochloric or sulfuric acids, yields gallic or ellagic acids. At the center of a hydrolysable tannin molecule, there is a carbohydrate (usually D-glucose but also cyclitols like quinic or shikimic acids). The hydroxyl groups of the carbohydrate are partially or totally esterified with phenolic groups such as gallic acid in gallotannins or ellagic acid in ellagitannins. Hydrolysable tannins are mixtures of polygalloyl glucoses and/or poly-galloyl quinic acid derivatives containing in between 3 up to 12 gallic acid residues per molecule. Hydrolysable tannins are hydrolysed by weak acids or weak bases to produce carbohydrate and phenolic acids. Examples of gallotannins are the gallic acid esters of glucose in tannic acid (C76H52O46), found in the leaves and bark of many plant species. Hydrolysable tannins can be extracted from different vegetable plants, such as chestnut wood (''Cast ...
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Pyrogallol
Pyrogallol is an organic compound with the formula C6H3(OH)3. It is a water-soluble, white solid although samples are typically brownish because of its sensitivity toward oxygen. It is one of three isomers of benzenetriols. Production and reactions It is produced in the manner first reported by Scheele in 1786: heating gallic acid to induce decarboxylation. Gallic acid is also obtained from tannin. Many alternative routes have been devised. One preparation involves treating ''para''-chlorophenoldisulfonic acid with potassium hydroxide, a variant on the time-honored route to phenols from sulfonic acids. Polyhydroxybenzenes are relatively electron-rich. One manifestation is the easy C-acetylation of pyrogallol. Uses It was once used in hair dyeing, dyeing of suturing materials. It also has antiseptic properties. In alkaline solution, pyrogallol undergoes deprotonation. Such solutions absorb oxygen from the air, turning brown. This conversion can be used to determine ...
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Glucose
Glucose is a sugar with the Chemical formula#Molecular formula, molecular formula , which is often abbreviated as Glc. It is overall the most abundant monosaccharide, a subcategory of carbohydrates. It is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, using energy from sunlight. It is used by plants to make cellulose, the most abundant carbohydrate in the world, for use in cell walls, and by all living Organism, organisms to make adenosine triphosphate (ATP), which is used by the cell as energy. In energy metabolism, glucose is the most important source of energy in all organisms. Glucose for metabolism is stored as a polymer, in plants mainly as amylose and amylopectin, and in animals as glycogen. Glucose circulates in the blood of animals as blood sugar. The naturally occurring form is -glucose, while its Stereoisomerism, stereoisomer L-glucose, -glucose is produced synthetically in comparatively small amounts and is less biologicall ...
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Quercus Infectoria
''Quercus infectoria'' or the Aleppo oak is a species of oak well known for producing galls (called manjakani in Malaysia, majuphal in India) that have been traditionally used for centuries in Asia medicinally while also used in softening leather and in making black dye and ink. Description ''Quercus infectoria'' is a small tree, growing to in height. The stems are crooked, shrubby looking with smooth and bright-green leaves borne on short petioles of long. The leaves are bluntly mucronate, rounded, smooth, unequal at the base and shiny on the upper side. The galls arise on young branches of the tree when gall wasps sting the oak tree and deposit their larvae. The chemical reaction causes an abnormality in the tree, causing hard balls to be formed. They are corrugated in appearance. Gall chemistry The galls from ''Quercus infectoria'' contain the highest naturally occurring level of tannin, approximately 50–70%, as well as syringic acid, β-sitosterol, amentoflavone, hexa ...
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Gall
Galls (from the Latin , 'oak-apple') or ''cecidia'' (from the Greek , anything gushing out) are a kind of swelling growth on the external tissues of plants. Plant galls are abnormal outgrowths of plant tissues, similar to benign tumors or warts in animals. They can be caused by various parasites, from viruses, fungi and bacteria, to other plants, insects and mites. Plant galls can be such highly organized structures that their cause can be determined without the actual agent being identified. This applies particularly to insect and mite plant galls. The study of plant galls is known as cecidology. Anatomy Shape and size Galls develop on various plant organs, providing nutrition and shelter to inducing insects. Galls display vast variation in morphology, size, and wall composition. The size of insect galls can range significantly, from approximately two inches in diameter to less than one-sixteenth of an inch. Some galls are so small that they are merely slightly thick ...
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Caesalpinia Spinosa
''Tara spinosa'', commonly known as ''tara'' ( Quechua), also known as Peruvian carob or spiny holdback, is a small leguminous tree or thorny shrub native to Peru. ''T. spinosa'' is cultivated as a source of tannins based on a galloylated quinic acid structure. This chemical structure has been confirmed also by LC–MS.M. N. Clifford, S. Stoupi and N. Kuhnert''Profiling and Characterization by LC-MSn of the Galloylquinic Acids of Green Tea, Tara Tannin, and Tannic Acid'' J. Agric. Food Chem., 2007, 55 (8), pp. 2797-2807. DOI: 10.1021/jf063533l. Publication Date (Web): March 24, 2007. It is also grown as an ornamental plant because of its large colorful flowers and pods. Names and taxonomy Its common names include spiny holdback, ''tara'', ''taya'', and ''algarroba tanino'' (Peru). ''Tara spinosa'' is placed in the family Fabaceae, subfamily Caesalpinioideae, and tribe Caesalpinieae. Description ''Tara spinosa'' typically grows tall; its bark is dark gray with scattered prick ...
