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High-pressure Chemistry
High-pressure chemistry is concerned with those chemical processes that are carried out under high pressure – pressures in the thousands of bars (100 k Pa) or higher. High-pressure processes are generally faster and have a higher conversion efficiency than processes at ambient pressure. However, they are usually only beneficial on an industrial scale because of the investment in plant required.Rupert Stevenson Bradley, Duncan Cottrel Munro, ''High Pressure Chemistry'' Pergamon Press, 1965 . The Haber–Bosch process produces ammonia from hydrogen and atmospheric nitrogen. It was first demonstrated in 1909 and became an important industrial process for Germany during World War One when it played a part in the manufacture of explosives. Today, it is mostly used to produce fertilizer. The Bergius process produces hydrocarbon fuel from bituminous coal and hydrogen. The process was first published in 1913 and was an important source of fuel for Germany during World War Two. Th ...
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High Pressure
In science and engineering the study of high pressure examines its effects on materials and the design and construction of devices, such as a diamond anvil cell, which can create high pressure. ''High pressure'' usually means pressures of thousands (kilo bars) or millions (megabars) of times atmospheric pressure (about 1 bar or 100,000 Pa). History and overview Percy Williams Bridgman received a Nobel Prize in 1946 for advancing this area of physics by two magnitudes of pressure (400 MPa to 40 GPa). The list of founding fathers of this field includes also the names of Harry George Drickamer, Tracy Hall, Francis P. Bundy, , and . It was by applying high pressure as well as high temperature to carbon that synthetic diamonds were first produced alongside many other interesting discoveries. Almost any material when subjected to high pressure will compact itself into a denser form, for example, quartz (also called silica or silicon dioxide) will first adopt a denser form known ...
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World War Two
World War II or the Second World War (1 September 1939 – 2 September 1945) was a global conflict between two coalitions: the Allies and the Axis powers. Nearly all of the world's countries participated, with many nations mobilising all resources in pursuit of total war. Tanks and aircraft played major roles, enabling the strategic bombing of cities and delivery of the first and only nuclear weapons ever used in war. World War II is the deadliest conflict in history, causing the death of 70 to 85 million people, more than half of whom were civilians. Millions died in genocides, including the Holocaust, and by massacres, starvation, and disease. After the Allied victory, Germany, Austria, Japan, and Korea were occupied, and German and Japanese leaders were tried for war crimes. The causes of World War II included unresolved tensions in the aftermath of World War I and the rise of fascism in Europe and militarism in Japan. Key events preceding the war ...
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Nylon
Nylon is a family of synthetic polymers characterised by amide linkages, typically connecting aliphatic or Polyamide#Classification, semi-aromatic groups. Nylons are generally brownish in color and can possess a soft texture, with some varieties exhibiting a silk-like appearance. As Thermoplastic, thermoplastics, nylons can be melt-processed into fibres, Thin film, films, and diverse shapes. The properties of nylons are often modified by blending with a variety of additives. Numerous types of nylon are available. One family, designated nylon-XY, is derived from diamines and dicarboxylic acids of carbon chain lengths X and Y, respectively. An important example is nylon-6,6 (). Another family, designated nylon-Z, is derived from amino acid, aminocarboxylic acids with carbon chain length Z. An example is nylon-[6]. Nylon polymers have extensive commercial applications, including uses in textiles and fibres (such as apparel, flooring and rubber reinforcement), molded components fo ...
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Vladimir Ipatieff
Vladimir Nikolayevich Ipatieff, also Ipatyev (; – 29 November 1952) was a Russian and American chemist. His most important contributions are in the field of petroleum chemistry and catalysts. Life and career Born in Moscow, Ipatieff first studied artillery in the Mikhailovskaya Artillery Academy in Petersburg, then later studied chemistry in Russia with Alexei Yevgrafovich Favorskii and in Germany. The prominence of his extended family is illustrated by the fact that the July 17, 1918, murders of Czar Nicholas Romanoff, the Empress and the rest of the royal family took place in the basement of a vacation house owned by the Ipatieff family in Ekaterinburg. His first works in chemistry were devoted to the study of metals and explosives. Later, his works on catalysis methods under high pressure made him famous as a chemist; for his reactions he used massive steel autoclaves (sometimes called Ipatieff bombs). With the start of World War I, Ipatieff organized a dedicated laborat ...
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Hanns Hörbiger
Johannes "Hanns" Evangelist Hörbiger (29 November 1860, in Atzgersdorf – 11 October 1931, in Mauer) was an Austrian engineer from Vienna with roots in Tyrol. He took part in the construction of the Budapest subway and in 1894 invented a new type of valve essential for compressors still in widespread use today. He is also remembered today for his pseudoscientific Welteislehre ("World Ice doctrine"). Early life Hanns Hörbiger was born in Atzgersdorf, a suburb of Liesing, Vienna, and studied engineering at the local Technical College. In 1894 Hörbiger had an idea for a new design of blast furnace blowing engine: he replaced the old and easily damaged leather flap valves with a steel valve. Opening and closing automatically, and light and frictionless guided, the disk valve eliminated all the drawbacks of previous valve designs. Hörbiger registered a patent for his invention, which smoothed the way for efficient steel production and greater productivity in mining. Hi ...
