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Flow Process
The region of space enclosed by open system boundaries is usually called a control volume. It may or may not correspond to physical walls. It is convenient to define the shape of the control volume so that all flow of matter, in or out, occurs perpendicular to its surface. One may consider a process in which the matter flowing into and out of the system is chemically homogeneous.Shavit, A., Gutfinger, C. (1995). ''Thermodynamics. From Concepts to Applications'', Prentice Hall, London, , Chapter 6. Then the inflowing matter performs work as if it were driving a piston of fluid into the system. Also, the system performs work as if it were driving out a piston of fluid. Through the system walls that do not pass matter, heat () and work () transfers may be defined, including shaft work. Classical thermodynamics considers processes for a system that is initially and finally in its own internal state of thermodynamic equilibrium, with no flow. This is feasible also under some restric ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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First Law Open System
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Control Volume
In continuum mechanics and thermodynamics, a control volume (CV) is a mathematical abstraction employed in the process of creating mathematical models of physical processes. In an inertial frame of reference, it is a fictitious region of a given volume fixed in space or moving with constant flow velocity through which the continuum ( gas, liquid or solid) flows. The closed surface enclosing the region is referred to as the control surface. At steady state, a control volume can be thought of as an arbitrary volume in which the mass of the continuum remains constant. As a continuum moves through the control volume, the mass entering the control volume is equal to the mass leaving the control volume. At steady state, and in the absence of work and heat transfer, the energy within the control volume remains constant. It is analogous to the classical mechanics concept of the free body diagram. Overview Typically, to understand how a given physical law applies to the system under con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Internal Energy
The internal energy of a thermodynamic system is the total energy contained within it. It is the energy necessary to create or prepare the system in its given internal state, and includes the contributions of potential energy and internal kinetic energy. It keeps account of the gains and losses of energy of the system that are due to changes in its internal state. It does not include the kinetic energy of motion of the system as a whole, or any external energies from surrounding force fields. The internal energy of an isolated system is constant, which is expressed as the law of conservation of energy, a foundation of the first law of thermodynamics. The internal energy is an extensive property. The internal energy cannot be measured directly and knowledge of all its components is rarely interesting, such as the static rest mass energy of its constituent matter. Thermodynamics is chiefly concerned only with ''changes'' in the internal energy, not with its absolute value. Inste ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Mechanical Device
A machine is a physical system that uses power to apply forces and control movement to perform an action. The term is commonly applied to artificial devices, such as those employing engines or motors, but also to natural biological macromolecules, such as molecular machines. Machines can be driven by animals and people, by natural forces such as wind and water, and by chemical, thermal, or electrical power, and include a system of mechanisms that shape the actuator input to achieve a specific application of output forces and movement. They can also include computers and sensors that monitor performance and plan movement, often called mechanical systems. Renaissance natural philosophers identified six simple machines which were the elementary devices that put a load into motion, and calculated the ratio of output force to input force, known today as mechanical advantage. Modern machines are complex systems that consist of structural elements, mechanisms and control componen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Enthalpy
Enthalpy , a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; bond, lattice, solvation and other "energies" in chemistry are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal energy, pressure, and volume, not on the path taken to achieve it. In the International System of Units (SI), the unit of measurement for enthalpy is the j ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Thermodynamic Potential
A thermodynamic potential (or more accurately, a thermodynamic potential energy)ISO/IEC 80000-5, Quantities an units, Part 5 - Thermodynamics, item 5-20.4 Helmholtz energy, Helmholtz functionISO/IEC 80000-5, Quantities an units, Part 5 - Thermodynamics, item 5-20.5, Gibbs energy, Gibbs function is a scalar quantity used to represent the thermodynamic state of a system. The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886. Josiah Willard Gibbs in his papers used the term ''fundamental functions''. One main thermodynamic potential that has a physical interpretation is the internal energy . It is the energy of configuration of a given system of conservative forces (that is why it is called potential) and only has meaning with respect to a defined set of references (or data). Expressions for all other thermodynamic energy potentials are derivable via Legendre transforms from an expression for . In thermodynamics, external forces, such as gravity, ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Steady-state (chemical Engineering)
