Disodium Hydrogen Arsenate
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Disodium Hydrogen Arsenate
Disodium hydrogen arsenate is the inorganic compound with the formula Na2HAsO4.7H2O. The compound consists of a salt and seven molecules of water of crystallization although for simplicity the formula usually omits the water component. The other sodium arsenates are NaH2AsO4 and Na3AsO4, the latter being called sodium arsenate. Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid Arsenic acid or arsoric acid is the chemical compound with the chemical formula, formula . More descriptively written as , this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic .... It is a white, water-soluble solid. Being a diprotic acid, its acid-base properties is described by two equilibria: : + H2O + H3O+ (p''K''a2 = 6.94) : + H2O + H3O+ (p''K''a3 = 11.5) Related compounds * Monopotassium arsenate, KH2AsO4 References Arsenates Sodium compounds {{inorg ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Chemical Formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name since it does not contain any words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called '' empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of atoms ...
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Water Of Crystallization
In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a chemical substance, substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the Crystal structure, crystalline framework of a metal complex or a salt (chemistry), salt, which is not directly chemical bond, bonded to the metal cation. Upon crystallization from water, or water-containing solvents, many chemical compound, compounds incorporate water molecules in their crystalline frameworks. Water of crystallization can generally be removed by heating a sample but the crystalline properties are often lost. Compared to Inorganic compound, inorganic salts, proteins crystallize with large amounts of water i ...
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Sodium Arsenate
Sodium arsenate is the inorganic compound with the formula Na3AsO4. Related salts are also called sodium arsenate, including Na2HAsO4 (disodium hydrogen arsenate) and NaH2AsO4 (sodium dihydrogen arsenate). The trisodium salt is a white or colourless solid that is highly toxic. It is usually handled as the dodecahydrate Na3AsO4.12H2O. The compound can be obtained by neutralizing arsenic acid: :H3AsO4 + 3 NaOH → Na3AsO4 + 3 H2O The salt (as its dodecahydrate) is isomorphous with trisodium phosphate Trisodium phosphate (TSP) is an inorganic compound with the chemical formula . It is a white, granular or crystalline solid, highly soluble in water, producing an alkaline solution. TSP is used as a cleaning agent, builder, lubricant, food addi ....Remy, Francis; Guerin, Henri "Radiocrystallographic study of dodecahydrate trisodium arsenate and vanadate Na3AsO4.12H2O and Na3VO4.12H2O, and some hydrates of fluorinated or hydroxylated salts of general formula: M3XO4.xMY.(10 ...
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Arsenic Acid
Arsenic acid or arsoric acid is the chemical compound with the chemical formula, formula . More descriptively written as , this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized. Its hemihydrate form () does form stable crystals. Crystalline samples dehydrate with condensation at 100 °C. Properties It is a tetrahedral species of idealized symmetry group, symmetry ''C''3v with As–O bond lengths ranging from 1.66 to 1.71 Å. Being a triprotic acid, its acidity is described by three equilibria: :, p''K''a1 = 2.19 :, p''K''a2 = 6.94 :, p''K''a3 = 11.5 These acid dissociation constant, p''K''a values are close to those for phosphoric acid. The highly basic arsenate, arsenate ion () is the product of the third ionization. Unlike phosphoric acid, arsenic acid is an oxidizer, as illustrated by its ability to ...
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Diprotic
An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen cation, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid. The first category of acids are the proton donors, or Brønsted–Lowry acids. In the special case of aqueous solutions, proton donors form the hydronium ion H3O+ and are known as Arrhenius acids. Brønsted and Lowry generalized the Arrhenius theory to include non-aqueous solvents. A Brønsted–Lowry or Arrhenius acid usually contains a hydrogen atom bonded to a chemical structure that is still energetically favorable after loss of H+. Aqueous Arrhenius acids have characteristic properties that provide a practical description of an acid. Acids form aqueous solutions with a sour taste, can turn blue litmus red, and react with bases and certain metals (like calcium) to form salts. The word ''acid'' is derived from the Latin , meaning 'sour'. An aqueous solution of an acid ...
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Monopotassium Arsenate
Monopotassium arsenate is the inorganic compound with the formula KH2AsO4. A white solid, this salt is used to prepared other arsenic-containing compounds, mainly pesticides. It is prepared by calcining arsenic oxide and potassium nitrate, followed by extraction with water. Relevant acid-base equilibria for aqueous solutions of this diprotic acid derived from arsenic acid Arsenic acid or arsoric acid is the chemical compound with the chemical formula, formula . More descriptively written as , this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic ... are as follows: :H3AsO4 + H2O + H3O+ (p''K''a1 = 2.19) : + H2O + H3O+ {{pad, 2em(p''K''a2 = 6.94) Related compounds * Trisodium arsenate, Na3AsO4 * Disodium hydrogen arsenate, Na2HAsO4 References Arsenates Potassium compounds ...
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Arsenates
The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. The four oxygen atoms orient around the arsenic atom in a tetrahedral geometry. Resonance disperses the ion's −3 charge across all four oxygen atoms. Arsenate readily reacts with metals to form arsenate metal compounds. Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with phosphate. Arsenate can replace phosphate in biochemical reactions and is toxic to most organisms. Natural occurrence Arsenates occur naturally, in hydrated and anhydrous form, in a variety of minerals. Examples of arsenate-containing minerals include adamite, alarsite, annabergite, ...
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