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Otto Ruff
Otto Ruff (30 December 1871 – 17 September 1939) was a German chemist. Life Otto Ruff was born in Schwäbisch Hall, Württemberg. After becoming a pharmacist under the supervision of Carl Magnus von Hell (known from the Hell-Volhard-Zelinsky halogenation) at the University of Stuttgart he joined the group of Hermann Emil Fischer at the University of Berlin. Fischer was noted for his work on carbohydrates (sugars) and so Ruff started his career as an organic chemist. In 1898 he published his work on the transformation of d-Glucose to d-Arabinose, later called the Ruff degradation. Supported by the far-sighted Fischer, who recognized that while organic chemistry was now mature, physical chemistry was growing rapidly, Ruff became head of the new inorganic department in Berlin, working alongside Alfred Stock who was five years his junior. This drastic change in subject benefited Ruff during his work on chlorides sulfur compounds. In 1902 he married Meta Richter, a pharmacist ...
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Jiri Jonas
Jiri Jonas (born April 1, 1932, in Prague, Czech Republic) is a professor emeritus of chemistry in the Center for Advanced Study at the University of Illinois at Urbana-Champaign. Jiri Jonas is considered a pioneer in the use of magnetic resonance imaging at high pressure, developing techniques to study the dynamic structure of liquids and proteins. This approach has been used in the study of the arc repressor, a DNA-binding protein containing 53 amino acid residues. Education and career Jiri Jonas was awarded his B. S. Degree at the University of Prague in 1956. In 1960 he received his a PhD from the Czechoslovak Academy of Sciences, where he worked with Josef Pliva. He won awards for scientific work from the academy in 1958, 1960 and 1964. In 1966, Jonas joined became a professor at the University of Illinois at Urbana-Champaign. He became the second director of the Beckman Institute for Advanced Science and Technology at the University of Illinois, and was instrumental ...
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Carl Bosch
Carl Bosch (; 27 August 1874 – 26 April 1940) was a German chemist and engineer and Nobel Laureate in Chemistry. He was a pioneer in the field of high-pressure industrial chemistry and founder of IG Farben, at one point the world's largest chemical company. He also developed the Haber–Bosch process, important for the large-scale synthesis of fertilizers and explosives. It is estimated that one-third of annual global food production uses ammonia from the Haber–Bosch process, and that this supports nearly half of the world's population. In addition, he co-developed the so-called Bosch-Meiser process for the industrial production of urea. Biography Early years Carl Bosch was born in Cologne to a successful gas and plumbing supplier. His father was Carl Friedrich Alexander Bosch (1843–1904) and his uncle was Robert Bosch, who pioneered the development of the spark plug and founded the multinational company Bosch. Carl, trying to decide between a career in metallu ...
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Friedrich Bergius
Friedrich Karl Rudolf Bergius (, 11 October 1884 – 30 March 1949) was a German chemist known for the Bergius process for producing synthetic fuel from coal, Nobel Prize in Chemistry (1931, together with Carl Bosch) in recognition of contributions to the invention and development of chemical high-pressure methods. Having worked with IG Farben during World War II, his citizenship came into question following the war, causing him to ultimately flee to Argentina, where he acted as adviser to the Ministry of Industry. Early life Bergius was born near Breslau (Wrocław), then in the German Empire. Academic career Before studying chemistry, Bergius was sent to work for 6 months at the Friedrich Wilhelms steel works in Mülheim. His studies started at the University of Breslau in 1903 and ended with a PhD in chemistry at the University of Leipzig in 1907, after only 4 years. His thesis on sulfuric acid as solvent was supervised by Arthur Rudolf Hantzsch. In 1909 Bergius worked fo ...
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Nobel Prize In Chemistry
The Nobel Prize in Chemistry () is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for outstanding contributions in chemistry, physics, literature, peace, and physiology or medicine. This award is administered by the Nobel Foundation and awarded by the Royal Swedish Academy of Sciences on proposal of the Nobel Committee for Chemistry, which consists of five members elected by the Academy. The award is presented in Stockholm at an annual ceremony on December 10th, the anniversary of Nobel's death. The first Nobel Prize in Chemistry was awarded in 1901 to Jacobus Henricus van 't Hoff, of the Netherlands, "for his discovery of the laws of chemical dynamics and osmotic pressure in solutions". From 1901 to 2024, the award has been bestowed on a total of 195 individuals. The 2024 Nobel Prize in Chemistry was awarded to Demis Hassabis ...
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Bituminous Coal
Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the coal seam, seams. It is typically hard but friable. Its quality is Coal analysis#Coal classification by rank, ranked higher than lignite and sub-bituminous coal, but lesser than anthracite. It is the most abundant rank of coal, with deposits found around the world, often in rocks of Carboniferous age. Bituminous coal is formed from sub-bituminous coal that is buried deeply enough to be heated to or higher. Bituminous coal is used primarily for electrical power generation and in the steel industry. Bituminous coal suitable for smelting iron (''coking coal'' or ''metallurgical coal'') must be low in sulfur and phosphorus. It commands a higher price than other grades of bituminous coal (thermal coal) used for heating and power generation. Within the ...
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Bar (unit)
The bar is a metric unit of pressure defined as 100,000  Pa (100 kPa), though not part of the International System of Units (SI). A pressure of 1 bar is slightly less than the current average atmospheric pressure on Earth at sea level (approximately 1.013 bar). By the barometric formula, 1 bar is roughly the atmospheric pressure on Earth at an altitude of 111 metres at 15 °C. The bar and the millibar were introduced by the Norwegian meteorologist Vilhelm Bjerknes, who was a founder of the modern practice of weather forecasting, with the bar defined as one megadyne per square centimetre. The SI brochure, despite previously mentioning the bar, now omits any mention of it.. The bar has been legally recognised in countries of the European Union since 2004. British Standard BS 350:2004 ''Conversion Factors for Units''. The US National Institute of Standards and Technology (NIST) deprecates its use except for "limited use in meteorology" and lists ...
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