In chemistry, a steady state is a situation in which all state variables are constant in spite of ongoing processes that strive to change them. For an entire system to be at steady state, i.e. for all state variables of a system to be constant, there must be a flow through the system (compare mass balance). A simple example of such a system is the case of a bathtub with the tap running but with the drain unplugged: after a certain time, the water flows in and out at the same rate, so the water level (the state variable Volume) stabilizes and the system is in a steady state. The steady state concept is different from chemical equilibrium. Although both may create a situation where a concentration does not change, in a system at chemical equilibrium, the net reaction rate is zero ( products transform into reactants at the same rate as reactants transform into products), while no such limitation exists in the steady state concept. Indeed, there does not have to be a reaction at all ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Turbine
A turbine ( or ) (from the Greek , ''tyrbē'', or Latin ''turbo'', meaning vortex) is a rotary mechanical device that extracts energy from a fluid flow and converts it into useful work. The work produced by a turbine can be used for generating electrical power when combined with a generator.Munson, Bruce Roy, T. H. Okiishi, and Wade W. Huebsch. "Turbomachines." Fundamentals of Fluid Mechanics. 6th ed. Hoboken, NJ: J. Wiley & Sons, 2009. Print. A turbine is a turbomachine with at least one moving part called a rotor assembly, which is a shaft or drum with blades attached. Moving fluid acts on the blades so that they move and impart rotational energy to the rotor. Early turbine examples are windmills and waterwheels. Gas, steam, and water turbines have a casing around the blades that contains and controls the working fluid. Credit for invention of the steam turbine is given both to Anglo-Irish engineer Sir Charles Parsons (1854–1931) for invention of the reaction turbine, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Pump
A pump is a device that moves fluids ( liquids or gases), or sometimes slurries, by mechanical action, typically converted from electrical energy into hydraulic energy. Pumps can be classified into three major groups according to the method they use to move the fluid: ''direct lift'', ''displacement'', and ''gravity'' pumps. Mechanical pumps serve in a wide range of applications such as pumping water from wells, aquarium filtering, pond filtering and aeration, in the car industry for water-cooling and fuel injection, in the energy industry for pumping oil and natural gas or for operating cooling towers and other components of heating, ventilation and air conditioning systems. In the medical industry, pumps are used for biochemical processes in developing and manufacturing medicine, and as artificial replacements for body parts, in particular the artificial heart and penile prosthesis. When a casing contains only one revolving impeller, it is called a single-stage ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Engine
An engine or motor is a machine designed to convert one or more forms of energy into mechanical energy. Available energy sources include potential energy (e.g. energy of the Earth's gravitational field as exploited in hydroelectric power generation), heat energy (e.g. geothermal), chemical energy, electric potential and nuclear energy (from nuclear fission or nuclear fusion). Many of these processes generate heat as an intermediate energy form, so heat engines have special importance. Some natural processes, such as atmospheric convection cells convert environmental heat into motion (e.g. in the form of rising air currents). Mechanical energy is of particular importance in transportation, but also plays a role in many industrial processes such as cutting, grinding, crushing, and mixing. Mechanical heat engines convert heat into work via various thermodynamic processes. The internal combustion engine is perhaps the most common example of a mechanical heat engine, in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Power (physics)
In physics, power is the amount of energy transferred or converted per unit time. In the International System of Units, the unit of power is the watt, equal to one joule per second. In older works, power is sometimes called ''activity''. Power is a Scalar (physics), scalar quantity. Power is related to other quantities; for example, the power involved in moving a ground vehicle is the product of the aerodynamic drag plus traction (engineering), traction force on the wheels, and the velocity of the vehicle. The output power of a Engine, motor is the product of the torque that the motor generates and the angular velocity of its output shaft. Likewise, the power dissipated in an electrical element of a electrical circuit, circuit is the product of the electric current, current flowing through the element and of the voltage across the element. Definition Power is the rate with respect to time at which work is done; it is the time derivative of Work (physics), work: P =\frac where ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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Chemical Reaction
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |