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Homogeneous Broadening
Homogeneous broadening is a type of emission spectrum broadening in which all atoms radiating from a specific level under consideration radiate with equal opportunity. If an optical emitter (e.g. an atom) shows homogeneous broadening, its spectral linewidth is its natural linewidth, with a Lorentzian profile. Broadening in laser systems Broadening in laser physics is a physical phenomenon that affects the spectroscopic line shape of the laser emission profile. The laser emission is due to the (excitation and subsequent) relaxation of a quantum system (atom, molecule, ion, etc.) between an excited state (higher in energy) and a lower one. These states can be thought of as the eigenstates of the energy operator. The difference in energy between these states is proportional to the frequency/wavelength of the photon emitted. Since this energy difference has a fluctuation, then the frequency/wavelength of the "macroscopic emission" (the beam) will have a certain width (i.e. it will b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Emission Spectrum
The emission spectrum of a chemical element or chemical compound is the Spectrum (physical sciences), spectrum of frequencies of electromagnetic radiation emitted due to electrons making a atomic electron transition, transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances. Emission In physics, emission is the process by which a higher energy quantum mechanical state of a particle becomes converted to a lower one through the emis ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Magnetic Resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. High-resolution nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crysta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Line Shape
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentz distribution, Lorentzian, Normal distribution, Gaussian and Voigt function, Voigt functions, whose parameters are the line position, maximum height and half-width. Actual line shapes are determined principally by Doppler broadening, Doppler, Spectral line#Broadening and shift, collision and proximity broadening. For each system the half-width of the shape function varies with temperature, pressure (or concentration (chemistry), concentration) and phase. A knowledge of shape function is needed for spectroscopic curve fitting and deconvolution. Origins A spectral line can result from an electron transition in an atom, molecule or ion, which is associated with a specific amount of energy, ''E''. When this energy is measured by means of some spectroscopic te ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Voigt Profile
The Voigt profile (named after Woldemar Voigt) is a probability distribution given by a convolution of a Cauchy-Lorentz distribution and a Gaussian distribution. It is often used in analyzing data from spectroscopy or diffraction. Definition Without loss of generality, we can consider only centered profiles, which peak at zero. The Voigt profile is then : V(x;\sigma,\gamma) \equiv \int_^\infty G(x';\sigma)L(x-x';\gamma)\, dx', where ''x'' is the shift from the line center, G(x;\sigma) is the centered Gaussian profile: : G(x;\sigma) \equiv \frac, and L(x;\gamma) is the centered Lorentzian profile: : L(x;\gamma) \equiv \frac. The defining integral can be evaluated as: : V(x;\sigma,\gamma)=\frac, where Re 'w''(''z'')is the real part of the Faddeeva function evaluated for : z=\frac. In the limiting cases of \sigma=0 and \gamma =0 then V(x;\sigma,\gamma) simplifies to L(x;\gamma) and G(x;\sigma), respectively. History and applications In spectroscopy, a Voi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Homogeneity (physics)
In physics, a homogeneous material or system has the same properties at every point; it is uniform without irregularities. (accessed November 16, 2009). Tanton, James. "homogeneous." Encyclopedia of Mathematics. New York: Facts On File, Inc., 2005. Science Online. Facts On File, Inc. "A polynomial in several variables p(x,y,z,…) is called homogeneous [...] more generally, a function of several variables f(x,y,z,…) is homogeneous [...] Identifying homogeneous functions can be helpful in solving differential equations [and] any formula that represents the mean of a set of numbers is required to be homogeneous. In physics, the term homogeneous describes a substance or an object whose properties do not vary with position. For example, an object of uniform density is sometimes described as homogeneous." James. homogeneous (math). (accessed: 2009-11-16) A uniform electric field (which has the same strength and the same direction at each point) would be compatible with homogeneity ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Permittivity
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter (epsilon), is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy in the material. In electrostatics, the permittivity plays an important role in determining the capacitance of a capacitor. In the simplest case, the electric displacement field resulting from an applied electric field E is \mathbf = \varepsilon\ \mathbf ~. More generally, the permittivity is a thermodynamic State function, function of state. It can depend on the Dispersion (optics), frequency, Nonlinear optics, magnitude, and Anisotropy, direction of the applied field. The International System of Units, SI unit for permittivity is farad per meter (F/m). The permittivity is often represented by the relative permittivity which is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Semiconductor
A semiconductor is a material with electrical conductivity between that of a conductor and an insulator. Its conductivity can be modified by adding impurities (" doping") to its crystal structure. When two regions with different doping levels are present in the same crystal, they form a semiconductor junction. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called " metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common semiconductor and is used in laser diodes, solar cells, microwave-frequency integrated circuits, and others. Silicon is a critical element for fabricating most electronic circuits. Semiconductor devices can display a range of different useful properties, such as passing current more easil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic Field
A magnetic field (sometimes called B-field) is a physical field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, electric currents, and electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function (mathematics), function assigning a Euclidean vector, vector to each point of space, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microwave
Microwave is a form of electromagnetic radiation with wavelengths shorter than other radio waves but longer than infrared waves. Its wavelength ranges from about one meter to one millimeter, corresponding to frequency, frequencies between 300 MHz and 300 GHz, broadly construed. A more common definition in radio-frequency engineering is the range between 1 and 100 GHz (wavelengths between 30 cm and 3 mm), or between 1 and 3000 GHz (30 cm and 0.1 mm). In all cases, microwaves include the entire super high frequency, super high frequency (SHF) band (3 to 30 GHz, or 10 to 1 cm) at minimum. The boundaries between far infrared, terahertz radiation, microwaves, and ultra-high-frequency (UHF) are fairly arbitrary and differ between different fields of study. The prefix ' in ''microwave'' indicates that microwaves are small (having shorter wavelengths), compared to the radio waves used in prior radio technology. Frequencies in the micr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Normal Distribution
In probability theory and statistics, a normal distribution or Gaussian distribution is a type of continuous probability distribution for a real-valued random variable. The general form of its probability density function is f(x) = \frac e^\,. The parameter is the mean or expectation of the distribution (and also its median and mode), while the parameter \sigma^2 is the variance. The standard deviation of the distribution is (sigma). A random variable with a Gaussian distribution is said to be normally distributed, and is called a normal deviate. Normal distributions are important in statistics and are often used in the natural and social sciences to represent real-valued random variables whose distributions are not known. Their importance is partly due to the central limit theorem. It states that, under some conditions, the average of many samples (observations) of a random variable with finite mean and variance is itself a random variable—whose distribution c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectral Linewidth
A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible. Types of line spectra Spectral lines are the result of interaction between a quantum system (usually atoms, but sometimes molecules or atomic nuclei) and a single photon. When a photon has about the right amount of energy (which is connected to its frequency) to allow a change in the energy state of the system (in the case of an atom this is usually an electron changing orbitals), the photon is absorbed. Then the energy will be spontaneously re-emitted, either as one photon at the same f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