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Quercus Alba
''Quercus alba'', the white oak, is one of the preeminent hardwoods of eastern and central North America. It is a long-lived oak, native to eastern and central North America and found from Minnesota, Ontario, Quebec, and southern Maine south as far as northern Florida and eastern Texas. Specimens have been documented to be over 450 years old. Although called a white oak, it is very unusual to find an individual specimen with white bark; the usual colour is a light gray. The name comes from the colour of the finished wood. In the forest it can reach a magnificent height and in the open it develops into a massive broad-topped tree with large branches striking out at wide angles. Description ''Quercus alba'' typically reaches heights of at maturity, and its canopy can become quite massive as its lower branches are apt to extend far out laterally, parallel to the ground. Trees growing in a forest will become much taller than ones in an open area which develop to be short and mass ...
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Quercus Petraea
''Quercus petraea'', commonly known as the sessile oak, Welsh oak, Cornish oak, Irish oak or durmast oak, is a species of oak tree native to most of Europe and into Anatolia and Iran. The sessile oak is the national tree of Ireland, and an unofficial emblem in Wales and Cornwall. Description The sessile oak is a large deciduous tree up to tall, in the white oak section of the genus (''Quercus'' sect. ''Quercus'') and similar to the pedunculate oak (''Q. robur''), with which it overlaps extensively in range. The leaves are long and broad, evenly lobed with five to six lobes on each side and a petiole. The male flowers are grouped into catkins, produced in the spring. The fruit is an acorn long and broad, which matures in about six months. File:Divljanski stari hrast.jpg, Old sacred oak ( zapis) in Divljana, Serbia File:Quercus petraea 02.jpg, Shoot with leaves and acorn File:Eglinton fish pond island inosculated Q. petraea.JPG, An inosculated tree File:Sessile O ...
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Quercus Robur
''Quercus robur'', the pedunculate oak, is a species of flowering plant in the beech and oak family, Fagaceae. It is a large tree, native plant, native to most of Europe and western Asia, and is widely cultivated in other temperate regions. It grows on soils of near neutral Soil pH, acidity in the lowlands and is notable for its value to natural ecosystems, supporting a very wide diversity of herbivorous insects and other pests, predators and pathogens. Description Pedunculate oak is a deciduous tree up to tall, with a single stout trunk that can be as much as in girth (circumference at breast height) or even 14 m in Pollarding, pollarded specimens. Older trees tend to be pollarded, with boles (the main trunk) about 3 m long. They often live longer and become more stout than unpollarded trees. The crown is spreading and unevenly domed, and trees often have massive lower branches. The bark is greyish-brown and closely grooved, with vertical plates. There are often large burrs ...
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Castanea Sativa
The sweet chestnut (''Castanea sativa''), also known as the Spanish chestnut or European chestnut, is a species of tree in the family Fagaceae, native to Southern Europe and Asia Minor, and widely cultivated throughout the Temperate climate, temperate world. A substantial, long-lived deciduous tree, it produces an edible seed, the chestnut, which has been used in cooking since ancient times. Description ''Castanea sativa'' attains a height of with a trunk often in diameter. Around 20 trees are recorded with diameters over including one in diameter at breast height. A famous ancient tree known as the Hundred Horse Chestnut in Sicily was historically recorded at in diameter (although it has split into multiple trunks above ground). The bark often has a net-shaped (retiform) pattern with deep furrows or fissures running spirally in both directions up the trunk. The trunk is mostly straight with branching starting at low heights. The Leaf shape, oblong-lanceolate, boldly toot ...
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Chestnut
The chestnuts are the deciduous trees and shrubs in the genus ''Castanea'', in the beech family Fagaceae. The name also refers to the edible nuts they produce. They are native to temperate regions of the Northern Hemisphere. Description Chestnut trees are of moderate growth rate (for the Chinese chestnut tree) to fast-growing for American and European species. Their mature heights vary from the smallest species of chinkapins, often shrubby,''Chestnuts, Horse-Chestnuts, and Ohio Buckeyes''
. In Yard and Garden Brief, Horticulture department at University of Minnesota.
to the giant of past American forests, '' C. dentata'' that could reach . Between these extremes ar ...
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Plants
Plants are the eukaryotes that form the kingdom Plantae; they are predominantly photosynthetic. This means that they obtain their energy from sunlight, using chloroplasts derived from endosymbiosis with cyanobacteria to produce sugars from carbon dioxide and water, using the green pigment chlorophyll. Exceptions are parasitic plants that have lost the genes for chlorophyll and photosynthesis, and obtain their energy from other plants or fungi. Most plants are multicellular, except for some green algae. Historically, as in Aristotle's biology, the plant kingdom encompassed all living things that were not animals, and included algae and fungi. Definitions have narrowed since then; current definitions exclude fungi and some of the algae. By the definition used in this article, plants form the clade Viridiplantae (green plants), which consists of the green algae and the embryophytes or land plants ( hornworts, liverworts, mosses, lycophytes, ferns, conifers and other ...
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Plant
Plants are the eukaryotes that form the Kingdom (biology), kingdom Plantae; they are predominantly Photosynthesis, photosynthetic. This means that they obtain their energy from sunlight, using chloroplasts derived from endosymbiosis with cyanobacteria to produce sugars from carbon dioxide and water, using the green pigment chlorophyll. Exceptions are parasitic plants that have lost the genes for chlorophyll and photosynthesis, and obtain their energy from other plants or fungi. Most plants are multicellular organism, multicellular, except for some green algae. Historically, as in Aristotle's biology, the plant kingdom encompassed all living things that were not animals, and included algae and fungi. Definitions have narrowed since then; current definitions exclude fungi and some of the algae. By the definition used in this article, plants form the clade Viridiplantae (green plants), which consists of the green algae and the embryophytes or land plants (hornworts, liverworts ...
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