Europium(III) Carbonate
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Europium(III) Carbonate
Europium(III) carbonate is an inorganic compound with the chemical formula Eu2(CO3)3. Preparation Europium(III) carbonate can be obtained by mixing and heating an aqueous solution of ammonium carbonate and europium(III) chloride. A saturated carbon dioxide ammonium carbonate solution (obtained from the reaction of hydrochloric acid and ammonium carbonate solution) can also precipitate europium carbonate from a europium salt solution. Other preparation methods include the thermal decomposition of europium(III) acetate and the reaction of a suspension of europium(III) oxide in water and supercritical carbon dioxide.Yanagihara, N.; Vemulapalli, K.; Fernando, Q. Synthesis of lanthanide carbonates using supercritical carbon dioxide. ''Kidorui'', 1991. 18: 136-137. ISSN: 0910-2205. Chemical properties Europium(III) carbonate is soluble in acid and releases carbon dioxide: :↑ Europium(III) carbonate decomposes at high temperatures to form europium(III) oxide: :↑ References


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Samarium(III) Carbonate
Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide. Discovered in 1879 by French chemist Paul-Émile Lecoq de Boisbaudran, samarium was named after the mineral samarskite from which it was isolated. The mineral itself was named after a Russian mine official, Colonel Vassili Samarsky-Bykhovets, who thus became the first person to have a chemical element named after him, though the name was indirect. Samarium occurs in concentration up to 2.8% in several minerals including cerite, gadolinite, samarskite, monazite and bastnäsite, the last two being the most common commercial sources of the element. These minerals are mostly found in China, the United States, Braz ...
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Gadolinium(III) Carbonate
Gadolinium is a chemical element; it has symbol Gd and atomic number 64. It is a silvery-white metal when oxidation is removed. Gadolinium is a malleable and ductile rare-earth element. It reacts with atmospheric oxygen or moisture slowly to form a black coating. Gadolinium below its Curie point of is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare earths because of their similar chemical properties. Gadolinium was discovered in 1880 by Jean Charles de Marignac, who detected its oxide by using spectroscopy. It is named after the mineral gadolinite, one of the minerals in which gadolinium is found, itself named for the Finnish chemist Johan Gadolin. Pure gadolinium was first isolated by the chemist Félix Trombe in 1935. Gadolinium possesses unusual metallurgical properties, to t ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Ammonium Carbonate
Ammonium carbonate is a chemical compound with the chemical formula . It is an ammonium salt of carbonic acid. It is composed of ammonium cations and carbonate anions . Since ammonium carbonate readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is a predecessor to the more modern leavening agents baking soda and baking powder. It is a component of what was formerly known as sal volatile and salt of hartshorn, and produces a pungent smell when baked. It comes in the form of a white powder or block, with a molar mass of 96.09 g/mol and a density of 1.50 g/cm3. It is a strong electrolyte. Production Ammonium carbonate is produced by combining carbon dioxide and aqueous ammonia. About 80,000 tons/year were produced as of 1997. : An orthorhombic ammonium carbonate monohydrate is known (). It crystallizes in an ammonia solution exposed in a carbon dioxide-rich atmos ...
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Europium(III) Chloride
Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research. Preparation Treating Eu2O3 with aqueous HCl produces hydrated europium chloride (EuCl3·6H2O). This salt cannot be rendered anhydrous by heating. Instead one obtains an oxychloride. Anhydrous EuCl3 is often prepared by the "ammonium chloride route," starting from either Eu2O3 or hydrated europium chloride (EuCl3·6H2O) by heating carefully to 230 °C. These methods produce (NH4)2 uCl5 :10 NH4Cl + Eu2O3 → 2 (NH4)2 uCl5 + 6 NH3 + 3 H2O :EuCl3·6H2O + ''2'' NH4Cl → (NH4)2 uCl5+ 6 H2O The pentachloride decomposes thermally according to the following equation: : (NH4)2 uCl5 → 2 NH4Cl + EuCl3 The thermolysis reaction proceeds via the intermediary of (NH4) u2Cl7 Reactions Europium(III) chloride is ...
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Hydrochloric Acid
Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical. Etymology Because it was produced from halite, rock salt according to the methods of Johann Rudolph Glauber, hydrochloric acid was historically called by European alchemists ''spirits of salt'' or ''acidum salis'' (salt acid). Both names are still used, especially in other languages, such as , , , , , , , , , , (''ensan''), zh, 盐酸 (''yánsuān''), and (''yeomsan''). Gaseous HCl was called ''marine acid air''. The name ''muriatic acid'' has the same origin (''muriatic'' means "pertaining to brine or salt", hence ''muriate'' means hydrochloride), and this ...
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Carbonate
A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group . The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and bicarbonate ions in water to produce carbonated water and other carbonated beverageseither by the addition of carbon dioxide gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In geology and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated sedimentary rock. The most common are calcite or calcium carbonate, , the chief constituent of limestone (as well as the main component of ...
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Europium(III) Acetate
Europium(III) acetate is an inorganic salt of europium and acetic acid with the chemical formula of Eu(CH3COO)3. In this compound, europium exhibits the +3 oxidation state. It can exist in the anhydrous form, sesquihydrate and tetrahydrate. Its hydrate molecule is a Dimer (chemistry), dimer. Preparation Europium acetate can be obtained by stirring reaction of acetic acid and Europium(III) oxide, europium oxide under heating, and then diluting with water and crystallizing: : Eu2O3 + 6 CH3COOH → 2 Eu(CH3COO)3 + 3 H2O Europium can also directly participate in the reaction: : 2 Eu + 6 CH3COOH → 2 Eu(CH3COO)3 + 3 H2↑ Properties Physical properties The anhydrous europium acetate crystallizes monoclinically in the space group ''C2/c'' (space group no. 15) with the lattice parameters ''a'' = 1126.0(3), ''b'' = 2900.5(6), ''c'' = 799.1( 2) pm and ''β'' = 132.03(2)° with four formula units per unit cell. The sesquihydrate crystallizes monoclinically in the space group Cc ...
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Europium(III) Oxide
Europium is a chemical element; it has symbol Eu and atomic number 63. It is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. Europium is the most chemically reactive, least dense, and softest of the lanthanides. It is soft enough to be cut with a knife. Europium was discovered in 1896, provisionally designated as Σ; in 1901, it was named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.Stwertka, Albert. ''A Guide to the Elements'', Oxford University Press, 1996, p. 156. ...
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Carbon Dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at normally-encountered concentrations it is odorless. As the source of carbon in the carbon cycle, atmospheric is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared, infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas Carbon dioxide in Earth's atmosphere, in Earth's atmosphere at 421 parts per million (ppm), or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%. Burning fossil fuels is the main cause of these increased concentrations, which are the primary cause of climate change.IPCC (2022Summary for pol ...
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