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Hexanitrohexaazaisowurtzitane
Hexanitrohexaazaisowurtzitane, also called HNIW and CL-20, is a polycyclic compound, polycyclic nitroamine explosive with the formula . It has a better Redox, oxidizer-to-fuel ratio than conventional HMX or RDX. It releases 20% more energy than traditional HMX-based propellants. History and use In the 1980s, CL-20 was developed by the Naval Air Weapons Station China Lake, China Lake facility, primarily to be used in propellants. While most development of CL-20 has been fielded by the Thiokol, Thiokol Corporation, the US Navy (through Office of Naval Research, ONR) has also been interested in CL-20 for use in rocket propellants, such as for missiles, as it has lower observability characteristics such as less visible smoke. Thus far, CL-20 has only been used in the AeroVironment Switchblade 300 “kamikaze” drone, but is undergoing testing for use in the Lockheed Martin [LMT] AGM-158C Long Range Anti-Ship Missile (LRASM) and AGM-158B Joint Air-to-Surface Standoff Missile-Exten ...
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Benzylamine
Benzylamine, also known as phenylmethylamine, is an Organic chemistry, organic chemical compound with the Structural formula#Condensed formulas, condensed structural formula C6H5CH2NH2 (sometimes abbreviated as Phenyl group#Nomenclature, PhCH2NH2 or Benzyl#Abbreviations, BnNH2). It consists of a benzyl group, C6H5CH2, attached to an amine functional group, NH2. This colorless water-soluble liquid is a common precursor in organic chemistry and used in the industrial production of many pharmaceuticals. The hydrochloride salt was used to treat motion sickness on the Mercury-Atlas 6 mission in which NASA astronaut John Glenn became the first American to orbit the Earth. Manufacturing Benzylamine can be produced by several methods, the main industrial route being the reaction of benzyl chloride and ammonia. It is also produced by the reduction of benzonitrile and reductive amination of benzaldehyde, both done over Raney nickel. : It was first produced accidentally by Rudolf Leucka ...
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Rocket Propellant
Rocket propellant is used as reaction mass ejected from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and nozzle, not by "pushing" against the air behind or below it. Rocket engines perform best in outer space because of the lack of air pressure on the outside of the engine. In space it is also possible to fit a longer nozzle without suffering from flow separation. Most chemical propellants release energy through redox chemistry, more specifically combustion. As such, both an oxidizing agen ...
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Metre Per Second
The metre per second is the unit of both speed (a scalar (physics), scalar quantity) and velocity (a Vector (mathematics and physics), vector quantity, which has direction and magnitude) in the International System of Units (SI), equal to the speed of a body covering a distance of one metre in a time of one second. According to the definition of metre, is exactly \frac of the speed of light. The International System of Units, SI unit symbols are m/s, m·s−1, m s−1, or . Conversions is equivalent to: : = 3.6 kilometres per hour, km/h (exactly) : ≈ 3.2808 feet per second (approximately) : ≈ 2.2369 miles per hour (approximately) : ≈ 1.9438 knot (unit), knots (approximately) 1 feet per second, foot per second = (exactly) 1 miles per hour, mile per hour = (exactly) 1 kilometres per hour, km/h = (exactly) Relation to other measures The benz, named in honour of Karl Benz, has been proposed as a name for one metre per second. Although it has seen some suppor ...
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HF-3
The Hsiung Feng III (HF-3; , "Brave Wind III") is a medium range supersonic missile with capabilities to destroy both land based targets and naval targets developed by the National Chung-Shan Institute of Science and Technology (NCSIST) in Taiwan. Design Initial prototype versions of the missile used the design of an integrated rocket ramjet to achieve supersonic speeds. It uses a solid fuel main booster with two side-by-side solid-propellant jettisonable strap-on rocket boosters for initial acceleration and a liquid-fueled ramjet for sustained cruise. It also employs electronic counter-countermeasures (ECCM) capabilities allowing it to penetrate an enemy ship's defenses. The missile is cylindrical in shape and composed of three sections, namely guidance and control, warhead, and propulsion. The body has four inlet ducts and four clipped delta control surfaces. It used the inertial navigation system (INS) during mid-course navigation phase and active radar seeker at terminal gu ...
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Journal Of Physics And Chemistry Of Solids
A journal, from the Old French ''journal'' (meaning "daily"), may refer to: *Bullet journal, a method of personal organization *Diary, a record of personal secretive thoughts and as open book to personal therapy or used to feel connected to oneself. A record of what happened over the course of a day or other period *Daybook, also known as a general journal, a daily record of financial transactions *Logbook, a record of events important to the operation of a vehicle, facility, or otherwise * Transaction log, a chronological record of data processing *Travel journal, a record of the traveller's experience during the course of their journey In publishing, ''journal'' can refer to various periodicals or serials: *Academic journal, an academic or scholarly periodical **Scientific journal, an academic journal focusing on science **Medical journal, an academic journal focusing on medicine **Law review, a professional journal focusing on legal interpretation *Magazine, non-academic or sch ...
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Cocrystal
In materials science (specifically crystallography), cocrystals are "solids that are crystalline, single- phase materials composed of two or more different molecular or ionic compounds generally in a stoichiometric ratio which are neither solvates nor simple salts." A broader definition is that cocrystals "consist of two or more components that form a unique crystalline structure having unique properties." Several subclassifications of cocrystals exist. Cocrystals can encompass many types of compounds, including hydrates, solvates and clathrates, which represent the basic principle of host–guest chemistry. Hundreds of examples of cocrystallization are reported annually. History The first reported cocrystal, quinhydrone, was studied by Friedrich Wöhler in 1844. Quinhydrone is a cocrystal of quinone and hydroquinone (known archaically as quinol). He found that this material was made up of a 1:1 molar combination of the components. Quinhydrone was analyzed by numerous groups ...
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Adam Matzger
Adam J. Matzger, a researcher in polymers and crystals, is the Charles G. Overberger Collegiate Professor of Chemistry at the University of Michigan. Biography Matzger is a native of Piedmont, California but moved to Ohio to complete his undergraduate career at Oberlin College, where he graduated with a Bachelor of Arts in Chemistry in 1992. From there he moved back to California for his graduate work at the University of California at Berkeley where he studied under Professor Peter C. Vollhardt. In 1997 he earned his Ph. D. degree with a thesis titled "Synthetic, Theoretical, and Structural Studies on Dehydrobenzoannulenes and Phenylenes." He then was a Postdoctoral Researcher at California Institute of Technology (co-mentored by Robert H. Grubbs and Nathan S. Lewis) until 2000 when he was appointed Assistant Professor of Chemistry and of Macromolecular Science and Engineering at the University of Michigan. In 2006 he became an Associate Professor and finally a full Pr ...
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Combust
Combust can refer to: * Combust (astrological aspect), the obscuring of the unassisted viewing of a planet by the Sun's light * Combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
, the exothermic chemical reaction {{Disambig ...
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Nitrosonium Tetrafluoroborate
Nitrosonium tetrafluoroborate, also called nitrosyl tetrafluoroborate, is a chemical compound with the chemical formula NOBF4. This colourless solid is used in organic synthesis as a nitrosating agent, diazotizing agent and a mild oxidant. NOBF4 is the nitrosonium salt of fluoroboric acid, and is composed of a nitrosonium cation, Osup>+, and a tetrafluoroborate anion, F4sup>−. Reactions The dominant property of NOBF4 is the oxidizing power and electrophilic character of the nitrosonium cation. It forms colored charge transfer complexes with hexamethylbenzene and with 18-crown-6. The latter, a deep yellow species, provides a means to dissolve NOBF4 in dichloromethane. Nitrosonium tetrafluoroborate may be used to prepare metal salts of the type II(CH3CN)''x''F4sub>2 (M = Cr, Mn, Fe, Co, Ni, Cu). The nitrosonium cation acts as the oxidizer, itself being reduced to nitric oxide gas: : With ferrocene the ferrocenium tetrafluoroborate is formed. In its infrared spectrum ...
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Nitronium Tetrafluoroborate
Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents. Preparation Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide. Applications Nitronium tetrafluoroborate is used in organic synthesis as an electrophilic nitrating agent and a mild oxidant An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "Electron acceptor, accepts"/"receives" an electron from a (called the , , or ''electr .... References Tetrafluoroborates Nitronium compounds {{ino ...
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Acetic Anhydride
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the chemical formula, formula . Commonly abbreviated , it is one the simplest organic acid anhydride, anhydrides of a carboxylic acid and is widely used in the production of cellulose acetate as well as a reagent in organic synthesis. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with moisture in the air. Structure and properties Acetic anhydride, like most organic acid anhydrides, is a flexible molecule with a nonplanar structure. The C=O and C-O distances are 1.19 and 1.39 Å. The Pi bond, pi system linkage through the central oxygen offers very weak resonance stabilization compared to the dipole, dipole-dipole repulsion between the two carbonyl oxygens. The energy barriers to bond rotation between each of the optimal aplanar conformations are quite low. Production Acetic anhydride was first synthesized in 1852 by the French chemist Charles Frédéric Gerhardt ...
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